电镀废水中有机多元LDHs 的原位合成

上海大学学报(自然科学版) ›› 2013, Vol. 19 ›› Issue (4): 358-362.

电镀废水中有机多元LDHs 的原位合成

阮秀秀, 徐楠楠, 林昱, 钱光人

(上海大学环境与化学工程学院, 上海200444)

出版日期:2013-08-27 发布日期:2013-08-27
通讯作者: 阮秀秀(1978—), 女, 博士, 研究方向为污染控制技术. E-mail: ruanxiuxiu@shu.edu.cn
作者简介:阮秀秀(1978—), 女, 博士, 研究方向为污染控制技术. E-mail: ruanxiuxiu@shu.edu.cn
基金资助:
国家自然科学基金资助项目(20907029); 上海市教委科研创新基金资助项目(10YZ07); 上海市重点学科建设资助项目(S30109)

In Situ Formation of Organic Multivariate Layer Double
Hydroxides in Electroplating Wastewater

RUAN Xiu-xiu, XU Nan-nan, LIN Yu, QIAN Guang-ren

(School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China)

Online:2013-08-27 Published:2013-08-27

摘要/Abstract

摘要： 利用层状双金属氢氧化物(layered double hydroxides, LDHs) 的合成原理, 提出原位合成LDH 处理电镀废水去除重金属的方法. 以十二烷基苯磺酸钠(sodium dodecyl benzene sulfonate, SDBS) 和十二烷基硫酸钠(sodium dodecyl sulfate, SDS) 作为有机阴离子插层剂, 原位合成有机多元LDH, 同时高效去除水体中的重金属,其中Fe³⁺, Al³⁺, Ni²⁺ 和Cu²⁺的去除率可达到94.9%.

关键词: 层状双金属氢氧化物, 电镀废水, 有机阴离子, 重金属

Abstract: This paper proposes a method of removing heavy metal ions from electroplating wastewater by layer double hydroxides (LDHs) synthesized in situ. The addition of sodium dodecyl benzene sulfonate (SDBS) and sodium dodecyl sulfate (SDS) as intercalated anions results in a good removal effect of the heavy metals. The rate of removal of Fe³⁺, Al³⁺, Ni²⁺ and Cu²⁺can reach 94.9%.

Key words: electroplating wastewater, heavy metals, layered double hydroxides (LDHs), organic anions

阮秀秀, 徐楠楠, 林昱, 钱光人. 电镀废水中有机多元LDHs 的原位合成[J]. 上海大学学报(自然科学版), 2013, 19(4): 358-362.

RUAN Xiu-xiu, XU Nan-nan, LIN Yu, QIAN Guang-ren. In Situ Formation of Organic Multivariate Layer Double
Hydroxides in Electroplating Wastewater[J]. Journal of Shanghai University（Natural Science Edition）, 2013, 19(4): 358-362.

参考文献

[1] 尚会来, 张雷, 张静蓉. 电镀废水处理技术展望[J]. 给

水排水, 2012, 38(S1): 260-263.

[2] 曾武. 电镀废水处理技术的研究和发展[J]. 广东化工,

2011, 38(4): 173-174.

[3] Cavani F, Trifiro F, Vaccari A. Hydrotalcite-type

anionic clays: preparation, properties and applications

[J]. Catalysis Today, 1991, 11(2): 173-301.

[4] Khan A, O’hare D. Intercalation chemistry of

layered double hydroxides: recent developments and

applications [J]. Journal of Materials Chemistry,

2002, 12(11): 3191-3198.

[5] Meyn M, Beneke K, Lagaly G. Anion-exchange

reactions of layered double hydroxides [J]. Inorganic

Chemistry, 1990, 29: 5201-5207.

[6] Carlino S. The intercalation of carboxylic acids into

layered double hydroxides: a critical evaluation and

review of the different methods [J]. Solid State Ionics,

1997, 98(12): 73-84.

[7] Badreddine M, Legrouri A, Barroug A. Ion

exchange of different phosphate ions into the zincaluminium-

chloride layered double hydroxides [J].

Materials Letters, 1999, 38(6): 391-395.

[8] Carrado K A, Kostapapa S A, Suib S L. Polymerization

of silicates in layered double hydroxides [J].

Solid State Ionics, 1988, 26(4): 77-86.

[9] Zhang Z J, Feng L G, Qiu F L, et al. Advances in

fire-retardant inorganic nanomaterials [J]. Progress in

Chemistry, 2004, 16(4): 508-515.
[10] Parthasarathy G, Kantam M, Choudary B, et

al. Pressure-induced phase transitions of hydrotalcite

by electrical resistivity, structural and thermal

studies [J]. Microporous and Mesoporous Materials,

2002, 56(2): 147-152.
[11] Ding W P, Gu G, Zhong W, et al. Enhanced photoluminescence

of C-60 incorporated into interlayers

of hydrotalcite [J]. Chemical Physics Letters, 1996,

262(3/4): 259-262.

[12] Padmasri A, Venugopal A, Kumra V S, et al. Role

of hydrotalcite precursors as supports for Pd catalysts

in hydrodechlorination of CCl2F2 [J]. Journal

of Molecular Catalysis A, 2004, 223(1/2): 329-337.

[13] Hussein M, Zainal Z, Yahaya A, et al. Synthesis

of layered-organic-inorganic nanohybrid material:

an organic dye, naphthol blue black in magnesiumaluminum

layered double hydroxide inorganic

lamella [J]. Materials Science and Engineering

B-Solid State Materials for Advanced Technology,

2002, 88(1): 98-102.

[14] Ulibarri M A, Pavlovic I, Barriga C, et al.

Adsorption of anionic species on hydrocite-like

compounds: effect of interlayer anion and crystallinity

[J]. Appl Clay Sci, 2001, 18(1/2): 17-27.

[15] Aisawa S, Hirahara H, Ishiyama K, et al. Sugaranionic

clay composite materials: intercalation of

pentoses into layered double hydroxide [J]. J Solid

State Chem, 2003, 174(2): 342-348.

[16] Devos D E, Wahlen J, Sels B F, et al. Peroxide

reactions with anion-exchanged layered double hydroxide

catalysts [J]. Synlett, 2002, 12(3): 367-380.
[17] Pavlovic I, Barriga C, Hermosin M C, et al.

Adsorption of acidic pesticides 2,4-D, clopyralid and

picloram on calcined hydrotalcite [J]. Applied Clay

Science, 2005, 30(2): 125-133.
[18] Crespo I, Barriga C, Rives V, et al. Intercalation

of iron hexacyano complexes in Zn,

Al-hydrotalcite [J]. Solid State Ionics, 1997, 101: 729-

735.

[19] Nong L P, Xiao C L, Jiang W. Azo dye removal

from aqueous solution by organic-inorganic hybrid

dodecanoic acid modified layered Mg-Al hydrotalcite

[J]. Korean J Chem Eng, 2011, 28(3): 933-938.

[20] Chuang Y H, Liu C H, Zou Y M, et al. Comparison

and characterization of chemical surfactants and biosurfactants

intercalated with layered double hydroxides

(LDHs) for removing naphthalene from contaminated

aqueous solutions [J]. Colloids and Surfaces

A: Physicochemical and Engineering Aspects, 2010,

366(1/2/3): 170-177.

[21] Boutahala M, Zaghouane-Boudiaf H, Tiar C,

et al. Treatment of 2,4,5-trichlorophenol by MgAl-

SDBS organo-layered double hydroxides: kinetic and

equilibrium studies [J]. Chemical Engineering

Journal, 2011, 173(1): 36-41.

[22] Rives V, Ulibarri M A. Layered double hydroxides

(LDHs) intercalated with metal coordination compounds

and oxometalates [J]. Coordination Chemistry

Reviews, 1999, 181(1): 61-120.

[23] Daniel L R , Agota D, Mark D S. Synthesis and

structure of a Cu4O4 cubane core complex from a

carboxylate ligand containing a strong - stacking

supramolecular synthon [J]. Inorganica Chimica

Acta, 2012, 386: 102-108.