碳基固体酸在生物柴油制备中的应用

doi:10.12066/j.issn.1007-2861.1895

Abstract

Abstract:

Optimization of the esterification reaction condition was investigated by orthogonal experiments using carbon-based acid as catalyst prepared by p-toluenesulfonic acid and starch. In a pilot scale study, biodiesels were produced from waste oil in an acid-base cascade process. It was found that the carbon-based solid catalysts displayed high activity under an optimization condition, which was 60 ${^\circ}$C for 7 h, with 30% methanol and 4% catalysts of waste oil. The acid value of waste oil can be reduced to 1.2 mg KOH/g after esterification. It was concluded that the carbon-based solid acid catalysts were proper to be used in biodiesel production from waste oil of acid-base process instead of liquid acid catalysts.

Key words: starch, carbon-based solid acid, catalyst, waste oil, biodiesel

CLC Number:

TQ426.94

ZHANG Baohua, XU Liying, QI Yong, ZHANG Huiying, Lü Xiaoqing. Application of carbon-based solid acid catalysts in preparing biodiesels[J]. Journal of Shanghai University（Natural Science Edition）, 2019, 25(1): 84-94.

Figures/Tables 9

Fig. 1

Fig. 2

Fig. 3

Table 1

Fig. 4

Table 2

Table 3

Fig. 5

Table 4

References 22

[1]	王常文, 崔方方, 宋宇 , 等. 生物柴油的研究现状及发展前景[J]. 中国油脂, 2014,39(5):44-48.
[2]	Doradom P, Ballesterosb E, Arnale J M . Exhaust emissions from a diesel engine fueled with transesterified waste olive oil[J]. Fuel, 2003,82(11):1311-1315.
[3]	McCormick R L, Graboski M S, Alleman T L , et al. Impact of biodiesel source material and chemical structure on emissions of criteria pollutants from a heavy-duty engine[J]. Environmental Science and Technology, 2001,35(9):1742-1747.
[4]	葛蕴珊, 李晓, 吴思进 , 等. 餐饮废油制生物柴油的排放特性研究[J]. 北京理工大学学报, 2004,24(4):290-294.
[5]	黄世丰, 陈国, 方柏山 . 酯化及转酯化法制备生物柴油过程中催化剂的研究进展[J]. 化工进展, 2008,27(4):508-514.
[6]	张菊波, 韩秋菊, 范明明 , 等. 酯交换法制备生物柴油反应机理的研究进展[J]. 石油化工, 2012,41(9):1081-1086.
[7]	丁灵, 王延臻, 刘晨光 . 碱催化油脂酯交换反应研究进展[J]. 工业催化, 2006,14(1):15-17.
[8]	吕亮, 段雪, 李峰 , 等. 固体碱催化剂酯交换反应的研究[J]. 中国皮革, 2002,31(17):25-28.
[9]	Chen G, Fang B S . Preparation of solid acid catalyst from glucose-starch mixture for biodiesel production[J]. Bioresource Technology, 2011,102(3):2635-2640.
[10]	Crabbe E, Nolasco H, Kobayashi G , et al. Biodiesel production from crude palm oil and evaluation of butanol extraction and fuel properties[J]. Process Biochemistry, 2001,37(1):65-71.
[11]	Wu M B, Wang Y, Wang D , et al. SO$_{3}$H-modified petroleum coke derived porous carbon as an efficient solid acid catalyst for esterification of oleic acid[J]. Journal of Porous Materials, 2016,23(1):263-271.
[12]	Park J Y, Kim D K, Lee J S . Esterification of free fatty acids using water-tolerable Amberlyst as a heterogeneous catalyst[J]. Bioresource Technology, 2010,101(1):62-65.
[13]	王婷, 蔡文静, 刘熠斌 , 等. 固体酸催化剂制备生物柴油研究进展[J]. 化工进展, 2016,35(9):2783-2789.
[14]	王丹君, 郑化安, 张生军 , 等. 固体酸催化剂在酯化反应中的研究进展[J]. 山东化工, 2016,45(3):41-46.
[15]	孙恩浩, 刘通, 闫义彬 , 等. S$_{2}$O$_{4}$/M$_{x}$O$_{y}$ 型固体超强酸催化剂改性研究进展[J]. 工业催化, 2016,24(5):13-18.
[16]	任立国, 余济玮, 张晓丽 , 等. 新型碳基固体酸催化剂在酯化反应中的催化性能研究[J]. 石油炼制与化工, 2009,40(5):38-41.
[17]	刘士涛, 刘玉环, 阮榕生 , 等. 固体碱催化剂生产生物柴油的研究进展[J]. 现代化工, 2013,33(7):30-33.
[18]	韦玉丹, 张树国, 李贵生 , 等. 近十年固体超强碱催化剂的研究进展[J]. 催化学报, 2011,32(6):891-898.
[19]	Boz N, Degirmenbasi N, Dilhan M K . Conversion of biomass to fuel: transesterification of vegetable oil to biodiesel using KF loaded nano-$\gamma $-Al$_{2}$O$_{3}$ as catalyst[J]. Applied Catalysis B: Environmental, 2009,89(3/4):590-596.
[20]	张家骞, 喻红梅, 华平 , 等. 碳基固体酸催化剂的制备及其催化酯化性能研究[J]. 功能材料, 2015,46(8):31-35.
[21]	张爱华, 肖志红, 张良波 , 等. 固体酸催化富烃燃料-----甲醇酯化反应[J]. 石油化工, 2014,43(9):1020-1023.
[22]	Zhang B H, Ren J W, Liu X H , et al. Novel sulfonated carbonaceous materials from $p$-toluenesulfonic acid/glucose as a high-performance solid-acid catalyst[J]. Catalysis Communications, 2010,7(11):629-632.

Application of carbon-based solid acid catalysts in preparing biodiesels

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 9

References 22

Related Articles 6

Recommended Articles

Metrics

Comments

[1]	ZHANG Chen, LIAO Peiyi, SHI Zhibiao, SUN Jian, WANG Hui. Preparation of Cu/ZnO/MCM-41 catalyst with double-solvent impregnation method and catalytic performance in methanol synthesis by CO$_{\textbf{2}}$ hydrogenation [J]. Journal of Shanghai University（Natural Science Edition）, 2019, 25(1): 109-119.
[2]	ZHANG Yunlong, PU Xianjuan, CHENG Lingli, JIANG Yong, DING Guoji, JIAO Zheng. Enhanced g-C₃N₄ photocatalyst with vacuum heating and electron beam irradiation [J]. Journal of Shanghai University（Natural Science Edition）, 2017, 23(3): 452-463.
[3]	XIAO Shuo1,2, GAO Peng2, YANG Haiyan2, XIA Lin2, ZHANG Jianming2, CHEN Zhiwen1, WANG Hui2. Preparation of layered Cu/ZnO/Al₂O₃ catalyst and its catalytic performance for CO₂ hydrogenation to methanol [J]. Journal of Shanghai University（Natural Science Edition）, 2016, 22(2): 218-230.
[4]	YANG Zhi-bin1, DING Wei-zhong2. CoO/MgO Solid Solution Catalyst in Mixed Conductor Oxygen Permeable Membrane Reactor [J]. Journal of Shanghai University（Natural Science Edition）, 2013, 13(5): 534-539.
[5]	DING Wei-zhong,SHEN Pei-jun,YANG Zhi-bin,GUO Shu-qiang,ZHANG Yu-wen,WANG Xue-guang,WU Cheng-zhang,LU Xiong-gang. Reforming Mechanism of Coke Oven Gas in Oxygen Permeable Membrane Reactor [J]. Journal of Shanghai University（Natural Science Edition）, 2011, 17(4): 529-534.
[6]	GUO Xiao-Ya-1, CI Bing-Bing-1, YU Jing-Lu-1, LI Shou-Guang-1, HU Wei-1, TANG Xiang-Hui-2. Synthesis of Glyceryol Triacetate by Glycerol Extracted from Waste Water [J]. Journal of Shanghai University（Natural Science Edition）, 2010, 16(5): 522-525.