上海大学学报(自然科学版) ›› 2012, Vol. 18 ›› Issue (3): 311-316.doi: 10.3969/j.issn.1007-2861.2012.03.018

• 论文 • 上一篇    下一篇

核反应堆压力容器模拟钢中纳米富Cu相的变形特征

蔡琳玲1,2,徐刚1,2,冯柳1,2,王均安1,2,彭剑超1,2,周邦新1,2   

  1. (1.上海大学 材料研究所,上海 200072; 2.上海大学 微结构重点实验室,上海 200444)
  • 出版日期:2012-06-30 发布日期:2012-06-30
  • 通讯作者: 周邦新(1935~),男,中国工程院院士,研究员,博士生导师,研究方向为核反应堆结构材料. E-mail:zhoubx@shu.edu.cn
  • 基金资助:

    国家重点基础研究发展计划(973计划)资助项目(2011CB610503);国家自然科学基金重点资助项目(50931003);上海市重点学科建设资助项目(S30107)

Deformation Characterization of NanoScale Cu-Rich Precipitates in  Reactor Pressure Vessel Model Steel

CAI Lin-ling1,2,XU Gang1,2,FENG Liu1,2,WANG Jun-an1,2,PENG Jian-chao1,2,ZHOU Bang-xin1,2   

  1. (1. Institute of Materials, Shanghai University, Shanghai 200072, China;2. Laboratory for Microstructures, Shanghai University, Shanghai 200444, China)
  • Online:2012-06-30 Published:2012-06-30

摘要: 提高了Cu含量的核反应堆压力容器(reactor pressure vessel,RPV)模拟钢样品,经过880 ℃水淬、660 ℃调质处理和400 ℃ 1 000~4 000 h的等温时效处理,观察到纳米富Cu相的析出;随后进行20%~30%冷轧变形,采用萃取复型(extraction replica,ER)和高分辨透射电镜(high resolution transmission electron microscopy,HRTEM)的方法研究纳米富Cu相的变形特征.研究结果表明,镶嵌在α-Fe基体中的纳米富Cu相,在冷轧变形时的变形机制较为复杂,存在多种变形方式.当纳米富Cu相的晶体处于有利取向时,可以跟随基体一起发生滑移变形,表现为“软”颗粒的特性;当晶体处于不利取向时,会发生孪生变形,甚至诱发马氏体相变,有时生成“轮毂辐条”状的孪晶结构,大大提高了纳米富Cu相继续变形时的抗力,表现为“硬”颗粒的特征,因而析出纳米富Cu相会产生明显的强化作用.

关键词: 变形, 萃取复型, 富Cu相, 高分辨透射电镜, 核反应堆压力容器模拟钢

Abstract: The nanoscale Cu-rich precipitates in reactor pressure vessel (RPV) model steel after water quenching, tempering and thermal aging at 400 ℃ has been investigated by extraction replica (ER) and high resolution transmission electron microscopy (HRTEM). Samples were coldrolled by 20%~30% after aging to study the deformation characterization of Cu-rich precipitates. The results show that the deformation characterization of the nanometer Cu-rich precipitates is complicated due to the restriction of αFe matrix. Different deformation mechanisms are detected. When the Cu-rich precipitates are located in a favorable orientation, they will be deformed by slipping together with the deformation of α-Fe matrix to show the particles of “soft” characteristic. When the Cu-rich precipitates are located in an unfavorable orientation, they will be deformed by twinning to form the spokelike twins within a Curich precipitate, even a martensitic phase transformation induced by strain. In this case, the Curich precipitates show the particles of “hard” characteristic. Therefore the precipitation hardening occurs after the formation of Cu-rich precipitates in α-Fe matrix.

Key words: Curich precipitate, deformation characterization, extraction replica (ER), high resolution transmission electron microscopy (HRTEM), reactor pressure vessel (RPV) model steel

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