温度对氯化胆碱/多元醇型低共熔溶剂物性的影响

doi:10.3969/j.issn.1007-2861.2014.03.005

Abstract

Abstract: Four kinds of deep eutectic solvents (DESs) based on choline chloride and polyols were prepared. Density, viscosity and conductivity of the four DESs were measured as functions of temperature in the range of 303～343 K. The results show that the densities of the four DESs sare linearly dependent on temperature. Viscosities decrease with increasing temperature, and conductivities increase rapidly with increasing temperature,both obeying the Arrhenius exponential law. The activation energy of viscosity and conductivity were calculated with the Arrhenius formula. The electrochemical windows of the four DESs were also tested by using cyclic voltammetry at 333 K.

Key words: conductivity, deep eutectic solvent, density, electrochemical window, viscosity

CLC Number:

O 646.54

HE Zhi-Jiang, YAN Gao, WANG Qi-Hu, YU Xin-Lou, WU Kai, XU Yi. Effect of temperature on physic-chemical properties of deep eutectic solvent based on choline chloride and polyols[J]. Journal of Shanghai University（Natural Science Edition）, 2015, 21(03): 384-392.

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Effect of temperature on physic-chemical properties of deep eutectic solvent based on choline chloride and polyols

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