利用电导率法研究聚环氧琥珀酸的阻垢性能

doi:10.3969/j.issn.1007-2861.2016.01.006

Abstract

Abstract:

With the proposal and development of green chemistry, corrosion inhibitors tend to be environmental friendly. This paper explores the anti-scale performance of polyepoxysuccinic acid (PESA) on CaCO₃ scale, BaCO₃ scale, BaSO₄ scale at different temperatures and different concentrations with conductivity measurement. The results showed that the ability of anti-scale performance of PESA was good. With the increasing of its concentration, the anti-scale performances of PESA on CaCO₃ and BaSO₄ continued to strengthen, while BaCO₃ decreased after the concentration rised to 40 mg/L. With temperature
increasing, its anti-scale performance of CaCO₃ scale decreased, while BaCO₃ scale and BaSO₄ scale increased. Therefore, PESA is an excellent anti-scale inhibitor suitable for inhibiting CaCO₃, CaSO₄, and BaSO₄ at normal temperature of the factory. Moreover, the conductivity measurement is simple and fast, and it can be used in exploring the anti-scale performance of scale inhibitors.

Key words: BaCO₃ , BaSO₄, CaCO₃ , conductivity measurement , scale inhibition , polyepoxysuccinic acid (PESA)

ZHU Shuiping, CAO Liya, YIN Tiantian, WANG Chaoqun, LIU Xiaoyan. Anti-scale performance of polyepoxysuccinic acid with conductivity measurement[J]. Journal of Shanghai University（Natural Science Edition）, 2016, 22(2): 211-217.

References

[1] 谢红军. 油田集输管网结垢机理与防治技术研究[D]. 长春: 吉林大学, 2005: 38.
[2] Epstein N. Fouling in heat exchange [C]//Heat Transfer 1978-Proc 6th IHTC. 1978: 235-253.
[3] Salman M, Qabazard H, Moshfeghian M. Water scaling case studies in a Kuwaiti oil field [J]. Journal of Petroleum Science and Engineering, 2007, 55(1): 48-55.
[4] Nesic S, Solvi G T, Skjerve S. Comparison of rotating cylinder and loop methods for testing CO₂ corrosion inhibitors [J]. British Corrosion Journal, 1997, 32(4): 269-276.
[5] Patel S, Nicol A J. Developing a cooling water inhibitor with multifunctional deposit control properties [J]. Material Performance, 1996, 35(6): 41-49.

[6] 齐冬子. 敞开式循环冷却水系统的化学处理[M]. 北京: 化学工业出版社, 2006: 354-358.
[7] Brown M J, McDowell J F, Chang K T. Method of controlling scale formation in aqueous systems: US, 5147555 [P]. 1992-09-15.
[8] Benton W J, Koskan L. Inhibition of carbon dioxide corrosion of metals [J]. Journal of Cleaner Production, 1997, 5(3): 243.
[9] 王骁, 潘明, 王书海, 等. 聚环氧琥珀酸的合成及其阻垢性能[J]. 精细石油化工, 2013, 29(2): 37-39.
[10] 柳鑫华, 王文静, 赵新强, 等. 聚环氧琥珀酸及其衍生物的缓蚀性能及缓蚀机理[J]. 化工学报, 2015, 66(2): 695-702.
[11] 安良海, 牟占军, 武朝军, 等. 聚环氧琥珀酸的改性及其阻垢机理的研究[J]. 广东化工, 2014, 41(277): 25-26.
[12] Carter C G, Fan L D G, Fan J C, et al. Method of inhibiting corrosion of metals using polytartaric acids: EP, 0609590 [P]. 1994-09-06.
[13] 张丽华, 郑成松, 张严, 等. 环境友好型聚环氧琥珀酸的研究进展[J]. 工业水处理, 2010, 30(5): 5-8.
[14] 陈燕敏, 孙彩霞, 吴晋英, 等. 一种环保型阻垢缓蚀剂的性能[J]. 化工进展, 2014, 33(1): 204-208.
[15] 张文存, 王丽莉, 覃小焕. 环氧琥珀酸/丙烯酸/磺酸共聚物性能研究[J]. 应用化工, 2011, 40(9): 1529-1531.
[16] 邓爱云. 聚环氧琥珀酸的合成工艺优化与阻垢性能研究[J]. 清洗世界, 2013, 29(9): 11-15.
[17] 柳鑫华, 王晓禹, 赵新强, 等. 聚环氧琥珀酸盐生物对CaCO3垢的阻垢性能及缓蚀性能研究[J]. 高校化学工程学报, 2015, 29(4): 1016-1024.
[18] 刘爱华. TH-60硫酸钡阻垢剂的研制及应用[J]. 现代化工, 2015, 35(7): 60-61.
[19] 张小霓. 电导率法评定阻垢剂碳酸钙结晶动力学研究[D]. 武汉: 武汉大学, 2004: 21-29.
[20] 王颖. 聚环氧琥珀酸环氧化条件优化及阻垢剂性能评价方法研究[D]. 大连: 大连交通大学, 2009: 40-57.
[21] 宋业林. 化学水处理技术问答[M]. 北京: 中国石化出版社, 1995: 7.
[22] 刘振法, 张利辉, 吴运娟, 等. 聚天冬氨酸复配物的合成阻垢缓蚀性能和阻垢机理[J]. 精细石油化工, 2008, 25(6): 34-38.
[23] 李晓梅. 绿色阻垢剂聚环氧琥珀酸的阻垢机理的研究[J]. 广州化工, 2011, 39(7): 90-92．
[24] 刘振, 王丽玲. 冷指实验研究碳酸钡结垢规律[J]. 当代化工, 2014, 43(2): 194-197.
[25] 高英杰. 油田管道结垢影响因素及治理措施研究[D]. 大庆: 大庆石油学院, 2010: 6.
[26] 欧阳沐鲲, 苟文安, 艾小丰. 天东90井气水管线结垢原因分析[J]. 天然气勘探与开发, 2012, 35(2): 78-80.
[27] 何亮, 乔宇, 熊蓉春, 等. 环氧琥珀共聚物的制备及对硫酸钡的阻垢作用[J]. 北京化工大学学报, 2008, 35(2): 47-49.

[28] Moses M S, Saviour A U. Performance evaluation of poly(methacrylic acid) as corrosion inhibitor in the presence of iodide ions for mild steel in H2SO4 solution [J]. Journal of Adhesion Science and Technology, 2015, 29(11): 1060-1080.
[29] Gisha E L, Vikas M. Anti-corrosion behavior of layer by layer coatings of cross-linked chitosan and poly(vinyl butyral) on carbon steel [J]. Cellulose, 2015, 22: 3275-3290.
[30] 李文举, 武亚军, 常莹. 隧道盾构施工对临近桩基影响的数值模拟[J]. 上海大学学报: 自然科学版, 2010, 16(2): 210-215.

Anti-scale performance of polyepoxysuccinic acid with conductivity measurement

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 0

Recommended Articles

Metrics

Comments