Journal of Shanghai University(Natural Science Edition) ›› 2010, Vol. 16 ›› Issue (4): 423-428.

• Material Science • Previous Articles     Next Articles

Effect of Coupling Agents Mixing with Silica on Vulcanization Characteristics and Mechanical Properties of Natural Rubber Vulcanizate

WU Rong-yi1,SHI Li-yi 2,3,ZHU Wei-de1,LU Huo-gen4   

  1. (1. School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China;
    2. College of Sciences, Shanghai University, Shanghai 200444, China;
    3. Research Centre of Nanoscience and Nanotechnology, Shanghai University, Shanghai 200444, China;
    4. School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China)
  • Received:2009-03-24 Online:2010-08-30 Published:2010-08-30

Abstract:

This article analyzes the application of four different coupling agents in silicafilled natural rubber (NR) namely KH-560, KH-570, Si-69 and C800, and discusses effects of different types and dosages of coupling agents on the properties of NR vulcanizates. The results show that curing time is shortened with dosage increase of coupling agents, among which coupling agent C800 mixing with silica enhances antiscorch property of NR vulcanizates and improves its processability. Mechanical properties of NR vulcanizates are enhanced in varied degrees by different coupling agents, among which KH-560 mixing with silica is most effective in enhancing NR vulcanizate, and the optimum loading is 2 phr.

Key words: coupling agent; silica; natural rubber (NR); vulcanization characteristics

CLC Number: