Zinc acetylacetonate and iron acetylacetonate are used as sources of organic zinc and organic iron to successfully synthesize a new type of organism-based zinc-iron bimetallic material using the sol-gel method. This organic material has wonderful photocatalytic performance for degrading organic contaminants in water. Several techniques including X-ray diffraction (XRD), elemental analysis (EA), UV-Vis diffuse reflection spectrum(UVPC), inductively coupled plasma emission spectrometry (ICP-AES) and Fourier transform infrared spectroscopy (FT-IR) are used to analyze its structure and composition. It is found that this organism-based zinc-iron bimetallic material has a layered structure with a layer distance of about 8.74 nm. Contents of iron, zinc and carbon of the material are 8.39%, 25.73% and 39.64%, respectively. The material contains metal-oxygen bond and acetylacetone. Photo-catalytic activity and selectivity of the photocatalysts are evaluated by visible photo-catalytic degradation of Congo Red, Rhodamine B and aniline, respectively standing for anion organic, cationic organic and non-ionic organic. The photocatalytic degradation rate of anion organic Congo Red reaches 99 mg/g by the catalyst under sunshine, the cationic organic Rhodamine B reaches 36 mg/g, and the non-ionic organic aniline is only 32 mg/g. Therefore, its selective photocatalysis performance of anionic
dyes is the best.