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Key scientific and technological principles of hydrogen energy and fuel cells: challenges and prospects
Received date: 2021-03-30
Online published: 2021-05-28
Hydrogen is a clean and sustainable secondary energy source. Its industrial chain consists of production, storage, transportation, and usage. Fuel cells, the devices that are the most efficient in terms of hydrogen use, play a pivotal role in the hydrogen industrial chain. In this paper, several fundamental scientific technologies are discussed alongside the industrialisation of hydrogen and fuel cell production. The processes and technologies introduced in this paper include hydrogen production, hydrogen storage, hydrogen refuelling stations, fuel cell stacks, key materials, and the key component/system requirements for fuel cells stacks. In addition, potential challenges as well as recent developments of the hydrogen industrial chain in China are summarised and discussed. Furthermore, to facilitate further research and development of these critical processes, several directions for future research are proposed.
Key words: hydrogen energy; fuel cell; industrial chain
ZHU Mingyuan, LIU Wenbo, LIU Yang, QI Cai, LI Ying, LI Wenxian, ZHANG Jiujun . Key scientific and technological principles of hydrogen energy and fuel cells: challenges and prospects[J]. Journal of Shanghai University, 2021 , 27(3) : 411 -443 . DOI: 10.12066/j.issn.1007-2861.2300
| [1] | 邵志刚, 衣宝廉. 氢能与燃料电池发展现状及展望[J]. 中国科学院院刊, 2019,34(4):469-477. |
| [1] | Shao Z G, Yi B L. Developing trend and present status of hydrogen energy and fuel cell development[J]. Bulletin of the Chinese Academy of Sciences, 2019,34(4):469-477. |
| [2] | Takeichi N, Senoh H, Yokota T, et al. "Hybrid hydrogen storage vessel", a novel high-pressure hydrogen storage vessel combined with hydrogen storage material[J]. International Journal of Hydrogen Energy, 2003,28(9):1121-1129. |
| [3] | Tie D, Huang S, Wang J, et al. Hybrid energy storage devices: advanced electrode materials and matching principles[J]. Energy Storage Materials, 2019,21(19):22-40. |
| [4] | 衣宝廉. 燃料电池: 原理$\cdot$技术$\cdot$应用 [M]. 北京: 化学工业出版社, 2003. |
| [4] | Yi B L. Fuel cell: principle, technology and application [M]. Beijing: Chemical Industry Press, 2003. |
| [5] | Cano Z P, Banham D, Ye S, et al. Batteries and fuel cells for emerging electric vehicle markets[J]. Nature Energy, 2018,3(4):279-289. |
| [6] | 前瞻研究院. 氢能源行业产业链分析下游燃料电池起飞在即[J]. 电器工业, 2018(11):59-60. |
| [6] | Foresight Institute. Hydrogen energy industry chain analysis: downstream fuel cells take off soon[J]. China Electrical Equipment Industry, 2018(11):59-60. |
| [7] | 鄢丽娜. 氢源结构呈"以煤为主"特点 [N]. 中国煤炭报, 2019-09-17(3). |
| [7] | Yan L N. The structure of hydrogen source shows the characteristics of "mainly coal"[N]. China Coal Daily, 2019-09-17(3). |
| [8] | 宁翔. 我国工业制氢技术路线研究及展望[J]. 能源研究与利用, 2020 (1):52-55. |
| [8] | Ning X. Research and prospect of China's industrial hydrogen production technology route[J]. Energy Research & Utilization, 2020 (1):52-55. |
| [9] | Khan M A, Zhao H, Zou W, et al. Recent progresses in electrocatalysts for water electrolysis[J]. Electrochemical Energy Reviews, 2018,1(4):483-530. |
| [10] | Dau H, Limberg C, Reier T, et al. The mechanism of water oxidation: from electrolysis via homogeneous to biological catalysis[J]. Chem Cat Chem, 2010,2(7):724-761. |
| [11] | Duan S, Han G, Su Y, et al. Magnetic Co@g-C$_3$N$_4$ core-shells on rGO sheets for momentum transfer with catalytic activity toward continuous-flow hydrogen generation[J]. Langmuir, 2016,32(25):6272-6281. |
| [12] | Zhong D Y, Zhang G Y, Liu S, et al. Lithium storage in polymerized carbon nitride nanobells[J]. Applied Physics Letters, 2001,79(21):3500-3502. |
| [13] | 国家能源局. 2018年可再生能源并网运行情况介绍 [EB/OL]. [2019-01-28]. http://www.nea.gov.cn/2019-01/28/c_137780519.htm. |
| [14] | 中国水电. 中国水电发展的现状与展望 [EB/OL]. [2019-11-06]. http://www.hydropower.org.cn/showNewsDetail.asp?nsId=26317. |
| [15] | 中国电力企业联合会规划发展部. 2016—2017 年度全国电力供需形势分析预测报告[J]. 电器工业, 2017(2):11-16. |
| [15] | China Electricity Council Planning and Development Department. 2016—2017 national electricity supply and demand situation analysis and forecast report[J]. China Electrical Equipment Industry, 2017(2):11-16. |
| [16] | 中国政府网. 新疆连续 4 个月弃风率低于 20% "红线" [EB/OL]. [2018-11-29]. http://www.gov.cn/xinwen/2018-11/29/content_5344457.htm. |
| [17] | 刘坚, 钟财富. 我国氢能发展现状与前景展望[J]. 中国能源, 2019,41(2):32-36. |
| [17] | Liu J, Zhong C F. China hydrogen energy development status and prospects[J]. Energy of China, 2019,41(2):32-36. |
| [18] | 第一财经网. 去年弃核电量致企业损失近 200 亿元, 核企呼吁要保障核电消纳 [EB/OL]. [2017-03-11]. https://www.yicai.com/news/5244152.html. |
| [19] | Fujishima A, Honda K. Electrochemical photolysis of water at a semiconductor electrode[J]. Nature, 1972,238:37-38. |
| [20] | Greiner C J, Korp?s M, Holen A T. A Norwegian case study on the production of hydrogen from wind power[J]. International Journal of Hydrogen Energy, 2007,32:1500-1507. |
| [21] | Zou G, Jia X, Huang Z, et al. Cube-shaped porous carbon derived from MOF-5 as advanced material for sodium-ion batteries[J]. Electrochimica Acta, 2016,196:413-421. |
| [22] | Thomas A, Fischer A, Goettmann F, et al. Graphitic carbon nitride materials: variation of structure and morphology and their use as metal-free catalysts[J]. Journal of Materials Chemistry, 2008,18(41):4893-4908. |
| [23] | Ley M B, Meggouh M, Moury R, et al. Development of hydrogen storage tank systems based on complex metal hydrides[J]. Materials (Basel), 2015,8(9):5891-5921. |
| [24] | Von Helmolt R, Eberle U. Compressed and liquid hydrogen for fuel cell vehicles[M]// Kreysa G, Ota K I, Savinell K F. Encyclopedia of applied electrochemistry. New York: Springer, 2014: 245-253. |
| [25] | 吉力强, 赵英朋, 王凡, 等. 氢能技术现状及其在储能发电领域的应用[J]. 金属功能材料, 2019,26(6):23-31. |
| [25] | Ji L Q, Zhao Y P, Wang F, et al. Current situation of hydrogen energy technology and hydrogen energy storage applied in power generation[J]. Metallic Functional Materials, 2019,26(6):23-31. |
| [26] | 单彤文, 宋鹏飞, 李又武, 等. 制氢、储运和加注全产业链氢气成本分析[J]. 天然气化工, 2019,45:85-91. |
| [26] | Shan T W, Song P F, Li Y W, et al. Cost analysis of hydrogen from the perspective of the whole industrial chain of production, storage, transportation and refueling[J]. Natural Gas Chemical Industry, 2019,45:85-91. |
| [27] | Taljegard M, Brynolf S, Grahn M, et al. Cost-effective choices of marine fuels in a carbon-constrained world: results from a global energy model[J]. Environmental Science & Technology, 2014,48(21):12986-12993. |
| [28] | 郭秀盈, 李先明, 许壮, 等. 可再生能源电解制氢成本分析[J]. 储能科学与技术, 2020,9(3):688-695. |
| [28] | Guo X Y, Li X M, Xu Z, et al. Cost analysis of hydrogen production by electrolysis of renewable energy[J]. Energy Storage Science and Technology, 2020,9(3):688-695. |
| [29] | Lamb K E, Dolan M D, Kennedy D F. Ammonia for hydrogen storage: a review of catalytic ammonia decomposition and hydrogen separation and purification[J]. International Journal of Hydrogen Energy, 2019,44(7):3580-3593. |
| [30] | 孙大林. 车载储氢技术的发展与挑战[J]. 自然杂志, 2011,33(1):13-18. |
| [30] | Sun D L. Development and challenges of on-board hydrogen storage technology[J]. Chinese Journal of Nature, 2011,33(1):13-18. |
| [31] | 张志芸, 张国强, 刘艳秋, 等. 车载储氢技术研究现状及发展方向[J]. 油气储运, 2018,37(11):1207-1212. |
| [31] | Zhang Z Y, Zhang G Q, Liu Y Q, et al. Research status and development direction of on-board hydrogen storage technologies[J]. Oil & Gas Storage and Transportation, 2018,37(11):1207-1212. |
| [32] | 徐丽, 马光, 盛鹏, 等. 储氢技术综述及在氢储能中的应用展望[J]. 智能电网, 2016,4(2):166-171. |
| [32] | Xu L, Ma G, Sheng P, et al. Overview of hydrogen storage technologies and their application prospects in hydrogen-based energy storage[J]. Smart Grid, 2016,4(2):166-171. |
| [33] | 张媛媛, 赵静, 鲁锡兰, 等. 有机液体储氢材料的研究进展[J]. 化工进展, 2016,35:2869-2874. |
| [33] | Zhang Y Y, Zhao J, Lu X L, et al. Progress in liquid organic hydrogen storage materials[J]. Chemical Industry and Engineering Progress, 2016,35:2869-2874. |
| [34] | Sultan O, Show H. Study of automotive storage of hydrogen using recyclable liquid chemical carriers [EB/OL]. [2021-01-20]. https://www.osti.gov/biblio/500065. |
| [35] | Luo W, Campbell P G, Zakharov L N, et al. A single-component liquid-phase hydrogen storage material[J]. Journal of the American Chemical Society, 2011,133(48):19326-19329. |
| [36] | Chen H, Yang H, Omotoso O, et al. Contribution of hydrogen spillover to the hydrogenation of naphthalene over diluted Pt/RHO catalysts[J]. Applied Catalysis A: General, 2009,358(2):103-109. |
| [37] | Zhang D, Zhao J, Zhang Y, et al. Catalytic hydrogenation of phenanthrene over NiMo/Al$_2$O$_3$ catalysts as hydrogen storage intermediate[J]. International Journal of Hydrogen Energy, 2016,41(27):11675-11681. |
| [38] | Mehranfar A, Izadyar M, Esmaeili A A. Hydrogen storage by N-ethylcarbazol as a new liquid organic hydrogen carrier: a DFT study on the mechanism[J]. International Journal of Hydrogen Energy, 2015,40(17):5797-5806. |
| [39] | Wulf C, Zapp P. Assessment of system variations for hydrogen transport by liquid organic hydrogen carriers[J]. International Journal of Hydrogen Energy, 2018,43(26):11884-11895. |
| [40] | 高金良, 袁泽明, 尚宏伟, 等. 氢储存技术及其储能应用研究进展[J]. 金属功能材料, 2016,23:1-11. |
| [40] | Gao J L, Yuan Z M, Shang H W, et al. Research progress on storage technology and stored energy application of hydrogen[J]. Metallic Functional Materials, 2016,23:1-11. |
| [41] | 第一财经网. 市场机构: 全国已建成加氢站 61 座, 广东上海领跑[EB/OL]. [2020-01-06]. https://www.yicai.com/news/100458136.html. |
| [42] | 王周. 我国加氢站建设的发展前景探讨[J]. 城市燃气, 2015,488:28-32. |
| [42] | Wang Z. Discussion on the development prospect of hydrogen station in China[J]. Urban Gas, 2015,488:28-32. |
| [43] | Evtank. 国内建成运营加氢站 23 座, 预计 2020 年达 100 座 [EB/OL]. [2019-03-03]. http://www.itdcw.com/news/focus/03031009102019.html. |
| [44] | 赵月晶, 何广利, 缪平, 等. 35 MPa/70 MPa加氢机加注性能综合评价研究[J]. 储能科学与技术, 2020,9(3):702-706. |
| [44] | Zhao Y J, He G L, Miao P, et al. Study on comprehensive evaluation of 35 MPa/70 MPa hydrogen dispenser refueling performance[J]. Energy Storage Science and Technology, 2020,9(3):702-706. |
| [45] | 何广利, 杨康, 董文平, 等. 基于国产三型瓶的氢气加注技术开发[J]. 储能科学与技术, 2020,9(3):696-701. |
| [45] | He G L, Yang K, Dong W P, et al. Filling technology development for type Ⅲ hydrogen tank[J]. Energy Storage Science and Technology, 2020,9(3):696-701. |
| [46] | 辛妍. 国外燃料电池汽车发展: 性能、优势、挑战及应对[J]. 新经济导刊, 2015(8):38-43. |
| [46] | Xin Y. The development of foreign fuel cell vehicles: performance, advantages, challenges and countermeasures[J]. New Economy Weekly, 2015(8):38-43. |
| [47] | Suzuki T. Fuel cell stack technology of Toyota[J]. ECS Transactions, 2016,75:423-434. |
| [48] | 许德超, 赵子亮, 赵洪辉, 等. 国内燃料电池电堆技术进展综述[J]. 汽车文摘, 2020(1):8-13. |
| [48] | Xu D C, Zhao Z L, Zhao H H, et al. Progress review of fuel cell stack technologies in China[J]. Automotive Digest, 2020(1):8-13. |
| [49] | Tian N, Lu B A, Yang X D, et al. Rational design and synjournal of low-temperature fuel cell electrocatalysts[J]. Electrochemical Energy Reviews, 2018,1(1):54-83. |
| [50] | Wang R, Wang H, Luo F, et al. Core-shell-structured low-platinum electrocatalysts for fuel cell applications[J]. Electrochemical Energy Reviews, 2018,1(3):324-387. |
| [51] | 侯明, 邵志刚, 俞红梅, 等. 2019 年氢燃料电池研发热点回眸[J]. 科技导报, 2020,38(1):137-150. |
| [51] | Hou M, Shao Z G, Yu H M, et al. Looking back on the research and development hotspots of hydrogen fuel cells in 2019[J]. Science & Technology Review, 2020,38(1):137-150. |
| [52] | Wang X X, Hwang S, Pan Y T, et al. Ordered Pt$_3$Co intermetallic nanoparticles derived from metal-organic frameworks for oxygen reduction[J]. Nano Letters, 2018,18(7):4163-4171. |
| [53] | Sui P C, Zhu X, Djilali N. Modeling of PEM fuel cell catalyst layers: status and outlook[J]. Electrochemical Energy Reviews, 2019,2(3):428-466. |
| [54] | Hou J, Yang M, Ke C, et al. Platinum-group-metal catalysts for proton exchange membrane fuel cells: from catalyst design to electrode structure optimization[J]. Energy Chem, 2020,2(1):100023-100062. |
| [55] | Cao L, Yi B, Jiang S, et al. Preparation of monodispersed ultra-small PtCu alloy with remarkable electrocatalytic performance[J]. Scientia Sinica Chimica, 2017,47(5):683-691. |
| [56] | Banham D, Ye S. Current status and future development of catalyst materials and catalyst layers for proton exchange membrane fuel cells: an industrial perspective[J]. ACS Energy Letters, 2017,2(3):629-638. |
| [57] | 刘义鹤, 江洪. 燃料电池质子交换膜技术发展现状[J]. 新材料产业, 2018,5:27-30. |
| [57] | Liu Y H, Jiang H. Development status of fuel cell proton exchange membrane technology[J]. Advanced Materials Industry, 2018,5:27-30. |
| [58] | 刘以成, 徐国祥, 李俊, 等. 基于 TRIZ 理论的质子交换膜燃料电池膜材料研究进展分析[J]. 化工进展, 2014,33(12):3412-3417. |
| [58] | Liu Y C, Xu G X, Li J, et al. Analysis of progress of proton exchange membrane fuel cell membrane materials based on TRIZ theory[J]. Chemical Industry and Engineering Progress, 2014,33(12):3412-3417. |
| [59] | Nolte R, Ledjeff K, Bauer M, et al. Partially sulfonated poly (arylene ether sulfone): a versatile proton conducting membrane material for modern energy conversion technologies[J]. Journal of Membrane Science, 1993,83(2):211-220. |
| [60] | 侯明, 衣宝廉. 燃料电池的关键技术[J]. 科技导报, 2016,34(6):52-61. |
| [60] | Hou M, Yi B L. The key technology of fuel cell[J]. Science & Technology Review, 2016,34(6):52-61. |
| [61] | Zhao D, Yi B L, Zhang H M, et al. Cesium substituted 12-tungstophosphoric (Cs$_x$H$_{3-x}$PW$_{12}$O$_{40}$) loaded on ceria-degradation mitigation in polymer electrolyte membranes[J]. Journal of Power Sources, 2009,190(2):301-306. |
| [62] | Yao Y, Liu J, Liu W, et al. Vitamin E assisted polymer electrolyte fuel cells[J]. Energy & Environmental Science, 2014,7(10):3362-3370. |
| [63] | 张永明, 唐军柯, 袁望章. 燃料电池全氟磺酸质子交换膜研究进展[J]. 膜科学与技术, 2011,31(3):76-85. |
| [63] | Zhang Y M, Tang J K, Yuan W Z. Research progress of perfluorosulfonic acid proton exchange membrane for fuel cell[J]. Membrane Science and Technology, 2011,31(3):76-85. |
| [64] | Chen L, Lin R, Tang S, et al. Structural design of gas diffusion layer for proton exchange membrane fuel cell at varying humidification[J]. Journal of Power Sources, 2020,467:228355. |
| [65] | Park J, Oh H, Ha T, et al. A review of the gas diffusion layer in proton exchange membrane fuel cells: durability and degradation[J]. Applied Energy, 2015,155:866-880. |
| [66] | Sando Y. Research and development of fuel cell vehicles at Honda[J]. ECS Transactions, 2009,25(1):211-224. |
| [67] | 鲍鹏龙, 章道彪, 许思传, 等. 燃料电池车用空气压缩机发展现状及趋势[J]. 电源技术, 2016,40(8):1731-1734. |
| [67] | Bao P L, Zhang D B, Xu S C, et al. Development status and trend of air compressor in fuel cells vehicle[J]. Chinese Journal of Power Sources, 2016,40(8):1731-1734. |
| [68] | 李超, 刘振全, 王君. 燃料电池用无油润滑涡旋压缩机研究[J]. 润滑与密封, 2008,33(6):74-77. |
| [68] | Li C, Liu Z Q, Wang J. Research on oilless scroll compressor for fuel cell[J]. Lubrication Engineering, 2008,33(6):74-77. |
| [69] | 张毅. 燃料电池车用空气压缩机的发展现状及趋势分析[J]. 内燃机与配件, 2019(2):201-202. |
| [69] | Zhang Y. Development status and trend analysis of air compressors for fuel cell vehicles[J]. Internal Combustion Engine & Parts, 2019(2):201-202. |
| [70] | 黄友艳, 秦国良. 燃料电池用离心压缩机设计与数值模拟[J]. 风机技术, 2012(1):30-33. |
| [70] | Huang Y Y, Qin G L. Design and numerical simulation of centrifugal compressor for fuel cell[J]. Chinese Journal of Turbomachinery, 2012(1):30-33. |
| [71] | 郝冬, 朱凯, 张妍懿, 等. 燃料电池电动汽车专用空压机技术简析[J]. 汽车零部件, 2019(8):96-100. |
| [71] | Hao D, Zhu K, Zhang Y Y, et al. Brief introduction of technology of air compressor for fuel cell vehicles[J]. Automobile Parts, 2019(8):96-100. |
| [72] | Migliardini F, Capasso C, Corbo P. Optimization of hydrogen feeding procedure in PEM fuel cell systems for transportation[J]. International Journal of Hydrogen Energy, 2014,39(36):21746-21752. |
| [73] | Mohammed H, Al-Othman A, Nancarrow P, et al. Direct hydrocarbon fuel cells: a promising technology for improving energy efficiency[J]. Energy, 2019,172:207-219. |
| [74] | 张奥, 杨军, 吴桐, 等. 燃料电池车载氢气供给系统概述[J]. 船电技术, 2019,39(9):53-56. |
| [74] | Zhang A, Yang J, Wu T, et al. Application of hydrogen supply system for fuel cell vehicles[J]. Marine Electric & Electronic Engineering, 2019,39(9):53-56. |
| [75] | 上海情报服务平台. 燃料电池下游应用分析: 固定式领域相对成熟, 交通领域市场起飞在即 [EB/OL]. [2020-02-12]. http://www.china-nengyuan.com/exhibition/exhibition_news_151689.html. |
| [76] | Hart D, Lehner F, Jones S, et al. The fuel cell industry review 2018[M]. London: E4tech, 2019. |
| [77] | 中国氢能源网. Intelligent Energy斩获印度大订单 [EB/OL]. [2019-10-16]. . |
| [78] | 弗尔塞官网. 与上海移动国内首创燃料电池备用电源产品租赁服务商业模式 [EB/OL]. http://www.foresight-energy.cn/about/?3.html. |
| [79] | 高工氢电网. 为 5G 基站提供氢燃料发电系统, 高成绿能有何硬实力 [EB/OL]. [2020-04-20]. https://www.gg-fc.com/art-39969.html. |
| [80] | 中汽协会行业信息部. 2019 年汽车工业经济运行情况 [EB/OL]. [2020-01-13]. http://www.caam.org.cn/chn/4/cate_39/con_5228367.html. |
| [81] | 东方财富网. 氢能与燃料电池产业链现状及发展前景 [EB/OL]. [2019-05-13]. https://baijiahao.baidu.com/s?id=1633399188785165470&wfr=spider&for=pc. |
| [82] | 张立国, 宁国宝. 国内电动汽车发展综述[J]. 农业装备与车辆工程, 2006,184:3-6. |
| [82] | Zhang L G, Ning G B. Overview of domestic electric vehicle development[J]. Agricultural Equipment & Vehicle Engineering, 2006,184:3-6. |
| [83] | 中国质量报. 上汽大通又一款全新燃料电池车试装下线 [EB/OL]. [2019-03-06]. http://epaper.cqn.com.cn/article/474636.html. |
| [84] | 明海, 邱景义, 祝夏雨, 等. 军用便携式燃料电池技术发展[J]. 电池, 2017,47(6):362-365. |
| [84] | Ming H, Qiu J Y, Zhu X Y, et al. Development of military portable fuel cell technologies[J]. Battery Bimonthly, 2017,47(6):362-365. |
| [85] | Renau J, Sánchez F, Lozano A, et al. Analysis of the performance of a passive hybrid powerplant to power a lightweight unmanned aerial vehicle for a high altitude mission[J]. Journal of Power Sources, 2017,356:124-132. |
| [86] | Li X, Blinn K, Chen D, et al. In situ and surface-enhanced Raman spectroscopy study of electrode materials in solid oxide fuel cells[J]. Electrochemical Energy Reviews, 2018,1(3):433-459. |
| [87] | 余意. 频繁启停对质子交换膜燃料电池堆性能的影响[J]. 电池, 2015,45(2):74-77. |
| [87] | Yu Y. Performance decay of PEMFC stack after startup-shutdown cycles[J]. Battery Bimonthly, 2015,45(2):74-77. |
| [88] | 朱琴君, 祝俊宗. 国内液氢加氢站的发展与前景[J]. 煤气与热力, 2020,40(7):B15-B20. |
| [88] | Zhu Q J, Zhu J Z. Development and prospects of domestic liquid hydrogen refueling stations[J]. Gas & Heat, 2020,40(7):B15-B20. |
| [89] | 孔垂颖, 刘双虎, 门峰. 我国加氢站行业发展驱动力分析[J]. 汽车工业研究, 2020(2):20-23. |
| [89] | Kong C Y, Liu S H, Men F. Analysis of the driving forces for the development of China's hydrogen refueling station industry[J]. Auto Industry Research, 2020(2):20-23. |
| [90] | 马秋玉, 赵子亮, 赵洪辉, 等. 燃料电池行业标准现状综述[J]. 汽车文摘, 2020(1):15-17. |
| [90] | Ma Q Y, Zhao Z L, Zhao H H, et al. Overview on the present situation of fuel cell industry standards[J]. Automotive Digest, 2020(1):15-17. |
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