上海大学学报(自然科学版) ›› 2021, Vol. 27 ›› Issue (4): 706-716.doi: 10.12066/j.issn.1007-2861.2154
收稿日期:
2019-04-01
出版日期:
2021-08-20
发布日期:
2021-07-22
通讯作者:
陈志文
E-mail:zwchen@shu.edu.cn
作者简介:
陈志文(1962—), 男, 教授, 博士生导师, 研究方向为纳米材料的合成与性质等. E-mail: zwchen@shu.edu.cn基金资助:
WANG Shangdai, HUANG Shoushuang, HU Zhangjun, CHEN Zhiwen()
Received:
2019-04-01
Online:
2021-08-20
Published:
2021-07-22
Contact:
CHEN Zhiwen
E-mail:zwchen@shu.edu.cn
摘要:
以金属有机骨架(metal-organic frameworks, MOFs)化合物为前驱体, 通过退火、硫化等后续处理方法成功制备了由 NiFe2O4 纳米棒与 Co9S8 空心球组装而成的杂化纳米结构. 该复合催化剂因具有较大的比表面积以及各组分间强力的协同作用, 在电催化析氧反应(oxygen evolution reaction, OER)中表现出了优异的催化活性. 在 1 mol/L KOH 电解质中, 当电流密度达到 10 mA/cm2 时, 仅需 290 mV 的过电位, 且 Tafel 斜率仅为 63.02 mV/dec. 此外, 1 000 次循环伏安(cyclic voltammetry, CV)测试后仍然具有良好的催化活性, 表明该复合催化剂具有优异的稳定性. 研究成果不仅为设计廉价、高效且稳定的析氧催化剂提供了设计思路, 也为其他新型纳米复合材料的合成和应用奠定了基础.
中图分类号:
王尚岱, 黄守双, 胡张军, 陈志文. 金属有机骨架衍生的 NiFe2O4/Co9S8复合催化剂的合成及其电催化析氧性能[J]. 上海大学学报(自然科学版), 2021, 27(4): 706-716.
WANG Shangdai, HUANG Shoushuang, HU Zhangjun, CHEN Zhiwen. Controlled synthesis of NiFe2O4/Co9S8 nanocomposites derived from metal-organic frameworks as efficient electrocatalysts for oxygen evolution reaction[J]. Journal of Shanghai University(Natural Science Edition), 2021, 27(4): 706-716.
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