上海大学学报(自然科学版) ›› 2021, Vol. 27 ›› Issue (1): 117-124.doi: 10.12066/j.issn.1007-2861.2113
赵攀登, 何永超, 何新华, 冯笑笑, 浦娴娟, 程伶俐, 焦正()
收稿日期:
2019-01-16
出版日期:
2021-02-28
发布日期:
2021-02-28
通讯作者:
焦正
E-mail:zjiao@shu.edu.cn
作者简介:
焦 正(1972---), 男, 教授, 博士生导师, 博士, 研究方向为纳米敏感材料和器件. E-mail: zjiao@shu.edu.cn基金资助:
ZHAO Pandeng, HE Yongchao, HE Xinhua, FENG Xiaoxiao, PU Xianjuan, CHENG Lingli, JIAO Zheng()
Received:
2019-01-16
Online:
2021-02-28
Published:
2021-02-28
Contact:
JIAO Zheng
E-mail:zjiao@shu.edu.cn
摘要:
通过溶剂热法合成了 Co/Cu-BTC 实心立方体前驱体, 并以此为自牺牲模板在空气中煅烧得到双层壳结构 Co$_{2.7}$Cu$_{0.3}$O$_{4}$ 立方体复合材料, 使用 X 射线衍射(X-ray diffraction, XRD)仪、扫描电子显微镜(scanning electron microscope, SEM)和透射电子显微镜(transmission electron microscope, TEM)对材料进行物相形貌分析. 结果表明: 制备的 Co$_{2.7}$Cu$_{0.3}$O$_{4}$ 具有双层壳立方体结构. 制备的复合材料作为锂电池负极材料, 表现出优异的循环稳定性能, 这归因于其独特的双层壳结构有效地缩短了电子转移路程, 缓解了在充放电过程中的体积膨胀, 保持了结构的稳定性.
中图分类号:
赵攀登, 何永超, 何新华, 冯笑笑, 浦娴娟, 程伶俐, 焦正. 双层壳结构 Co$_{\bf 2.7}\rm {\bf Cu_{0.3}O_{4}}$ 立方体复合材料的制备及锂电性能[J]. 上海大学学报(自然科学版), 2021, 27(1): 117-124.
ZHAO Pandeng, HE Yongchao, HE Xinhua, FENG Xiaoxiao, PU Xianjuan, CHENG Lingli, JIAO Zheng. Synthesis of double layer Co$_{\bf 2.7}$Cu$_{\bf 0.3}$O$_{\bf 4 }$ cubes composites with enhanced lithium ion battery performance[J]. Journal of Shanghai University(Natural Science Edition), 2021, 27(1): 117-124.
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