上海大学学报(自然科学版) ›› 2023, Vol. 29 ›› Issue (5): 842-858.doi: 10.12066/j.issn.1007-2861.2534

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碳化钛类 MXene 基材料在锂硫电池中的 应用研究进展 

刘广森,曹 俊,牛志强   

  1. 1. 山东理工大学 材料科学与工程学院, 山东 淄博 255000; 2. 南开大学 化学学院, 天津 300110
  • 收稿日期:2023-05-10 出版日期:2023-10-28 发布日期:2023-11-03
  • 通讯作者: 曹 俊 (1988—), 女, 副教授, 博士, 研究方向为碳材料、锂硫电池等. E-mail:juncao@sdut.edu.cn
  • 基金资助:
    国家自然科学基金资助项目 (21805171) 

Research progress in the application of MXene-based materials in lithium-sulfur batteries 

LIU Guangsen , CAO Jun , NIU Zhiqiang   

  1. 1. School of Materials Science and Engineering, Shandong University of Technology, Zibo 255000, Shandong, China; 2. School of Chemistry, Nankai University, Tianjin 300110, China
  • Received:2023-05-10 Online:2023-10-28 Published:2023-11-03

摘要:

作为储能器件的重要一员, 锂硫电池具有理论能量密度高、安全性好、成本低等优点,已成为目前最具前景的电源体系之一. 但锂硫电池充放电过程中多硫化物的穿梭效应使其在长期循环过程中的性能衰减. MXene 基材料具有优异的导电性和高比表面积, 对多硫化锂具有强化学吸附和催化转化能力, 能够有效避免多硫化物的穿梭效应, 从而提高锂硫电池的循环稳定性和倍率性能. 本工作简述了 MXene 基材料在锂硫电池中的应用优势, 总结了 MXene基复合材料在锂硫电池正极和隔膜中的应用研究现状, 归纳了 MXene 基材料对锂硫电池穿梭效应的影响, 最后, 展望了 MXene 基材料在锂硫电池领域的未来研究方向. 

关键词: 锂硫电池, MXene, 催化转化, 穿梭效应, 多硫化锂 

Abstract: Lithium–sulfur (Li–S) batteries have been considered as one of the most promising systems for next-generation high-energy rechargeable Li batteries owing to their high theoretical energy density, safe operation, cost effectiveness, and environmental friendliness. However, the shuttle effect of polysulfide in the charge-discharge process of Li–S battery degrades its performance in a long-term cycle. MXene-based materials possess excellent electrical conductivity and high specific surface area, which can effectively avoid the shuttle effect of polysulfide owing to their enhanced chemical adsorption capacity and catalytic conversion ability, thereby improving the cycle stability and magnification performance of Li–S batteries. This paper briefly describes the advantages of using MXene-based materials in Li–S batteries, summarises the application status of MXene-based composites in the positive electrodes and separators of Li–S batteries, and the influence of MXene-based materials on the shuttle effect of Li–S batteries. Finally, the future research direction of MXene-based materials in the field of Li–S batteries is prospected.

Key words: lithium–sulfur battery, MXene, catalytic conversion, shuttle e?ect, lithium polysul?de 

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