SnO$_{\boldsymbol{x}}$S$_{\boldsymbol{y}}$@PANI@rGO 复合材料的制备及其电化学性能

doi:10.12066/j.issn.1007-2861.2104

Abstract

Abstract:

By hydrothermal synthesis of tin disulfide hexagonal wafers, polyaniline was wrapped outside by using oxidative polymerization, and tin-oxygen sulfide compound@polyaniline@reduced graphene oxide composites were prepared by hydrothermal reduction. Characterization instruments of X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscope (SEM), and transmission electron microscope (TEM) were used to analyze the morphology and phase of the composites. The results show that the prepared hexagonal tin oxysulfide compound is double-coated by polyaniline and reduced graphene. The electrochemical properties of the composites as a negative electrode of a lithium-ion battery were investigated. The results reveal that the polyaniline and reduced graphene in the multicomponent composite increase the conductivity and buffer the volume expansion of the tin-oxygen sulfide compound during charge and discharge, maintain structural stability, and exhibit superior electrical performance.

Key words: tin-oxygen sulfide compound, hexagonal phase, lithium-ion battery

CLC Number:

TQ152

ZHU Ying, ZHOU Diwen, TANG Yan, WANG Hao, ZHAO Pandeng, PU Xianjuan, JIAO Zheng, CHENG Lingli. Synthesis of tin-oxygen sulfide compound @poly-aniline@reduced graphene composites with superior electrochemical performance[J]. Journal of Shanghai University（Natural Science Edition）, 2021, 27(1): 78-85.

Figures/Tables 6

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

Table 1

References 24

[1]	Hu J, Jia F F, Song Y F. Engineering high-performance polyoxometalate/PANI/MWNTs nanocomposite anode materials for lithium ion batteries[J]. Chemical Engineering Journal, 2017,326:273-280. doi: 10.1016/j.cej.2017.05.153
[2]	Dong Y F, Zhao Z B, Wang Z Y, et al. Dually fixed SnO$_{2}$ nanoparticles on graphene nanosheets by polyaniline coating for superior lithium storage[J]. ACS Applied Materials & Interfaces, 2015,7(4):2444-2451. doi: 10.1021/am506818h pmid: 25602679
[3]	Dinkelacker F, Marzak P, Yun J, et al. Multistage mechanism of lithium intercalation into graphite anodes in the presence of the solid electrolyte interface[J]. ACS Applied Materials ${\&}$ Interfaces, 2018,10(16):14063-14069. doi: 10.1021/acsami.7b18738 pmid: 29539259
[4]	Teixidor G T, Park B Y, Mukherjee P P, et al. Modeling fractal electrodes for Li-ion batteries[J]. Electrochimica Acta, 2009,54(24):5928-5936. doi: 10.1016/j.electacta.2009.05.060
[5]	Wang F, Jiao H X, He E K, et al. Facile synjournal of ultrafine SnO$_{2}$ nanoparticles embedded in carbon networks as a high-performance anode for lithium-ion batteries[J]. Journal of Power Sources, 2016,326:78-83. doi: 10.1016/j.jpowsour.2016.06.120
[6]	Qu B H, Ma C Z, Ji G, et al. Layered SnS$_{2}$-reduced graphene oxide composite: a high-capacity, high-rate, and long-cycle life sodium-ion battery anode material[J]. Advanced Materials, 2014,26(23):3854-3859. doi: 10.1002/adma.201306314
[7]	Du Y, Yin Z, Rui X, et al. A facile, relative green, and inexpensive synthetic approach toward large-scale production of SnS$_{2}$ nanoplates for high-performance lithium-ion batteries[J]. Nanoscale, 2013,5(4):1456-1466. doi: 10.1039/c2nr33458e
[8]	Samad A, Alam M, Shin Y H. First principles study of a SnS$_{2}$/graphene heterostructure: a promising anode material for rechargeable Na ion batteries[J]. Journal of Materials Chemistry A, 2016,4(37):14316-14323. doi: 10.1039/C6TA05739J
[9]	Khan Z, Parveen N, Ansari S A, et al. Three-dimensional SnS$_{2}$ nanopetals for hybrid sodium-air batteries[J]. Electrochimica Acta, 2017,257:328-334. doi: 10.1016/j.electacta.2017.10.063
[10]	Zhao B, Chen F, Wang Z X, et al. Lithiation-assisted exfoliation and reduction of SnS$_{2}$ to SnS decorated on lithium-integrated graphene for efficient energy storage[J]. Nanoscale, 2017,9(45):17922-17932. doi: 10.1039/c7nr06798d pmid: 29124272
[11]	Luo, B, Hu Y X, Zhu X B, et al. Controllable growth of SnS$_2$ nanostructures on nanocarbon surfaces for lithium-ion and sodium-ion storage with high rate capability[J]. Journal of Materials Chemistry A, 2018,6(4):1462-1472. doi: 10.1039/C7TA09757C
[12]	Zhai C, Du N, Yang H Z. Large-scale synjournal of ultrathin hexagonal tin disulfide nanosheets with highly reversible lithium storage[J]. Chemical communications, 2011,47(4):1270-1282. doi: 10.1039/c0cc03023f
[13]	Wang J G, Sun H H, Liu H Y, et al. Edge-oriented SnS$_{2}$ nanosheet arrays on carbon paper as advanced binder-free anodes for Li-ion and Na-ion batteries[J]. Journal of Materials Chemistry A, 2017,5(44):23115-23122. doi: 10.1039/C7TA07553G
[14]	Zheng P L, Dai Z F, Zhang Y, et al. Scalable synjournal of SnS$_{2}$/S-doped graphene composites for superior Li/Na-ion batteries[J]. Nanoscale, 2017,9(39):14820-14825. doi: 10.1039/c7nr06044k pmid: 28959816
[15]	Chen Q, Lu F, Xia Y, et al. Interlayer expansion of few-layered Mo-doped SnS$_{2}$ nanosheets grown on carbon cloth with excellent lithium storage performance for lithium ion batteries[J]. Journal of Materials Chemistry A, 2017,5(8):4075-4083. doi: 10.1039/C7TA00236J
[16]	白雪君. 高性能锂离子电池用锡基、硅基负极材料研究[D]. 上海: 东华大学, 2016.
	Bai X J. Study on Tin and Silicon based anode meterials for high performance lithium-ion battery[D]. Shanghai: Donghua University, 2016.
[17]	程娅伊. 锂/钠离子电池用锡基负极材料的制备及电化学性能研究[D]. 西安: 陕西科技大学, 2018.
	Cheng Y Y. Study on synthesis of tin-based anodes materials and their electrochemical performance for lithium/sodium-ion batteries [D]. Xi'an: Shaanxi University of Science $\&$ Technology, 2018.
[18]	周丹. 锂/钠离子电池负极材料的设计及性能研究[D]. 北京: 北京科技大学, 2017.
	Zhou D. Design and performance of anode materials for Li/Na-ion batteries[D]. Beijing: University of Science and Technology Beijing, 2017.
[19]	Wang L Y, Zhuo L H, Yu Y C, et al. High-rate performance of SnS$_{2}$ nanoplates without carbon-coating as anode material for lithium ion batteries[J]. Electrochimica Acta, 2013,112:439-447. doi: 10.1016/j.electacta.2013.08.154
[20]	Wu Q, Jiao L, Du J, et al. One-pot synjournal of three-dimensional SnS$_{2}$ hierarchitectures as anode material for lithium-ion batteries[J]. Journal of Power Sources, 2013,239:89-93. doi: 10.1016/j.jpowsour.2013.03.062
[21]	Wei W, Jia F F, Wang K F, et al. SnS$_{2}$/graphene nanocomposite: a high rate anode material for lithium ion battery[J]. Chinese Chemical Letters, 2017,28(2):324-328. doi: 10.1016/j.cclet.2016.09.003
[22]	Lu M W, Wang Q F, Miao J, et al. Synjournal and electrochemical performances of cotton ball-like SnS$_{2}$ compound as anode material for lithium ion batteries[J]. Materials Technology, 2016,31(5):281-285. doi: 10.1179/1753555715Y.0000000054
[23]	Guan D S, Ma L L, Pan D Q, et al. Atomic layer deposition of alumina coatings onto SnS$_{2}$ for lithium-ion battery applications[J]. Electrochimica Acta, 2017,242:117-124. doi: 10.1016/j.electacta.2017.05.023
[24]	Zhu W B, Yang Y W, Ma D M, et al. Controlled growth of flower-like SnS$_{2}$ hierarchical structures with superior performance for lithium-ion battery applications[J]. Ionics, 2015,21(1):19-26. doi: 10.1007/s11581-014-1163-7

Synthesis of tin-oxygen sulfide compound @poly-aniline@reduced graphene composites with superior electrochemical performance

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 6

References 24

Related Articles 4

Recommended Articles

Metrics

Comments

[1]	ZHU Delun, PENG Yuqing, BAI Ruicheng, LI Aijun, ZHAO Tianting, SUN Ningxia. Design and fabrication of silver-coated three-dimensional porous silicon composite anode with high performance for lithium ion battery [J]. Journal of Shanghai University（Natural Science Edition）, 2021, 27(1): 144-153.
[2]	TANG Xuxu, YANG Qingsi, YANG Jianwei, SUN Weiwei. Composite of covalent organic framework-derived nitrogen-doped carbon with carbon nanotubes for lithium-storage [J]. Journal of Shanghai University（Natural Science Edition）, 2020, 26(6): 972-979.
[3]	MIAO Chunjie, HU Zhixiang, REN Lanlan, GAO Ziming, DONG Jingyu, LI Qi, LUO Zhigang, CHEN Zhiwen. Preparation and properties of Ni-doped SnO₂ nanospheres for lithium-ion battery anode materials [J]. Journal of Shanghai University（Natural Science Edition）, 2016, 22(2): 239-244.
[4]	WU Feng-Dan, GU Yan, WANG Yong. Facile Synthesis of Graphite Nanosheets as Anode Materials for Lithium-ion Batteries [J]. Journal of Shanghai University（Natural Science Edition）, 2010, 16(5): 471-475.