钴镁固溶体催化剂在混合导体透氧膜反应器中的应用

doi:10.3969/j.issn.1007-2861.2013.05.017

Abstract

Abstract: The catalytic reform performance of CoO/MgO solid solution catalyst for partial oxidation of methane (POM) in a coke oven gas (COG) in BaCo_0.7Fe_0.2Nb_0.1O_3−σ(BCFNO) oxygen permeable-membrane reactor was investigated. Synthesis technology of the CoO/MgO solid solution catalyst is analyzed. The effect of COG flow rate and air flow rate on the reform performance is discussed. For comparison, the reform performance of NiO/MgO, CoO/MgO and 0.5% RuCoO/MgO solid solution catalyst were studied. The results indicate that the NiO/MgO catalyst is superior to CoO/MgO solid solution catalyst, and the catalytic activity of CoO/MgO with the addition of Ru is greatly improved.

Key words: catalyst, coke oven gas (COG), oxygen permeation membrane, partial oxidation of methane (POM), hydrogen

CLC Number:

TQ 031.2

YANG Zhi-bin1, DING Wei-zhong2. CoO/MgO Solid Solution Catalyst in Mixed Conductor Oxygen Permeable Membrane Reactor[J]. Journal of Shanghai University（Natural Science Edition）, 2013, 13(5): 534-539.

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CoO/MgO Solid Solution Catalyst in Mixed Conductor Oxygen Permeable Membrane Reactor

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