CuPc/CuPc∶C60/Alq/Al结构的有机太阳能电池

上海大学学报(自然科学版) ›› 2010, Vol. 16 ›› Issue (1): 38-42.

CuPc/CuPc∶C₆₀/Alq/Al结构的有机太阳能电池

唐健敏,史伟民,王林军,周文静,朱文清,夏义本

（上海大学材料科学与工程学院，上海 200072）

收稿日期:2008-07-14 出版日期:2010-02-28 发布日期:2010-02-28
通讯作者: 史伟民(1951~)，男，教授，研究方向为功能材料与器件. E-mail:wmshi@mail.shu.edu.cn
基金资助:
上海应用材料研究发展基金资助项目(06SA08)

Organic Solar Cells Based on CuPc/CuPc∶C₆₀/Alq /Al Structure

TANG Jian-min,SHI Wei-min,WANG Lin-jun,ZHOU Wen-jing,ZHU Wen-qing,XIA Yi-ben

(School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China)

Received:2008-07-14 Online:2010-02-28 Published:2010-02-28

摘要/Abstract

摘要：

制备了一种ITO/CuPc/CuPc∶C₆₀/Alq/Al 结构的PIN有机太阳能电池，采用Cu-phthalocyanine (CuPc)和fullerene (C₆₀)的共混层作为光吸收层，CuPc和Alq作为空穴传输层和电子传输层.利用真空蒸发镀膜法制备各层有机薄膜，并用I-V曲线和紫外可见吸收光谱来表征器件性能.研究了器件的光吸收层、电子传输层、空穴传输层的膜厚参数对器件性能的影响.结果表明,当器件光吸收层、电子传输层、空穴传输层的厚度分别为15,30,40 nm时，器件的性能达到最优化.优化器件的短路电流密度J_SC为2.07 mA·cm^-2,开路电压V_OC为0.56 V, 填充因子F_F为0.46，器件的能量转换效率达到0.53%.

关键词: 有机太阳能电池；PIN；Alq；真空蒸发

Abstract:

Blends of Cuphthalocyanine (CuPc) and fullerene (C₆₀) was used as an active layer and Alq and CuPc as a transport layer to fabricate a CuPc/CuPc∶C₆₀/Alq/Al PINtype organic solar cell. These layers were grown with a vacuum evaporation method and characterized with I-V curve and UVvisible spectrometry. Cell performance with different thickness of the active layers, P layer and N layer, has been studied. The results show that when thicknesses of the active layers, N layer and P layer, are 15, 30 and 40 nm, respectively, the prepared solar cell has a good performance. The cell parameters with optimal P, I, and N layers have been measured as J_SC=2.07 mA·cm^-2, V_OC = 0.53 V, and F_F=0.46. Power efficiency of this kind of solar cell can reach approximately over 0.53%.

Key words: organic solar cell; PIN; Alq; vacuum evaporation

中图分类号:

TK 513

唐健敏,史伟民,王林军,周文静,朱文清,夏义本. CuPc/CuPc∶C₆₀/Alq/Al结构的有机太阳能电池[J]. 上海大学学报(自然科学版), 2010, 16(1): 38-42.

TANG Jian-min,SHI Wei-min,WANG Lin-jun,ZHOU Wen-jing,ZHU Wen-qing,XIA Yi-ben. Organic Solar Cells Based on CuPc/CuPc∶C₆₀/Alq /Al Structure[J]. Journal of Shanghai University（Natural Science Edition）, 2010, 16(1): 38-42.

CuPc/CuPc∶C₆₀/Alq/Al结构的有机太阳能电池

Organic Solar Cells Based on CuPc/CuPc∶C₆₀/Alq /Al Structure

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