钴镁固溶体催化剂在混合导体透氧膜反应器中的应用

doi:10.3969/j.issn.1007-2861.2013.05.017

上海大学学报(自然科学版) ›› 2013, Vol. 13 ›› Issue (5): 534-539.doi: 10.3969/j.issn.1007-2861.2013.05.017

钴镁固溶体催化剂在混合导体透氧膜反应器中的应用

杨志彬1, 丁伟中2

1. 江苏科技大学张家港校区冶金与材料工程学院, 江苏张家港215600;
2. 上海大学上海市现代冶金与材料制备重点实验室, 上海200072

收稿日期:2012-05-06 出版日期:2013-10-28 发布日期:2013-10-28
通讯作者: 杨志彬(1981—), 男, 博士, 研究方向为冶金环境保护和资源回收利用. E-mail: zhibinyang@shu.edu.cn E-mail:zhibinyang@shu.edu.cn
基金资助:
国家自然科学基金资助项目(51304082); 江苏省自然科学基金资助项目(BK20130462); 江苏省高校自然科学基金资助项目(12KJB450001); 江苏科技大学人才引进基金资助项目(35271103); 江苏科技大学青年教师科研基金资助项目(112110108)

CoO/MgO Solid Solution Catalyst in Mixed Conductor Oxygen Permeable Membrane Reactor

YANG Zhi-bin1, DING Wei-zhong2

1. School of Metallurgy and Materials Engineering, Zhangjiagang Campus, Jiangsu University of
Science and Technology, Zhangjiagang 215600, Jiangsu, China;
2. Shanghai Key Laboratory of Modern Metallurgy and Material Processing, Shanghai University, Shanghai 200072, China

Received:2012-05-06 Online:2013-10-28 Published:2013-10-28
About author:杨志彬(1981—), 男, 博士, 研究方向为冶金环境保护和资源回收利用. E-mail: zhibinyang@shu.edu.cn

摘要/Abstract

摘要： 考察了CoO/MgO 固溶体催化剂在BaCo_0.7Fe_0.2Nb_0.1O_3−σ(BCFNO)透氧膜反应器内, 对焦炉煤气(coke oven gas, COG)中甲烷部分氧化重整(partial oxidation of methane, POM)的催化性能. 首先, 研究了CoO/MgO固溶体催化剂合成的工艺条件; 然后, 考察了焦炉煤气流量和空气流量对重整性能的影响, 并对比分析了NiO/MgO固溶体、CoO/MgO 固溶体催化剂和0.5%RuCoO/MgO 催化剂的重整性能. 实验结果表明, NiO/MgO 固溶体催化剂的重整性能优于CoO/MgO 固溶体催化剂. 但经Ru贵金属修饰后, CoO/MgO 固溶体催化剂的催化活性得到了很大提高.

关键词: 催化剂, 甲烷部分氧化重整, 焦炉煤气, 透氧膜, 氢气

Abstract: The catalytic reform performance of CoO/MgO solid solution catalyst for partial oxidation of methane (POM) in a coke oven gas (COG) in BaCo_0.7Fe_0.2Nb_0.1O_3−σ(BCFNO) oxygen permeable-membrane reactor was investigated. Synthesis technology of the CoO/MgO solid solution catalyst is analyzed. The effect of COG flow rate and air flow rate on the reform performance is discussed. For comparison, the reform performance of NiO/MgO, CoO/MgO and 0.5% RuCoO/MgO solid solution catalyst were studied. The results indicate that the NiO/MgO catalyst is superior to CoO/MgO solid solution catalyst, and the catalytic activity of CoO/MgO with the addition of Ru is greatly improved.

Key words: catalyst, coke oven gas (COG), oxygen permeation membrane, partial oxidation of methane (POM), hydrogen

中图分类号:

TQ 031.2

杨志彬1, 丁伟中2. 钴镁固溶体催化剂在混合导体透氧膜反应器中的应用[J]. 上海大学学报(自然科学版), 2013, 13(5): 534-539.

YANG Zhi-bin1, DING Wei-zhong2. CoO/MgO Solid Solution Catalyst in Mixed Conductor Oxygen Permeable Membrane Reactor[J]. Journal of Shanghai University（Natural Science Edition）, 2013, 13(5): 534-539.

参考文献

[1] Dov`? V G, Friedler F, Huisingh D, et al. Cleaner energy for sustainable future [J]. J Cleaner Production, 2009, 17(10): 889-895.

[2] Meng N, Michael K H L, Sumathy K, et al. Potential of renewable hydrogen production for energy supply in Hong Kong [J]. Int J Hydrogen Energy, 2006, 31: 1401-1412.

[3] Yao R M, Li B Z, Steemer K. Energy policy and standard for built environment in China [J]. Renewable Energy, 2005, 30: 1973-1988.

[4] Midilli A, Dincer I. Key strategies of hydrogen energy systems for sustainability [J]. Int J Hydrogen Energy, 2007, 32: 511-524.

[5] Forsberg C W. Future hydrogen markets for largescale hydrogen production systems [J]. Int J Hydrogen Energy, 2007, 32: 431-439.

[6] Thomas C E, James B D, Lomax F D, Jr., et al. Fuel options for the fuel cell vehicle: hydrogen, methanol or gasoline? [J]. Int J Hydrogen Energy, 2000, 25: 551-567.

[7] Freni S, Calogero G, Cavallaro S. Hydrogen production from methane through catalytic partial oxidation reactions [J]. J Power Sources, 2000, 87: 28-38.

[8] Li Z, Gao D, Chang L, et al. Coal-derived methanol for hydrogen vehicles in china: energy, environment and economic analysis for distributed reforming [J]. Chemical Engineering Research and Design, 2010, 88: 73-80.

[9] Joseck F, Wang M, Wu Y. Potential energy and greenhouse gas emission effects of hydrogen production from coke oven gas in U.S. steel mills [J]. Int J Hydrogen Energy, 2008, 33: 1445-1454.

[10] 徐匡迪. 中国钢铁工业的发展和技术创新[J]. 钢铁, 2008, 43(2): 1-4.

[11] 丁伟中, 沈培俊, 杨志彬, 等. 焦炉煤气在透氧膜反应器中的重整机理[J]. 上海大学学报: 自然科学版, 2011, 17(4): 529-534.

[12] Onozaki M, Watanabe K, Hashimoto T, et al. Hydrogen production by the partial oxidation and steam reforming of tar from hot coke oven gas [J]. Fuel, 2006, 85(2): 143-149.

[13] Ruckenstein E, Hu Y H. Carbon dioxide reforming of methane to synthesis gas over supported cobalt catalysts [J]. Appl Catal A: Gen, 2000, 204: 257-263.

[14] Ruckenstein E, Hu Y H. Combined catalytic partial oxidation and CO₂ reforming of methane over supported cobalt catalysts [J]. Catal Lett, 2001, 73(2/3/4): 99-105.

[15] Chen Y G, Tomishige K, Yokoyama K, et al. Promoting effect of Pt, Pd and Rh noble metals to the Ni_0.03Mg_0.97O solid solution catalysts for the reforming of CH4 with CO₂ [J]. Appl Catal A: Gen, 1997, 165: 335-347.

[16] Zhang Y W, Li Q, Shen P J, et al. Hydrogen amplification of coke oven gas by reforming of methane in a ceramic membrane reactor [J]. Int J Hydrogen Energy, 2008, 33: 3311-3319.

[17] 刘旭, 丁伟中, 沈培俊, 等. BaCoO₃ 基透氧材料的B位参杂优化[J]. 上海大学学报: 自然科学版, 2011, 17(1): 7-11.

[18] Yang Z B, Ding W Z, Zhang Y Y, et al. Catalytic partial oxidation of coke oven gas to syngas in an oxygen permeation membrane reactor combined with NiO/MgO catalyst [J]. Int J Hydrogen Energy, 2010, 35: 6239-6247.

[19] Yang Z B, Zhang Y Y, Ding W Z, et al. Hydrogen production from coke oven gas over LiNiREOx/-Al₂O₃ catalyst modified by rare earth metal in a membrane reactor [J]. J Natural Gas Chemistry, 2009, 18: 407-414.
[20] 杨志彬, 丁伟中. 透氧膜反应器内NiO/MgO 催化剂焦炉煤气重整反应途径[J]. 物理化学学报, 2012, 28(4): 935-941.

[21] Chouahary V R, Mondali K C, Choudhary T V. Methane reforming over a high temperature stable-NiCoMgO_x supported on zirconia–hafnia catalyst [J]. Chem Eng Jour, 2006, 121: 73-77.

[22] 王桂茹. 催化剂与催化剂作用[M]. 2 版. 大连: 大连理工大学出版社, 2006: 19-107.

[23] Choudhary V R, Raiput A M, Prabhakar B, et al. Partial oxidation of methane to CO and H₂ over nickel and/or cobalt containing ZrO₂, ThO2, UO₂, TiO₂ and SiO₂ catalysts [J]. Fule, 1998, 77: 1803-1807.

[24] Slagtern A, Swaanh M, Olsbye U, et al. Catalytic partial oxidation of methane over Ni-, Co- and Fe-based catalysts [J]. Catal Today, 1998, 46: 107-115.

[25] Swaan H M, Rouanet R, Widyananda P, et al. Partial oxidation of methane over nickel- and cobaltbased catalysts [J]. Stud Surf Scil Catal, 1997, 107: 447-453.

[26] Chen Y G, Tomishige K, Yokoyama K, et al. Promoting effect of Pt, Pd and Rh noble metals to the Ni_0.03Mg_0.97O solid solution catalysts for the reforming of CH₄ with CO₂ [J]. Appl Catal A: Gen, 1997, 165: 335-347.

[27] 徐东彦, 李文钊, 段洪敏, 等. Pt, Ru 和Pd 助剂对FT合成中Co/-Al₂O₃ 催化剂性能的影响[J]. 催化学报, 2005, 26(9): 780-784.

钴镁固溶体催化剂在混合导体透氧膜反应器中的应用

CoO/MgO Solid Solution Catalyst in Mixed Conductor Oxygen Permeable Membrane Reactor

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 11

编辑推荐

Metrics

本文评价

[1]	张辰, 廖珮懿, 石志彪, 孙俭, 王慧. "双溶剂"浸渍法制备Cu/ZnO/MCM-41催化剂及其在CO$_{\textbf{2}}$加氢中的催化性能[J]. 上海大学学报(自然科学版), 2019, 25(1): 109-119.
[2]	张宝华, 许丽瑛, 杞勇, 张慧颖, 吕晓庆. 碳基固体酸在生物柴油制备中的应用[J]. 上海大学学报(自然科学版), 2019, 25(1): 84-94.
[3]	张云龙, 浦娴娟, 程伶俐, 蒋永, 丁国际, 焦正. 真空加热和电子束辐照改性处理g-C₃N₄光催化剂[J]. 上海大学学报(自然科学版), 2017, 23(3): 452-463.
[4]	肖硕1,2, 高鹏2, 杨海艳2, 夏林2, 张建明2, 陈志文1, 王慧2. 层状Cu/ZnO/Al₂O₃催化剂的制备及其催化CO₂加氢合成甲醇的性能[J]. 上海大学学报(自然科学版), 2016, 22(2): 218-230.
[5]	耿淑华, 丁伟中, 郭曙强, 方展, 邹星礼, 鲁雄刚. 富氢气体直接还原铁矿石及其碳沉积行为[J]. 上海大学学报(自然科学版), 2015, 21(6): 749-756.
[6]	杨志彬1, 丁伟中2. 透氧膜反应器内NiO/MgO催化甲烷重整反应的途径[J]. 上海大学学报(自然科学版), 2013, 19(6): 572-578.
[7]	丁伟中,沈培俊,杨志彬,郭曙强,张玉文,汪学广,吴成章,鲁雄刚. 焦炉煤气在透氧膜反应器中的重整机理[J]. 上海大学学报(自然科学版), 2011, 17(4): 529-534.
[8]	邹星礼，鲁雄刚，李重河，钟庆东，丁伟中. 含钛复合矿选择性提取制备钛合金[J]. 上海大学学报(自然科学版), 2011, 17(1): 1-6.
[9]	刘旭，丁伟中，沈培俊，刘蛟，王海海，耿振. BaCoO₃基透氧材料的B位掺杂优化[J]. 上海大学学报(自然科学版), 2011, 17(1): 7-12.
[10]	黄少卿，丁伟中，沈培俊，杨志彬，周宇鼎，张玉文. BaCo_0.7Fe_0.2Nb_0.1O_3-δ钙钛矿型混合导体透氧膜的性能[J]. 上海大学学报(自然科学版), 2010, 16(1): 43-47.
[11]	〗张兵;王锦花;包伯荣;吴明红;吴君萍;郑卫芳 . 乙异羟肟酸辐解产生的氢气和一氧化碳的定性定量分析[J]. 上海大学学报(自然科学版), 2006, 12(4): 408-411 .