上海大学学报(自然科学版) ›› 2012, Vol. 18 ›› Issue (3): 277-281.doi: 10.3969/j.issn.1007-2861.2012.03.012

• 论文 • 上一篇    下一篇

扩散方阻对多晶硅太阳能电池效率的影响

李鹏荣,吴伟,马忠权,王义飞   

  1. (上海大学 理学院,上海 200444)
  • 出版日期:2012-06-30 发布日期:2012-06-30
  • 通讯作者: 吴伟(1965~),男,副教授,博士,研究方向为硅太阳能电池工艺. E-mail:wuwei@shu.edu.cn

Influence of Sheet Resistance on Efficiency of Multicrystalline Silicon Solar Cells

LI Peng-rong,WU Wei,MA Zhong-quan,WANG Yi-fei   

  1. (College of Sciences, Shanghai University, Shanghai 200444, China)
  • Online:2012-06-30 Published:2012-06-30

摘要: 在现有大规模太阳能电池生产工艺的基础上,改变扩散工艺条件,制备一系列的方块电阻发射极.在未改变其他工艺参数的条件下,当发射极方块电阻升高时,短路电流持续上升,开路电压在接近70 Ω/□时接近饱和,而填充因子(fill factor,FF)则因串联电阻的增加呈下降趋势.器件的效率在70 Ω/□方阻发射极时达到最大值.通过光致发光图(photoluminescence, PL)比较方阻为50和70 Ω/□发射极的吸杂效果,结果说明,在磷扩散过程中,硅片的晶粒、晶界以及位错区域的吸杂效果都非常明显,且50 Ω/□发射极硅片的吸杂效果略优于70 Ω/□的硅片.

关键词: 方块电阻, 光致发光图, 扩散, 太阳能电池, 吸杂

Abstract: Based on the existing largescale solar cell production process, a series of sheet resistance emitters were prepared by changing diffusion process conditions. When the emitter sheet resistance increases, shortcircuit current rises continuously, and opencircuit voltage is close to saturation near 70 Ω/□, while fill factor (FF) declines due to the increase of serial resistance under the condition that other process parameters are unchanged. Efficiency of the device reaches maximum when the emitter sheet resistance is 70 Ω/□. Based on this conclusion, this paper compares gettering effect of the emitter sheet resistance between 50 and 70 Ω/□ by photoluminescence (PL) images. PL images show that during the diffusion process of phosphorus in a silicon grain, grain boundary and dislocation, gettering effect of these regions is very obvious, and the absorbing effect of the 50 Ω/□ emitter silicon is slightly better than the 70 Ω/□ one.

Key words: absorbing effect, diffusion, photoluminescence (PL), sheet resistance, solar cells

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