含钛复合矿选择性提取制备钛合金

doi:10.3969/j.issn.1007-2861.2011

上海大学学报(自然科学版) ›› 2011, Vol. 17 ›› Issue (1): 1-6.doi: 10.3969/j.issn.1007-2861.2011

• 上海市现代冶金与材料制备重点实验室专栏 • 下一篇

含钛复合矿选择性提取制备钛合金

邹星礼，鲁雄刚，李重河，钟庆东，丁伟中

（上海大学上海市现代冶金与材料制备重点实验室，上海 200072）

收稿日期:2010-11-22 出版日期:2011-02-28 发布日期:2011-02-28
通讯作者: 鲁雄刚（1969~），男，教授，博士生导师，博士，研究方向为冶金新工艺开发、渣金反应的电化学机理等. E-mail:luxg@shu.edu.cn
基金资助:
国家重点基础研究发展计划（973计划）资助项目（2007CB613606）；国家自然科学基金资助项目(50774052,51074105)

Direct Deoxidization of Ti-Bearing Compounds and Selective Extraction of Titanium Alloys

ZOU Xing-li, LU Xiong-gang, LI Chong-he, ZHONG Qing-dong, DING Wei-zhong

(Shanghai Key Laboratory of Modern Metallurgy & Materials Processing, Shanghai University, Shanghai 200072, China)

Received:2010-11-22 Online:2011-02-28 Published:2011-02-28

摘要/Abstract

摘要：

采用固体透氧膜（solid oxygen-ion membrane，SOM）熔盐电解法，对含钛复合矿直接脱氧并选择性提取钛合金.经过X-射线衍射（X-ray diffraction, XRD）、扫描电子显微镜（scanning electron microscope, SEM）和能量分数X-射线（energy dispersive Xray, EDX）分析，结果表明：从含钛高炉渣中可以直接提取出Ti5Si3合金粉末，并可有效去除金属杂质Ca，Mg，Al；从钛铁矿中可以直接提取出TiFex合金.最后，对电解脱氧过程进行讨论分析.

关键词: 固体透氧膜；熔盐电解；钛合金；含钛复合矿

Abstract:

Direct deoxidization of Ti-bearing compounds was done by using solid oxygen-ion membrane (SOM) molten salt electrolysis and selective extraction of titanium alloys simultaneously. X-ray diffraction (XRD), scanning electron microscope (SEM) and energy dispersive X-ray (EDX) analyses show that the Ti5Si3 alloy can be extracted directly from Ti-bearing blast furnace slag. Metallic impurities such as calcium, magnesium and aluminum were completely removed from products during electrolysis. In addition, TiFex alloys can also be obtained directly from deoxidized ilmenite (FeTiO3) in molten salt. Finally, the electro-deoxidation processes are discussed.〖HJ〗

Key words: solid oxygen-ion membrane (SOM); molten salt electrolysis; titanium alloys; Ti-bearing compounds

中图分类号:

邹星礼，鲁雄刚，李重河，钟庆东，丁伟中. 含钛复合矿选择性提取制备钛合金[J]. 上海大学学报(自然科学版), 2011, 17(1): 1-6.

ZOU Xing-li, LU Xiong-gang, LI Chong-he, ZHONG Qing-dong, DING Wei-zhong. Direct Deoxidization of Ti-Bearing Compounds and Selective Extraction of Titanium Alloys[J]. Journal of Shanghai University（Natural Science Edition）, 2011, 17(1): 1-6.

含钛复合矿选择性提取制备钛合金

Direct Deoxidization of Ti-Bearing Compounds and Selective Extraction of Titanium Alloys

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