咪唑酰胺化衍生物的制备与性能

上海大学学报(自然科学版) ›› 2010, Vol. 16 ›› Issue (5): 517-521.

咪唑酰胺化衍生物的制备与性能

1.上海大学环境与化学工程学院，上海200444； 2.东华大学生态纺织教育部重点实验室，上海 201620

收稿日期:2010-06-03 出版日期:2010-10-30 发布日期:2010-10-30
通讯作者: 张宝华(1969～)，女，副教授，博士,研究方向为精细高分子合成与应用. E-mail:zhangbh@shu.edu.cn
基金资助:
上海市联盟计划资助项目（09LM05）；上海市重点学科建设资助项目（S30109）

Preparation of Imidazole Amidate Derivatives and Their Properties

1. School of Environmental and Chemical Engineering , Shanghai University, Shanghai 200444, China; 2. Key Laboratory of Science & Technology of Eco-Textile of Ministry of Education, Donghua University, Shanghai 201620, China

Received:2010-06-03 Online:2010-10-30 Published:2010-10-30

摘要/Abstract

摘要：

通过一元羧酸与2-甲基咪唑进行酰胺化反应制备咪唑酰胺化衍生物及其盐，并对咪唑酰胺化衍生物及其盐的结构与性能进行表征.结果表明：咪唑酰胺化衍生物及其盐可降低咪唑的固化反应活性，提高潜伏性；可显著改善与环氧树脂之间的相容性，从而提高工艺操作性；可明显提高环氧树脂固化物的力学性能.

关键词: 咪唑衍生物；羧酸；酰胺化；环氧树脂；固化剂

Abstract:

Derivatives of 2-methylimidazole amidate and their carboxylic acid salts were synthesized by amidate reaction of carboxylic acid and 2-methylimidazole. Their structures and properties were studied. It was found that the 2-methylimidazole amidate derivatives and their carboxylic acid salts had lower curing activities and better latent properties than those of 2-methylimidazole. They also had better compatibility with epoxy resin than 2-methylimidazole, thus clearly improving mixed process operability of epoxy resin curing system. Mechanical properties of epoxy resin thermosets of 2-methylimidazole amidate derivatives and their carboxylic acid salts were better than those of 2-methylimiadzole.

Key words: imidazole derivatives; carboxylic acid; amidate; epoxy resin; curing agent

中图分类号:

TQ 252.3

张宝华1 2 翁燕青1 陈斌1 张玉颖1. 咪唑酰胺化衍生物的制备与性能[J]. 上海大学学报(自然科学版), 2010, 16(5): 517-521.

ZHANG Bao-Hua-1, 2, WENG Yan-Qing-1, CHEN Bin-1, ZHANG Yu-Ying-1. Preparation of Imidazole Amidate Derivatives and Their Properties[J]. Journal of Shanghai University（Natural Science Edition）, 2010, 16(5): 517-521.