上海大学学报(自然科学版) ›› 2023, Vol. 29 ›› Issue (5): 900-914.doi: 10.12066/j.issn.1007-2861.2518

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水系锌离子电池电解液添加剂的研究进展

金鸣哲, 王 晨, 王 谈, 傅 婧   

  1. 同济大学 材料科学与工程学院, 上海 201804
  • 收稿日期:2023-04-03 出版日期:2023-10-28 发布日期:2023-11-03
  • 通讯作者: 傅 婧 (1988—), 女, 教授, 博士生导师, 博士, 研究方向为储锌材料及锌电池器件等. E-mail:jingfu@tongji.edu.cn
  • 基金资助:
    国家自然科学基金资助项目 (52001232); 上海市科技创新行动计划资助项目 (20ZR1460200)

Research progress on electrolyte additives for aqueous zinc ion batteries 

JIN Mingzhe, WANG Chen, WANG Tan, FU Jing   

  1. School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
  • Received:2023-04-03 Online:2023-10-28 Published:2023-11-03

摘要:

水系锌离子电池具有比容量高、安全性高和经济性好的特点, 是最具潜力的新一代电化学储能装置之一. 然而, 直接利用锌箔作为负极存在严重的锌枝晶和副反应等问题. 近年来,大部分研究主要聚焦于通过电解液添加剂来抑制枝晶的生长和减少副反应的发生, 以此获得高性能的水系锌离子电池. 首先, 介绍了水系锌离子电池概况; 然后, 系统总结了电解液添加剂抑制枝晶生长和副反应的机理; 最后, 对电解液添加剂策略在水系锌离子电池中的进一步发展提出了建议. 

关键词: 锌离子电池, 锌负极, 锌枝晶, 副反应, 电解液添加剂

Abstract: Aqueous Zn ion batteries are regarded as one of the most promising newgeneration electrochemical energy storage devices with a high specific capacity, high safety, and economic benefits. However, the direct utilization of Zn foils as metallic anodes is constrained by the problems of notorious Zn dendrite growth and severe corrosion. Recently, researchers have focused on inhibiting dendrite growth and reducing side reactions through electrolyte additives to obtain high-performance aqueous Zn ion batteries. Hence, this review first presents a general overview of aqueous Zn ion batteries and then systematically summarizes the mechanism of inhibition of dendrite growth and side reactions by electrolyte additives. Finally, suggestions for further development of electrolyte additive strategies in aqueous Zn ion batteries are presented. 

Key words: aqueous Zn ion batteries, Zn anode, Zn dendrite, side reaction, electrolyte additive 

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