共价有机骨架衍生的氮掺杂碳/碳纳米管杂化结构的储锂性能

doi:10.12066/j.issn.1007-2861.2111

Abstract

Abstract:

The covalent organic framework, obtained by the facile room-temperature method, was selected as the precursor for fabricating the nitrogen-doped carbon/carbon nanotube composite (N-C-CNT), in with the nitrogen-doped carbon was derived directly from the covalent organic framework, while the carbon nanotubes were formed in situ from acetylene under catalysis by metallic cobalt. Due to N-doping, the carbon layer provides more active sites for lithium storage; therefore, the N-C-CNT composite exhibits high specific capacity and excellent cycle stability (reversible capacity of 652 mA·h·g^-1 after300 cycles) as an anode material for lithium ion batteries.

Key words: covalent organic framework (COF), carbon nanotube, lithium-ion battery, anode materials, composite

CLC Number:

TM912

TANG Xuxu, YANG Qingsi, YANG Jianwei, SUN Weiwei. Composite of covalent organic framework-derived nitrogen-doped carbon with carbon nanotubes for lithium-storage[J]. Journal of Shanghai University（Natural Science Edition）, 2020, 26(6): 972-979.

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Composite of covalent organic framework-derived nitrogen-doped carbon with carbon nanotubes for lithium-storage

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