中文

Journal of Shanghai University >

2020 , Vol. 26 >Issue 1: 153 - 162

DOI: https://doi.org/10.12066/j.issn.1007-2861.2020

Research Articles

Fabrication and electrochemical properties of nitrogen doped MOF-derived carbon electrodes

Expand
  • School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China

Received date: 2018-03-29

  Online published: 2020-03-22

Fold

Abstract

The N-GQDs@cZIF-8 supercapacitor has been fabricated following a two-step process through combining N-doped graphene quantum dots (N-GQDs) with metal-organic framework-derived carbon material (cZIF-8). The N-GQDs@cZIF-8 electrode has a high specific capacitance of 246.6 F · g-1 at a current density of 0.5 A · g-1 in 1 mol/L H2SO4 electrolyte and has excellent cycle stability with 83.7% capacity retention over 8 000 cycles. At the same time, the N-GQDs@cZIF-8 supercapacitor achieves an excellent energy density of about 8.2 W · h · kg-1 at a power density of 104.5 W · kg-1. The outstanding electrochemical performance of the device owes much to its 3D structure with high specific surface area and high nitrogen doping level (10.13%) with high pseudo capacitive activity, which makes this electrode have potential application in the field of supercapacitors and lithium-ion batteries.

Key words： metal organic frameworks (MOF)-derived carbon material; N-doped graphene quantum dots (N-GQDs); supercapacitor

Cite this article

Xiang LIU, Ling CAO, Weiwei YAO, Zhen LI, Minghong WU . Fabrication and electrochemical properties of nitrogen doped MOF-derived carbon electrodes[J]. Journal of Shanghai University, 2020 , 26(1) : 153 -162 . DOI: 10.12066/j.issn.1007-2861.2020

References

[1] Salunkhe R R, Kamachi Y, Torad N L , et al. Fabrication of symmetric supercapacitors based on MOF-derived nanoporous carbons[J]. J Mater Chem A, 2014,2(46):19848-19854.
[2] Zhong S, Zhan C X, Cao D P . Zeolitic imidazolate framework-derived nitrogen-doped porous carbons as high performance supercapacitor electrode materials[J]. Carbon, 2015,85:51-59.
[3] Salunkhe R R, Kaneti Y V, Kim J , et al. Nanoarchitectures for metal-organic framework-derived nanoporous carbons toward supercapacitor applications[J]. Acc Chem Res, 2016,49(12):2796-2806.
[4] Liu W W, Feng Y Q, Yan X B , et al. Superior micro-supercapacitors based on graphene quantum dots[J]. Adv Funct Mater, 2013,23(33):4111-4122.
[5] Torad N L, Salunkhe R R, Li Y Q , et al. Electric double-layer capacitors based on highly graphitized nanoporous carbons derived from ZIF-67[J]. Chem Eur J, 2014,20(26):7895-7900.
[6] Pu J, Li C W, Tang L , et al. Impregnation assisted synjournal of 3D nitrogen-doped porous carbon with high capacitance[J]. Carbon, 2015,94:650-660.
[7] Chen L F, Zhang X D, Liang H W , et al. Synjournal of nitrogen-doped porous carbon nanofibers as an efficient electrode material for supercapacitors[J]. ACS Nano, 2012,6(8):7092-7102.
[8] Dong X W, Hu N T, Wei L M , et al. A new strategy to prepare N-doped holey graphene for high-volumetric supercapacitors[J]. J Mater Chem A, 2016,4(25):9739-9743.
[9] Du X S, Liu H Y, Mai Y W . Ultrafast synjournal of multifunctional N-doped graphene foam in an ethanol flame[J]. ACS Nano, 2016,10(1):453-462.
[10] Jiang M, Cao X P, Zhu D D , et al. Hierarchically porous N-doped carbon derived from ZIF-8 nanocomposites for electrochemical applications[J]. Electrochim Acta, 2016,196:699-707.
[11] Iamprasertkun P, Krittayavathananon A, Sawangphruk M . N-doped reduced graphene oxide aerogel coated on carboxyl-modified carbon fiber paper for high-performance ionic-liquid supercapacitors[J]. Carbon, 2016,102:455-461.
[12] Su F B, Poh C K, Chen J S , et al. Nitrogen-containing microporous carbon nanospheres with improved capacitive properties[J]. Energy Environ Sci, 2011,4(3):717-724.
[13] Lai F L, Miao Y E, Zuo L , et al. Biomass-derived nitrogen-doped carbon nanofiber network: a facile template for decoration of ultrathin nickel-cobalt layered double hydroxide nanosheets as high-performance asymmetric supercapacitor electrode[J]. Small, 2016,12(24):3235-3244.
[14] Lee Y H, Chang K H, Hu C C . Differentiate the pseudocapacitance and double-layer capacitance contributions for nitrogen-doped reduced graphene oxide in acidic and alkaline electrolytes[J]. Journal of Power Sources, 2013,227:300-308.
[15] Liu Y Z, Li G R, Guo Y , et al. Flexible and binder-free hierarchical porous carbon film for supercapacitor electrodes derived from MOFs/CNT[J]. ACS Applied Materials & Interfaces, 2017,9(16):14043-14050.
Options
Outlines

/

〈 〉