镁铝复合金属氧化物负载钌纳米颗粒催化HMF 选择性氧化制 FDCA

doi:10.12066/j.issn.1007-2861.2064

Abstract

Abstract:

Ru nanoparticles supported on Mg-Al mixed metal oxide catalysts have been prepared via the hydrothermal-reduction method. The structure, morphology and composition of the catalysts have been systematically analyzed using X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), N₂ physisorption, CO₂-temperature programmed desorption（CO₂-TPD) and inductively coupled plasma-optical emission spectroscopy (ICP-OES). The characterization results show that the highly dispersed Ru nanoparticles benefit from the strongest alkalinity (142.81 mmol·g^-1 and the competitive specific surface area (97.0 m²·g^-1 of mixed metal oxides with n(Mg):n(Al)=5:1. The RO-5 catalyst with Ru loading of 2.0% can efficiently catalyze aerobic oxidation of 5-hydroxymethylfurfural (HMF), obtaining 100.0% HMF conversion and 99.0% 2,5-furandicarboxylic acid (FDCA) yield under the optimal reaction condition (120 ℃ , 2 MPa O₂, 5 h). According to the optimizing results, the reaction pathway for the conversion of HMF to FDCA is further confirmed for the formation of 2,5-diformylfuran,(DFF) and 5-formyl-2-furancarboxylic acid (FFCA) intermediates.

Key words: Mg-Al mixed oxide, Ru nanoparticles, oxidation, hydroxymethylfurfural, furandicarboxylic acid

CLC Number:

O643.3

WANG Lingchen, CHEN Chunlin, ZHANG Min. Ru nanoparticles supported on Mg-Al mixed metal oxide catalysts for selective oxidation of HMF methylfurfural into FDCA[J]. Journal of Shanghai University（Natural Science Edition）, 2020, 26(4): 552-561.

Figures/Tables 9

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References 21

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Ru nanoparticles supported on Mg-Al mixed metal oxide catalysts for selective oxidation of HMF methylfurfural into FDCA

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