上海大学学报(自然科学版)

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8-羟基喹啉萃取La(Ⅲ)的机理

张倩,包伯荣

  

  1. 上海大学 理学院,上海 200444
  • 收稿日期:2006-11-28 修回日期:1900-01-01 出版日期:2008-04-30 发布日期:2008-04-30
  • 通讯作者: 包伯荣

Extraction of Lanthanum with 8-Hydroxyquinoline

ZHANG Qian, BAO Bo-rong   

  1. College of Sciences, Shanghai University, Shanghai 200444, China
  • Received:2006-11-28 Revised:1900-01-01 Online:2008-04-30 Published:2008-04-30
  • Contact: BAO Bo-rong

摘要: 研究8羟基喹啉的正庚烷溶液在盐酸介质中对3价稀土离子镧的萃取效应,探讨水相酸度、萃取剂浓度、Clˉ浓度、不同稀释剂等因素对萃取平衡的影响,并运用双对数斜率法确定
8-羟基喹啉萃取La(Ⅲ)的机理.

关键词: 8-羟基喹啉, La(Ⅲ), 萃取

Abstract: The solvent extraction of La3+ from hydrochloric acid solutions was Investigated using 8-Hydroxyquinoline as extractant. The effect of equilibrium of aqueous acidity on extraction of La3+ using 8Hydroxyquinoline was discussed. The effects of extractant concentraction, different diluents and chloride ion on extraction reaction were also studied. With a doublelogarithmic slope method, composition of the extracted species of 8-Hydroxyquinoline was derived.

Key words: extraction, Lanthanum, 8-Hydroxy quinoline

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