A special TiCoSb composite target is designed with the convenience of adjusting film composition by varying the area of each element in the target. Using this target, polycrystalline TiCoSb thin films with single phase are successfully fabricated through direct current magnetron sputtering and rapid thermal annealing. The film structure and surface morphology of TiCoSb thin films are analyzed with XRD (X-ray diffraction) and AFM (atomic force microscopy). The electrical properties of the films are studied by Hall effect measurements. The results show that the TiCoSb thin films are uniform and dense, and have good adhension to the quartz glass substrate. The TiCoSb thin film annealed at 600 ºC for 5 min has better crystalline quality than those annealed at lower temperatures, having conductivity of 13.7 S/cm at room temperature.
ZHANG Min, QIN Juan, SUN Niu-yi, ZHANG Xiao-li, SHI Wei-min
. Preparation of Half-Heusler Compound Semiconductor TiCoSb Thin Film by Magnetron Sputtering[J]. Journal of Shanghai University, 2013
, 19(1)
: 71
-74
.
DOI: 10.3969/j.issn.1007-2861.2013.01.014
[1] Lin H, Wray L A, Xia Y Q, et al. Half-Heusler ternary compounds as new multifunctional experimental platforms for topological quantum phenomena [J]. Nature
Materials, 2010, 9: 546-549.
[2] Uher C, Yang J, Hu S, et al. Transport properties of pure and doped MNiSn (M=Zr, Hf) [J]. Physical Review B, 1999, 59: 8615-8621.
[3] Li S K, Shen Y H, Xie A J, et al. Rapid, roomtemperature synthesis of amorphous selenium/protein composites using Capsicum annuum L. extract [J].
Nanotechnology, 2007, 40(18): 401-405.
[4] Graf T, Felser C, Parkin S S P. Simple rules for the understanding of Heusler compounds [J]. Progress in Solid State Chemistry, 2011, 39: 1-50.
[5] Xia Y, Ponnambalam V, Bhattacharya S, et al. Electrical transport properties of TiCoSb half-Heusler phases that exhibit high resistivity [J]. Journal of
Physics: Condensed Matter, 2001, 13(1): 76-89.
[6] Stadnyk Y, Gorelenko Y, Tkachuk A, et al. Electric transport and magnetic properties of TiCo1−xNixSb solid solution [J]. Journal of Alloys
and Compounds, 2001, 329(1/2): 37-41.
[7] Kawaharada Y, Kurosaki K, Muta H, et al. High temperature thermoelectric properties of CoTiSb half-Heusler compounds [J]. Journal of Alloys and Compounds,
2004, 384: 308-311.
[8] Zhou M, Feng C, Chen L D, et al. Effects of partial substitution of Co by Ni on the high-temperature thermoelectric properties of TiCoSb-based half-Heusler
compounds [J]. Journal of Alloys and Compounds, 2005, 391: 194-197.
[9] 邹星礼, 鲁雄刚, 李重河, 等. 含钛复合矿选择性提取制备钛合金[J]. 上海大学学报: 自然科学版, 2011, 17(1): 1-5.
[10] Sekimoto T, Kurosaki K, Muta H, et al. Thermoelectric properties of Sn-doped TiCoSb half-Heusler
compounds [J]. Journal of Alloys and Compounds, 2006, 407(1/2): 326-329.
[11] 刘海强, 唐新峰, 王焜, 等. Ti1−x(Hf0.919Zr0.081)xNiSn的制备及热电性能[J]. 物理学报, 2006, 55(4): 2003-2007.
[12] Wang L L, Miao L, Wang Z Y, et al. Thermoelectric performance of half-Heusler compounds TiNiSn and TiCoSb [J]. Journal of Applied Physics, 2009, 105:013709.
[13] Xie J, Lee C K, Wang M F, et al. Characterization of heavily doped polysilicon films for CMOS-MEMS thermoelectric power generators [J]. Journal of Micromechanics
and Microengineering, 2009, 12(19): 125029.