镍掺杂SnO2纳米微球锂离子电池负极材料的制备及其性能

doi:10.3969/j.issn.1007-2861.2015.05.020

上海大学学报(自然科学版) ›› 2016, Vol. 22 ›› Issue (2): 239-244.doi: 10.3969/j.issn.1007-2861.2015.05.020

镍掺杂SnO₂纳米微球锂离子电池负极材料的制备及其性能

苗纯杰, 胡志翔, 任兰兰, 郜子明, 董敬余, 李琦, 罗志刚, 陈志文

上海大学环境与化学工程学院, 上海 200444

收稿日期:2016-01-15 出版日期:2016-04-30 发布日期:2016-04-30
通讯作者: 陈志文(1962—),男,教授,博士生导师,研究方向为纳米材料的合成与性质. E-mail: zwchen@shu.edu.cn
作者简介:陈志文(1962—),男,教授,博士生导师,研究方向为纳米材料的合成与性质. E-mail: zwchen@shu.edu.cn
基金资助:
国家自然科学基金资助项目(11375111, 11428410)；教育部博士点基金资助项目(20133108110021)

Preparation and properties of Ni-doped SnO₂ nanospheres for lithium-ion battery anode materials

MIAO Chunjie, HU Zhixiang, REN Lanlan, GAO Ziming, DONG Jingyu, LI Qi, LUO Zhigang, CHEN Zhiwen

School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China

Received:2016-01-15 Online:2016-04-30 Published:2016-04-30

摘要/Abstract

摘要：

利用简单的一步水热法制备高性能的镍掺杂SnO₂ 纳米微球锂离子电池负极材料. 利用扫描电镜(scanning electron microscope, SEM)、高分辨率透射电镜(high resolution transmission electron microscope, HRTEM)、拉曼分析仪、X射线衍射(X-ray diffraction, XRD)仪以及电化学性能测试仪器(如蓝电测试系统、电化学工作站)分别研究了镍掺杂对SnO₂ 微观形貌、组成、结晶行为及电化学性能的影响, 并得到了最佳反应时间. 实验结果表明：与纯SnO₂相比, 镍掺杂SnO₂ 纳米微球表现出了更好的倍率性能和优异的循环性能. 特别地, 反应时间为12 h 的5 % 镍掺杂SnO₂ 在100 mA/g 电流密度下的首次放电比容量为1 970.3 mA·h/g,远高于SnO₂的理论容量782 mA·h/g. 这是因为镍掺杂可适应庞大的体积膨胀, 避免了纳米粒子的团聚, 因此其电化学性能得到了显著改善.

关键词: 负极材料, 锂离子电池 , 镍掺杂SnO₂

Abstract:

Ni-doped SnO₂ nanospheres were synthesized with a facile one-step hydrothermal method as a high-performance anode material for lithium-ion batteries. Scanning electron microscope (SEM), high resolution transmission electron microscope (HRTEM), Raman analyzer, X-ray diffraction (XRD) and electrochemical performance testing equipment such as blue electrical test systems and electrochemical workstation were used to investigate morphology, composition, crystallization behavior and electrochemical properties of Ni-doped SnO₂ and find the best doping reaction time. It has been found that the appropriate Ni-doped SnO₂ nanospheres showed much better rate capability and excellent cycling performance compared with the pristine SnO₂. In particular, the sample of 5% Ni-doped SnO₂ whose reaction time was 12 h showed a high initial discharge capacity of 1 970.3 mA·h/g at a current density of 100 mA/g, far higher than the theoretical capacity of SnO2 of 782 mA·h/g. This was because Ni-doping could accommodate huge volume expansion and avoid agglomeration of nanoparticles. Thus, the electrochemical performance of Ni-doped SnO₂ nanospheres was significantly improved.

Key words: anode material, lithium-ion battery , Ni-doped SnO₂

苗纯杰, 胡志翔, 任兰兰, 郜子明, 董敬余, 李琦, 罗志刚, 陈志文. 镍掺杂SnO₂纳米微球锂离子电池负极材料的制备及其性能[J]. 上海大学学报(自然科学版), 2016, 22(2): 239-244.

MIAO Chunjie, HU Zhixiang, REN Lanlan, GAO Ziming, DONG Jingyu, LI Qi, LUO Zhigang, CHEN Zhiwen. Preparation and properties of Ni-doped SnO₂ nanospheres for lithium-ion battery anode materials[J]. Journal of Shanghai University（Natural Science Edition）, 2016, 22(2): 239-244.

参考文献

[1] Ji L W, Lin Z, Alcoutlabi M, et al. Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries [J]. Energy Environ Sci, 2011, 4: 2682-2699.

[2] Goodenough J B, Kim Y. Challenges for rechargeable Li batteries [J]. Chem Mater, 2010, 22: 587-603.
[3] Tarascon J M, Armand M. Issues and challenges facing rechargeable lithium batteries [J]. Nature, 2001, 414: 359-367.
[4] Scrosati B, Hassoun J, Sun Y K. Lithium-ion batteries: a look into the future [J]. Energy Environ Sci, 2011, 4: 3287-3295.
[5] Bruce P G, Scrosati B, Tarascon J M. Nanomaterials for rechargeable lithium batteries [J]. Angew Chem Int Ed, 2008, 47: 2930-2946.
[6] Arico A S, Bruce P, Scrosati B, et al. Nanostructured materials for advanced energy conversion and storage devices [J]. Nat Mater, 2005, 4: 366-377.
[7] Winter M, Besenhard J O, Spahr M E, et al. Insertion electrode materials for rechargeable lithium batteries [J]. Adv Mater, 1998, 10: 725-763.
[8] Kang K S, Meng Y S, Breger J, et al. Electrodes with high power and high capacity for rechargeable lithium batteries [J]. Science, 2006, 311: 977-980.
[9] Scosati B, Garche J. Lithium batteries: status, prospects and future [J]. J Power Sources, 2010, 195: 2419-2430.
[10] Wakihara M. Recent developments in lithium ion batteries [J]. Mater Sci Eng, 2001, R33: 109-134.
[11] Whittingham M S. Lithium batteries and cathode materials [J]. Chem Rev, 2004, 104(10): 4271-4302.
[12] Yang Y C. Status and future of the electric vehicles and their relevant power source materials [J]. Engineering Science, 2003, 5(12): 1-11.
[13] Deng D, Kim M G, Lee J Y, et al. Green energy storage materials: nanostructured TiO2 and Sn-based anodes for lithium-ion batteries [J]. Energy Environ Sci, 2009, 2(8): 818-837.
[14] Chen Z W, Pan D Y, Li Z, et al. Recent advances in tin dioxide materials: some developments in thin films, nanowires, and nanorods [J]. Chemical Reviews, 2014, 114(15): 7442-7486.
[15] Zhang X, Jiang B, Guo J X, et al. Large and stable reversible lithium-ion storages from mesoporous SnO₂ nanosheets with ultralong lifespan over 1 000 cycles [J]. J Power Sources, 2014, 268: 365-371.
[16] Liu X H, Zhang J, Si W P, et al. High-rate amorphous SnO₂ nanomembrane anodes for Li-ion batteries with a long cycling life [J]. Nanoscale, 2015, 7: 282-288.
[17] Li X H, He Y B, Miao C, et al. Carbon coated porous tin peroxide/carbon composite electrode for lithium-ion batteries with excellent electrochemical properties [J]. Carbon, 2015, 81: 739-747.
[18] Wang Y D, Djerdj I, Smarsly B, et al. Antimony-doped SnO₂ nanopowders with high crystallinity for lithium-ion battery electrode [J]. Chem Mater, 2009, 21(14): 3202-3209.
[19] Wang Y D, Chen T. Nonaqueous and template-free synthesis of Sb doped SnO₂ microspheres and their application to lithium-ion battery anode [J]. Electrochim Acta, 2009, 54(13): 3510-3515.
[20] El-Shinawi H, B¨ohm M, Leichtweiß T, et al. A simple synthesis of nanostructured Cuincorporated SnO₂ phases with improved cycle performance for lithium ion batteries [J]. Electrochem Commun, 2013, 36: 33-37.

[21] Ye X M, Zhang W J, Liu Q J, et al. One-step synthesis of Ni-doped SnO₂ nanospheres with enhanced lithium ion storage performance [J]. New J Chem, 2015, 39: 130-135.
[22] Chen Z W, Jiao Z, Wu M H, et al. Microstructure evolution of oxides and semiconductor thin films [J]. Progress in Materials Science, 2011, 56(7): 901-1029.
[23] Chen Z W, Pan D Y, Zhao B, et al. Insight on fractal assessment strategies for tin dioxide thin films [J]. ACS Nano, 2010, 4(2): 1202-1208.
[24] Chen Z W, Wu M H, Shek C H, et al. Multifunctional tin dioxide materials: advances in preparation strategies, microstructure, and performance [J]. Chemical Communications, 2015, 51(7): 1175-1184.
[25] Wang Z Y, Zhou L, Lou X W. Metal oxide hollow nanostructures for lithium-ion batteries [J]. Adv Mater, 2012, 24: 1903-1911.

镍掺杂SnO₂纳米微球锂离子电池负极材料的制备及其性能

Preparation and properties of Ni-doped SnO₂ nanospheres for lithium-ion battery anode materials

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