基于 FTIR 对水库沉积物中 TOC, TN 和 BSi 含量的快速测定

doi:10.12066/j.issn.1007-2861.2290

上海大学学报(自然科学版) ›› 2021, Vol. 27 ›› Issue (2): 227-235.doi: 10.12066/j.issn.1007-2861.2290

• 中国西南地区河流拦截对物质循环的影响及生态意义 • 上一篇下一篇

基于 FTIR 对水库沉积物中 TOC, TN 和 BSi 含量的快速测定

梅林, 范新怡, 岳一鸿, 刘留, 褚永胜, 汪福顺()

上海大学环境与化学工程学院, 上海 200444

收稿日期:2021-03-10 出版日期:2021-04-30 发布日期:2021-04-27
通讯作者: 汪福顺 E-mail:fswang@shu.edu.cn
作者简介:汪福顺(1976—), 男, 教授, 博士生导师, 博士, 研究方向为水库运行与温室气体释放生源要素、水坝拦截效应、水生生态系统演变. E-mail:fswang@shu.edu.cn
基金资助:
国家重点研发计划资助项目(2016YFA0601003);上海市科学技术发展基金资助项目(19010500100)

Rapid determination of TOC, TN and BSi content in reservoir sediments based FTIR

MEI Lin, FAN Xinyi, YUE Yihong, LIU Liu, CHU Yongsheng, WANG Fushun()

School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China

Received:2021-03-10 Online:2021-04-30 Published:2021-04-27
Contact: WANG Fushun E-mail:fswang@shu.edu.cn

摘要/Abstract

摘要：

利用傅里叶变换红外光谱(Fourier transform infrared spectroscopy, FTIR)分析了中国西南喀斯特地区岩滩(Yantan, YT)水库中的沉积物, 探讨了基于 FTIR 的沉积物总有机碳(total organic carbon, TOC)、总氮(total nitrogen, TN)和生物硅(biogenic silica, BSi)含量的快速分析方法. 采用偏最小二乘回归(partial least squares regression, PLSR)方法, 分别建立了 TOC/TN/BSi 含量的 FTIR 预测模型, 并根据实测数据对这一预测模型的预测精度进行了验证. 结果表明: 该方法可有效提取水库沉积物中的地球化学信息, 应用于高分辨率古环境变化的研究; 需要样品量少, 预处理过程简单, 并因其快速和经济的特点, 在测定大量沉积物样品时具有极大的优势.

关键词: 傅里叶变换红外光谱, 总有机碳, 总氮, 生物硅, 水库沉积物

Abstract:

Fourier transform infrared spectroscopy (FTIR) was used to analyse sediments from Yantan (YT) Reservoir in Southwest China, and a rapid analysis method for sediment total organic carbon (TOC), total nitrogen (TN) and biogenic silica (BSi) content based on FTIR was investigated. The FTIR prediction models of TOC/TN/BSi contents were established by partial least squares regression (PLSR) method, respectively. The prediction accuracy of this model was verified based on the measured data. This method can effectively extract geochemical information from reservoir sediments and can be applied to the study of high-resolution paleoenvironmental changes. The method requires small sample size and simple pretreatment process to rapidly and economically determine the content of various sediments components, which is of great advantage in determining a large number of sediment samples.

Key words: Fourier transform infrared spectroscopy (FTIR), total organic carbon (TOC), total nitrogen (TN), biogenic silica (BSi), reservoir sediment

中图分类号:

X142

梅林, 范新怡, 岳一鸿, 刘留, 褚永胜, 汪福顺. 基于 FTIR 对水库沉积物中 TOC, TN 和 BSi 含量的快速测定[J]. 上海大学学报(自然科学版), 2021, 27(2): 227-235.

MEI Lin, FAN Xinyi, YUE Yihong, LIU Liu, CHU Yongsheng, WANG Fushun. Rapid determination of TOC, TN and BSi content in reservoir sediments based FTIR[J]. Journal of Shanghai University（Natural Science Edition）, 2021, 27(2): 227-235.

图/表 5

参考文献 34

[1]	Liu X, Colman S M, Brown E T, et al. Estimation of carbonate, total organic carbon, and biogenic silica content by FTIR and XRF techniques in lacustrine sediments[J]. Journal of Paleolimnology, 2013,50(3):387-398.
[2]	Peck J A, King J W, Colman S M, et al. A rock magnetic record from Lake Baikal, Siberia: evidence for late quaternary climate-change[J]. Earth and Planetary Science Letters, 1994,128(3/4):703.
[3]	Colman S M, Peck J A, Karabanov E B, et al. Continental climate response to orbital forcing from biogenic silica records in Lake Baikal[J]. Nature, 1995,378(6559):769-771.
[4]	Williams D F, Peck J, Karabanov E B, et al. Lake Baikal record of continental climate response to orbital insolation during the past 5 million years[J]. Science, 1997,278:1114-1117
[5]	Cohen A, Soreghan M, Scholtz C. Estimating the age of formation of lakes: an example from Lake Tanganyika[J]. Geology, 1993,21:511-514.
[6]	Tiercelin J J, Lezzar K E. A 300 million years history of Rift Lakes in Central and East Africa: an updated broad review[M]// Advances in global change research. Berlin: Springer Netherlands, 2002: 3-60.
[7]	Fuji N. Palaeovegetation and palaeoclimate changes around Lake Biwa, Japan during the last CA 3 million years[J]. Quaternary Science Reviews, 1998,7(1):21-28.
[8]	Allen D T, Palen E J, Haimov M I, et al. Fourier transform infrared spectroscopy of aerosol collected in a low pressure impactor (LPI/FTIR): method development and field calibration[J]. Aerosol Science $\&$ Technology, 2016,21(4):325-342.
[9]	Alvarado A, Tuazon E C, Aschmann S M, et al. Products and mechanisms of the gas-phase reactions of OH radicals and O$_3$ with 2-methyl-3-buten-2-ol[J]. Atmospheric Environment, 1999,33(18):2893-2905.
[10]	Coury C, Dillner A M. A method to quantify organic functional groups and inorganic compounds in ambient aerosols using attenuated total reflectance FTIR spectroscopy and multivariate chemometric techniques[J]. Atmospheric Environment, 2008,42(23):5923-5932.
[11]	Rosén P, Persson P. Fourier-transform infrared spectroscopy (FTIR), a new method to infer past changes in tree-line position and TOC using lake sediment[J]. Journal of Paleolimnology, 2006,35(4):913-923.
[12]	Vogel H, Rosén P, Wagner B, et al. Fourier transform infrared spectroscopy, a new cost-effective tool for quantitative analysis of biogeochemical properties in long sediment records[J]. Journal of Paleolimnology, 2008,40(2):689-702.
[13]	Wirrmann D, Bertaux J, Kossoni A. Late holocene paleoclimatic changes in Western Central Africa inferred from mineral abundance in dated sediments from Lake Ossa (Southwest Cameroon)[J]. Quaternary Research, 2001,56:275-287.
[14]	Bertaux J, Ledru M P, Soubiès F, et al. The use of quantitative mineralogy linked to palynological studies in palaeoenvironmental reconstruction: the case study of the Lagoa Campestr Lake, Salitre, Minas Gerais, Brazil[J]. Comptes Rendus Académie Sciences de Paris Séries II, 1996,323:65-71.
[15]	Sifeddine A, Frölich F, Fournier M, et al. La sédimentation lacustre indicateur de changements des paléoenvironnements au cours des 30 000 dernières années (Carajas, Amazonie, Brésil)[J]. Comptes-Rendus de l'Académie des Sciences de Paris, 1994,318(12):1645-1652.
[16]	Mecozzi M, Pietrantonio E, Amici M, et al. Determination of carbonate in marine solid samples by FTIR-ATR spectroscopy[J]. Analyst, 2001,126(2):144. doi: 10.1039/b009031j pmid: 11235093
[17]	Braguglia C M, Campanella L, Petronio B M, et al. Sedimentary humic acids in the continental margin of the Ross Sea (Antarctica)[J]. International Journal of Environmental Analytical Chemistry, 1995,60(1):61-70.
[18]	Belzile N, Joly H A, Li H. Characterization of humic substances extracted from Canadian lake sediments[J]. Canadian Journal of Chemistry, 1997,75(1):14-27.
[19]	Calace N, Cardellicchio N, Petronio B M, et al. Sedimentary humic substances in the Northern Adriatic Sea (Mediterranean Sea)[J]. Marine Environmental Research, 2006,61(1):40-58. pmid: 16019060
[20]	De Master D J. The supply and accumulation of silica in the marine environment[J]. Geochimica et Cosmochimica Acta, 1981,45(10):1715-1732.
[21]	Rosén P, Vogel H, Cunningham L, et al. Fourier transform infrared spectroscopy, a new method for rapid determination of total organic and inorganic carbon and biogenic silica concentration in lake sediments[J]. Journal of Paleolimnology, 2010,43(2):247-259.
[22]	Geladi P, Macdougall D, Martens H. Linearization and scatter-correction for near-infrared reflectance spectra of meat[J]. Applied Spectroscopy, 1985,39(3):491-500.
[23]	Geladi P, Dbakk E. Computational methods and chemometrics in near infrared spectroscopy[M]// Encyclopedia of spectroscopy and spectrometry. Amsterdam: Elsevier, 1999: 343-349.
[24]	Wold S, Sjöström M, Eriksson L. PLS-regression: a basic tool of chemometrics[J]. Chemometrics and Intelligent Laboratory Systems, 2001,58(2):109-130.
[25]	Vogel H, Meyer-Jacob C, Thöle L, et al. Quantification of biogenic silica by means of Fourier transform infrared spectroscopy (FTIR) in marine sediments[J]. Limnology and Oceanography (Methods), 2016,14(12):828-838.
[26]	Moenke H H W, Farmer V C. Silica, the three-dimensional silicates, borosilicates and beryllium silicates[M]. London: Mineralogical Society, 1974.
[27]	Farmer V C. The infrared spectra of minerals[M]. London: Mineralogical Society, 1974: 227-284.
[28]	Madejová J. FTIR techniques in clay mineral studies[J]. Vibrational Spectroscopy, 2003,31(1):1-10.
[29]	Mecozzi M, Pietrantonio E. Carbohydrates proteins and lipids in fulvic and humic acids of sediments and its relationships with mucilaginous aggregates in the Italian seas[J]. Marine Chemistry, 2006,101(1/2):27-39.
[30]	Bettmer J. Analytical chemistry: a modern approach to analytical science[J]. Angewandte Chemie International Edition, 2005,44(28):4286-4287.
[31]	Pironon J, Pelletier M, de Donato P, et al. Characterization of smectite and illite by FTIR spectroscopy of interlayer NH$^+_4$ cations[J]. Clay Minerals, 2003,38(2):201-211.
[32]	Gendron-Badou A, Coradin T, Maquet J, et al. Spectroscopic characterization of biogenic silica[J]. Journal of Non-Crystalline Solids, 2003,316(2/3):331-337.
[33]	Conley D. An interlaboratory comparison for the measurement of biogenic silica insediments[J]. Marine Chemistry, 1998,63(1/2):39-48.
[34]	Rosé P, Vogel H, Cunningham L, et al. Universally applicable model for the quantitative determination of lake sediment composition using Fourier transform infrared spectroscopy[J]. Environmental Science $\&$ Technology, 2011,45(20):8858-8865. pmid: 21882858

基于 FTIR 对水库沉积物中 TOC, TN 和 BSi 含量的快速测定

Rapid determination of TOC, TN and BSi content in reservoir sediments based FTIR

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