一步水热法制备 Ni3S2 纳米空心球及其在超级电容器中的应用

doi:10.12066/j.issn.1007-2861.2008

Abstract

Abstract:

Ni₃S₂ nano hollow sphere was successfully synthesized with one-step hydrothermal method, in which nickel acetate and L-cysteine were used as nickel source and sulfur source, respectively. The morphology, composition, and phase structure of the as-prepared material were characterized by X-ray diffraction (XRD) spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The results showed that the as-prepared Ni₃S₂ was uniform hollow sphere with an average diameter of about 300 nm, and it has good dispersion. The Ni₃S₂ was pressed on the foam nickel to be a work electrode, and its performance of supercapacitor was investigated. The results suggested that the as-prepared Ni₃S₂ nano hollow sphere has excellent rate capability and cycle performance. This is due to its good stability and specific hollow spherical structure, which not only provides abundant active sites for electrode reaction, but also effectively shortens the transmission path of electrons and ions.

Key words: one-step hydrothermal method, Ni₃S₂, pseudocapacitance, supercapacitor

CLC Number:

TQ316.3

Xiaomeng JIANG, Yiyang HU, Chenghui LIN, Lingli CHENG, Zongxin PI, Zheng JIAO. One-step hydrothermal synthesis of Ni₃S₂ nano hollow sphere for high-performance supercapacitors[J]. Journal of Shanghai University（Natural Science Edition）, 2020, 26(1): 123-131.

Figures/Tables 6

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One-step hydrothermal synthesis of Ni₃S₂ nano hollow sphere for high-performance supercapacitors

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One-step hydrothermal synthesis of Ni3S2 nano hollow sphere for high-performance supercapacitors

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One-step hydrothermal synthesis of Ni₃S₂ nano hollow sphere for high-performance supercapacitors