碳基固体酸在生物柴油制备中的应用

doi:10.12066/j.issn.1007-2861.1895

Abstract

Abstract:

Optimization of the esterification reaction condition was investigated by orthogonal experiments using carbon-based acid as catalyst prepared by p-toluenesulfonic acid and starch. In a pilot scale study, biodiesels were produced from waste oil in an acid-base cascade process. It was found that the carbon-based solid catalysts displayed high activity under an optimization condition, which was 60 ${^\circ}$C for 7 h, with 30% methanol and 4% catalysts of waste oil. The acid value of waste oil can be reduced to 1.2 mg KOH/g after esterification. It was concluded that the carbon-based solid acid catalysts were proper to be used in biodiesel production from waste oil of acid-base process instead of liquid acid catalysts.

Key words: starch, carbon-based solid acid, catalyst, waste oil, biodiesel

CLC Number:

TQ426.94

ZHANG Baohua, XU Liying, QI Yong, ZHANG Huiying, Lü Xiaoqing. Application of carbon-based solid acid catalysts in preparing biodiesels[J]. Journal of Shanghai University（Natural Science Edition）, 2019, 25(1): 84-94.

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URL: https://www.journal.shu.edu.cn/EN/10.12066/j.issn.1007-2861.1895

https://www.journal.shu.edu.cn/EN/Y2019/V25/I1/84

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Application of carbon-based solid acid catalysts in preparing biodiesels

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