上海大学学报(自然科学版) ›› 2023, Vol. 29 ›› Issue (6): 1022-1029.doi: 10.12066/j.issn.1007-2861.2304

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银纳米线柔性透明导电薄膜的制备

刘晓文,潜飞, 张波,吴美莹,李红斌,张宝华   

  1. (1. 上海大学 环境与化学工程学院, 上海 200444; 2. 中华人民共和国台州海关, 浙江 台州 318000)
  • 接受日期:2021-05-24 出版日期:2023-12-28 发布日期:2023-12-29
  • 通讯作者: 张宝华 (1969—), 副教授, 博士, 研究方向为精细高分子的合成与应用. E-mail:zhangbh@shu.edu.cn
  • 基金资助:
    上海市教育基金会2016年度联盟计划资助课题(LM201667)

Preparation of silver nanowires and their flexible transparent conductive films

Liu Xiaowen,Qian Fei,Zhang Bo,Wu Meiying,Li Hongbin,Zhang Baohua   

  1. (1. School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China; 2. Taizhou Customs of People’s Republic of China, Taizhou 318000, Zhejiang, China
  • Accepted:2021-05-24 Online:2023-12-28 Published:2023-12-29

摘要: 采用多元醇法制备了直径约 40 nm、长径比约 300 的银纳米线. 以聚对苯二甲酸 乙二醇酯-1,4-环己烷二甲醇酯 (polyethylene terephthalateco-1,4-cylclohexylenedimethylene terephthalate, PETG) 膜为基底, 采用旋涂法制备了银纳米线柔性透明导电薄膜, 探究了不同 辅助成膜剂对成膜性能的影响. 发现以黄原胶为辅助成膜剂制备的银纳米线薄膜具有较理想 的透明性和导电性; 银纳米线分散液沉积密度对银纳米线薄膜的透明性和导电性有重要影响, 当沉积密度为 10 mg/cm2 时, 银纳米线薄膜的透光率和导电性能最优; 弯曲测试结果表明, 银 纳米线薄膜具有很好的柔韧性.

关键词: 多元醇法, 银纳米线, 旋涂法, 柔性透明导电薄膜

Abstract: Silver nanowires with a diameter of approximately 40 nm and a length to diameter ratio of approximately 300 were prepared via the polyol method. Subsequently, uniform, stable, and flexible transparent conductive films of silver nanowires were prepared by the spin coating method. Polyethylene terephthalateco-1,4-cylclohexylenedimethylene terephthalate (PETG) film was used as the substrate and Chitosan or Xanthan gum as the auxiliary film forming agent. It was found that the deposition density of silver nanowires dispersion had an significant effect on the transparency and electrical conductivity of silver nanowires flexible transparent conductive films. The light transmittance and electrical conductivity of the films reached a maximum when the deposition density was 10 mg/cm2 . The bending performance test of the film indicated good flexibility.

Key words: Polyol method, Silver nanowires, Spin coating method, `Flexible transparent conductive film

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