上海大学学报(自然科学版) ›› 2018, Vol. 24 ›› Issue (5): 782-790.doi: 10.12066/j.issn.1007-2861.1956
收稿日期:2017-06-29
出版日期:2018-10-30
发布日期:2018-10-26
通讯作者:
刘丽
E-mail:liuli@staff.shu.edu.cn
基金资助:
LIU Li1(
), ZHU Huijie1, TU Duoxiang1, HAO Xinmin2, HUANG Jie3
Received:2017-06-29
Online:2018-10-30
Published:2018-10-26
Contact:
LIU Li
E-mail:liuli@staff.shu.edu.cn
摘要:
以用途广泛的乙烯-醋酸乙烯酯(ethylene-vinyl acetate, EVA)为基体, 采用模压成型工艺制备了 EVA/汉麻秆芯粉(EVA/hemp stem powder, EVA/HSP)复合发泡材料. 通过扫描电子显微镜(scanning electron microscopy, SEM)观察了 EVA/HSP 复合发泡材料的泡孔形貌, 通过哈克转矩流变仪研究了 EVA/HSP 复合发泡材料的流变形能, 表征了不同 HSP 添加量的 EVA/HSP 复合发泡材料的吸湿快干性能和力学性能, 探讨了 HSP 添加量对吸湿快干性能和断裂伸长率的影响机制. 结果发现, 当 HSP 的添加量为 10$\sim$20 phr 时, 材料的综合性能最优. 这是因为适量的 HSP 有助于改善材料的泡孔形貌, 兼具补强和增韧的效果, 并赋予了材料优异的吸湿快干性能.
中图分类号:
刘丽, 诸慧杰, 涂多想, 郝新敏, 黄杰. EVA/HSP 复合发泡材料的制备和性能[J]. 上海大学学报(自然科学版), 2018, 24(5): 782-790.
LIU Li, ZHU Huijie, TU Duoxiang, HAO Xinmin, HUANG Jie. Preparation and properties of EVA/HSP composite foams[J]. Journal of Shanghai University(Natural Science Edition), 2018, 24(5): 782-790.
| [1] | 接家振. 我国 EVA 生产现状及发展前景[J]. 化工管理, 2015(8):74-75. |
| [2] | Pandey J K, Reddy K R, Kumar A P, et al. An overview on the degradability of polymer nanocomposites[J]. Polymer Degradation & Stability, 2005,88(2):234-250. |
| [3] | Deng F, Ma J, Xue C, et al. Foamed materials from POE/EVA blends[J]. Journal of Functional Materials, 2012(4):508-511. |
| [4] |
Julyanon J, Kaesaman A, Sakai T, et al. Improvement of structure and properties of nanocomposite foams based on ethylene-vinyl acetate (EVA)/natural rubber (NR)/nanoclay: effect of NR addition[J]. Key Engineering Materials, 2015,659:418-422.
doi: 10.4028/www.scientific.net/KEM.659 |
| [5] | Spina R. Technological characterization of PE/EVA blends for foam injection molding[J]. Materials & Design, 2015,84:64-71. |
| [6] |
Zhang Z X, Zhang T, Wang D, et al. Physicomechanical, friction, and abrasion properties of EVA/PU blend foams foamed by supercritical nitrogen[J]. Polymer Engineering and Science, 2017, DOI: 10.1002/pen.24598.
doi: 10.1002/pen.25094 pmid: 31937978 |
| [7] |
Thongpin C, Muanwong A, Yanyongsak J, et al. Effect of ENR contents on cure characteristic and properties of NR/ENR/EVA foam[J]. Materials Science Forum, 2017,889:45-50.
doi: 10.4028/www.scientific.net/MSF.889 |
| [8] | Deng F, Ma J, Xue C, et al. Morphology and mechanical properties of EVA/OSEP foamed materials[J]. Journal of Functional Materials, 2013(7):15. |
| [9] | Jin B H, Xia Z W. Study on the effect of filling modification of foaming EVA from slag powder and modified slag powder[J]. Journal of Hunan Industry Polytechnic, 2016,16(2):12-14. |
| [10] | Zheng H D, Qiu H F, Zheng Y Y, et al. Preparation and antibacterial property of EVA composite foams supported by nano-silver[J]. Journal of Materials Engineering, 2016, DOI: 10.11868/j.issn.1001-4381.2016.07.018. |
| [11] | Sang G, Zhu Y, Yang G. Mechanical properties of high porosity cement-based foam materials modified by EVA[J]. Construction & Building Materials, 2016,112:648-653. |
| [12] |
Rodriguez-Perez M A, Simoes R D, Constantino C J L, et al. Structure and physical properties of EVA/starch precursor materials for foaming applications[J]. Journal of Applied Polymer Science, 2011,121(4):2324-2330.
doi: 10.1002/app.33946 |
| [13] | Rodriguezpe-Rez M A, Simoes R D, Roman-Lorza S, et al. Foaming of EVA/starch blends: characterization of the structure, physical properties, and biodegradability[J]. Polymer Engineering and Science, 2012,52(1):62-70. |
| [14] | Matheus V G Z, Taís C T, Ruth M C S, et al. The influence of wood flour particle size and content on the rheological, physical, mechanical and morphological properties of EVA/wood cellular composites[J]. Materials & Design, 2014,57:660-666. |
| [15] | Kim J H, Kim G H. Preparation and cell morphology of ethylene-vinyl acetate copolymer (EVA)/wood-flour foams with low density[J]. Journal of Applied Polymer Science, 2014,131(20), DOI: 10.1002/app.40894. |
| [16] | Zimmermann M V G, Turella T C, Santana R M C, et al. The influence of wood flour particle size and content on the rheological, physical, mechanical and morphological properties of EVA/wood cellular composites[J]. Materials & Design, 2014,57:660-666. |
| [17] |
Hao X M, Ma W J, Gan G, et al. Analysis of novel structure of EVA/hemp stem powder foam materials[J]. Advanced Materials Research, 2012,627:651-654.
doi: 10.4028/www.scientific.net/AMR.627 |
| [18] | 倪燕, 柯勤飞, 冯云. 汉麻纤维及其发展前景[J]. 轻纺工业与技术, 2013,42(1):21-23. |
| [19] | 郝新敏, 杨元, 安利霞, 等. 汉麻秆芯抗菌成分提取与织物抗菌整理应用研究[C]// 抗菌科学与技术论坛. 2014: 103. |
| [20] | 王菲. 高品质汉麻产业化的实现[J]. 纺织科学研究, 2017(2):31-33. |
| [21] |
Zhang S, Rodrigue D, Riedl B. Preparation and morphology of polypropylene/wood flour composite foams via extrusion[J]. Polymer Composites, 2005,26(6):731-738.
doi: 10.1002/(ISSN)1548-0569 |
| [22] | Rodrigue D, Gosselin R. The effect of nucleating agents on polypropylene foam morphology[J]. Blowing Agents and Foaming Process, 2003(5):169-178. |
| [23] | Matuana L M, Park C B, Balatinecz J J. Cell morphology and property relationships of microcellular foamed PVC/wood-fiber composites[J]. Polymer Engineering & Science, 1998,38(11):1862-1872. |
| [24] |
Rizvi G M, Park C B, Guo G. Strategies for processing wood plastic composites with chemical blowing agents[J]. Journal of Cellular Plastics, 2008,44(2):125-137.
doi: 10.1177/0021955X07082184 |
| [25] |
Kuboki T, Lee Y H, Park C B, et al. Mechanical properties and foaming behavior of cellulose fiber reinforced high-density polyethylene composites[J]. Polymer Engineering & Science, 2009,49(11):2179-2188.
doi: 10.1002/pen.v49:11 |
| [26] |
Rizvi G M, Pop-Iliev R, Parky C B. A novel system design for continuous processing of plastic/wood-fiber composite foams with improved cell morphology[J]. Journal of Cellular Plastics, 2002,38(5):367-383.
doi: 10.1177/0021955X02038005786 |
| [27] |
Ganter M, Gronski W, Reichert P, et al. Rubber nanocomposites: morphology and mechanical properties of BR and SBR vulcanizates reinforced by organophilic layered silicates[J]. Rubber Chemistry and Technology, 2001,74(2):221-235.
doi: 10.5254/1.3544946 |
| [28] |
Gatos K G, Sawanis N S, Apostolov A A, et al. Nanocomposite formation in hydrogenated nitrile rubber (HNBR)/organo-montmorillonite as a function of the intercalant type[J]. Macromolecular Materials and Engineering, 2004,289(12):1079-1086.
doi: 10.1002/(ISSN)1439-2054 |
| [29] |
Wu Y P, Ma Y, Wang Y Q, et al. Effects of characteristics of rubber, mixing and vulcanization on the structure and properties of rubber/clay nanocomposites by melt blending[J]. Macromolecular Materials and Engineering, 2004,289(10):890-894.
doi: 10.1002/(ISSN)1439-2054 |
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