上海大学学报(自然科学版)

• 材料科学与工程 •    下一篇

Zr-4合金薄板的织构与耐疖状腐蚀性能的关系

周邦新,姚美意,李强,夏爽,刘文庆   

  1. 上海大学 材料研究所,上海 200072
  • 收稿日期:2008-04-15 修回日期:1900-01-01 出版日期:2008-10-23 发布日期:2008-10-23
  • 通讯作者: 周邦新

Relationship between Nodular Corrosion Resistance and Textures for Zircaloy-4 Strip

ZHOU Bang-xin,YAO Mei-yi,LI Qiang,XIA Shuang,LIU Wen-qing   

  1. Institute of Materials, Shanghai University, Shanghai 200072, China
  • Received:2008-04-15 Revised:1900-01-01 Online:2008-10-23 Published:2008-10-23
  • Contact: ZHOU Bang-xin

摘要: 采用500 ℃/10.3 MPa过热蒸汽中腐蚀的方法,研究热处理及织构取向对Zr-4合金薄板耐疖状腐蚀性能的影响.样品在820 ℃-1 h加热快冷后,晶粒发生长大,得到了集中的 (0001)[11 20]和 (0001)[10 10]织构,这时耐腐蚀性能比较好的(0001)面基本平行于轧面,而样品四周的侧面是耐腐蚀性能较差的(11 20)和(10 10)面.样品经过这样热处理后,增加了Fe和Cr合金元素在 α-Zr中的过饱和固溶含量,提高了样品轧面的耐疖状腐蚀性能,但是样品的侧面上仍然会出现疖状腐蚀现象.耐疖状腐蚀性能的好坏与织构的晶体取向有关,只有当样品在1 000 ℃ β 相加热快冷,使 Fe和Cr合金元素在 α-Zr中的过饱和固溶含量进一步得到提高后,才能完全抑制疖状腐蚀现象.

关键词: Zr-4合金, 疖状腐蚀, 热处理, 织构

Abstract: The effects of heat treatments and textures on the nodular corrosion resistance of Zircaloy-4 strip have been investigated in superheated steam of 500 °Cand 10.3 MPa by autoclave tests. After heat treatment at 820 °C-1 h and fast cooling, concentrated textures with (0001) [11 20] and (0001) [10 10] orientations were obtained after grain growth, and the supersaturated solid solution of alloying elements of Fe and Cr in α-Zr matrix was increased simultaneously. (0001) planes with better corrosion resistance were mainly parallel to the rolling plane of the specimens, while (10 10) and (11 20) planes with worse corrosion resistance were on the side planes around the specimens. In this case, the nodular corrosion resistance on the rolling plane of the specimens was improved but the nodular corrosion phenomena could also appear on the side planes around the specimens. The nodular corrosion behavior was closely related to the texture orientations. And it could be completely suppressed when the supersaturated solid solution contents of Fe and Cr in α-Zr matrix were further increased after heat treatment in β phase.

Key words: heat treatments, nodular corrosion, textures, zircaloy-4

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