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    28 February 2022, Volume 28 Issue 1
    Invited Review
    Research progress on catalytic oxidation for the removal of volatile organic compounds
    JIAO Zheng, WU Minghong
    2022, 28(1):  1-18.  doi:10.12066/j.issn.1007-2861.2350
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    The sources and types of typical volatile organic compounds (VOCs) are reviewed in this paper. The impact of the category of nanocatalysts and their preparation methods is discussed, and the key parameters controlling nanocatalyst performance, such as particle size, structure, and morphology, are evaluated. Current research trends on the development of supported noble- and transition-metal oxide catalysts to remove halocarbons, aromatic hydrocarbons, oxygenated organic compounds, aliphatic hydrocarbons, and nitrogen- and sulfur-containing compounds are then examined. Moreover, the effects of carbon monoxide and water vapor on the catalytic oxidation of VOCs are investigated. Finally, perspectives on the development of methods to achieve the catalytic oxidation of VOCs are presented.

    Research Articles
    Synthesis of Ce-doped Co3O4  nanoflowers with rich oxygen vacancies based on MOF template method for enhancing gas sensing performance
    HE Yongchao, LI Fei, YAN Bingjun, HE Xinhua, PU Xianjuan, NING Zhukai, CHENG Lingli, JIAO Zheng
    2022, 28(1):  19-30.  doi:10.12066/j.issn.1007-2861.2284
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    Co3O4  nanomaterials have low sensitivity and long response/recovery time in gas sensor applications. Ce-doped Co-based metal organic framework (MOF) precursors were prepared by a simple solvothermal method and Ce-doped Co3O4  nanoflowers were then successfully synthesised by heat treatment. The morphology and composition of the materials were analysed by X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectron spectroscope (XPS), energy dispersive spectroscope (EDS), and other characterization methods. The results indicated that Ce doping could effectively change the oxygen distribution and increase the number of oxygen vacancies in Co3O4 . The sensor made of this material exhibited an excellent sensing performance. At an operating temperature of 190 °C, the response to 100×10-6 n-butanol could reach 87.79 and the calculated theoretical detection limit could reach 122×10-9.

    Effects of diesel fuel and Cd pollution on enzyme activity and microbial biomass in the soil
    HE Zichen, HU Xuefeng, LU Siwen, ZHAO Jinglong, LAN Guojun, LI Mei, ZHANG Weijie
    2022, 28(1):  31-39.  doi:10.12066/j.issn.1007-2861.2233
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    A pot experiment was conducted to study the effects of pollutants of diesel fuel and Cd alone or in combination on the activities of urease (UR) and dehydrogenase (DE) and microbial biomass in non-polluted paddy soil collected from an urban setting in Shanghai. The experiment included seven treatments: control (CK), low content of diesel fuel (CYL), high content of diesel fuel (CYH), low content of Cd (CdL), high content of Cd (CdH), combination of high content of diesel fuel and Cd (CYH+CdH), and combination of high content of diesel fuel, Cd and crop seedlings (CYH+CdH+P). The activity of UR was significantly raised when the soil was polluted with CYH and Cd for the treatments of CYH and CYH + CdH. The maximum UR for the two treatments was 5.25 and 2.63 times that of CK, respectively. The microbial biomass for the treatments was also correspondingly raised to some extent. Conversely, the activity of DE in the soil for the CYL, CYH and CYH + CdH treatments was significantly inhibited. The influence of Cd on DE activity in the soil was relatively mild. DE was activated even when the soil was polluted with CdL.

    Remediation of Cd-Zn-Cu contaminated river sediment by typical herbaceous plants
    SHEN Jiayi, GAO Mingjing, LIU Yu, HUANG Xun, GUO Hao, ZHANG Xinying
    2022, 28(1):  40-48.  doi:10.12066/j.issn.1007-2861.2260
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    A typical black-odor urban river sediment in Shanghai was assessed in the study. Six characteristic herbaceous plants, namely Trifolium repens L., Festuca arundinacea, Lolium perenne L., Elymus dahuricus Turcz., Amaranthus hypochondriacus L., and Medicago sativa L., were used as experimental plants in the phytoremediation of Cd-Zn-Cu contaminated river sediment. The tolerance to heavy metals, enrichment and transport features, and remediation efficiencies of the six plants in the river sediment were explored. The results showed that, except for Trifolium repens L., the plants had good tolerance to heavy metals in the sediment. For Cd and Zn, the accumulation ability of Lolium perenne L. was higher, and the content of Zn in the plant was 707.69 mg/kg. The accumulation ability of Elymus dahuricus Turcz. to Cu was relatively higher. The accumulation of heavy metals in the plants was primarily within the roots, except for the accumulation of Zn in Medicago sativa L. The bioaccumulation factor of Cd and Zn in Festuca arundinacea and Lolium perenne L. was greater than 1. Furthermore, the Cd, Zn and Cu extraction efficiencies of Festuca arundinacea and Lolium perenne L. exceeded 7%, 6% and 2%, respectively, which suggested stronger phytoextraction potentiality of the Cd-Zn-Cu contaminated river sediment.

    Ammonia nitrogen release from surface sediment of a reservoir in East China
    ZHU Yiping, GAO Peiyue, ZHAO Yiying, WANG Feifei, HUANG Xin, LI Huaizheng
    2022, 28(1):  49-56.  doi:10.12066/j.issn.1007-2861.2331
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    To determine the contribution of ammonia nitrogen release from the surface sediments of reservoirs, the total nitrogen and ammonia nitrogen contents in surface sediments ($<$10 cm), overlying water, and interstitial water in typical areas of a reservoir were analyzed via on-site sampling of a reservoir in East China combined with an ammonia nitrogen release test, which revealed the temporal and spatial distribution characteristics of nitrogen in the reservoir sediments. The results showed that the ammonia nitrogen and total nitrogen contents in the reservoir showed clear seasonal changes, and the total nitrogen concentration in the surface sediment was higher than that in the summer. The total nitrogen concentration in the surface sediment was higher than that in the overlying water, and the ammonia nitrogen diffusion flux in the sediment was 0.18$\sim$0.53 mg/(m$^{2}\cdot $d), which was one order of magnitude lower than that of a heavily polluted reservoir. During the thermodynamic distribution of ammonia nitrogen in the sediment-interstitial water-overlying water, the surface sediment had an adsorption effect on ammonia nitrogen, which could buffer the sudden ammonia nitrogen pollution problem to a certain extent; however, the strong disturbance of the water flow could also promote the diffusion of ammonia nitrogen in the sediment to the water body in a short time.

    Degradation characteristics of biodegradation of tetrabromobisphenol A by the novel aerobic strain W1-2
    YANG Shuxian, HU Xing
    2022, 28(1):  57-66.  doi:10.12066/j.issn.1007-2861.2267
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    A novel strain, namely W1-2, was acclimatised and isolated from aerobic activated sludge in a mineral salt medium with tetrabromobisphenol A (TBBPA). Strain W1-2 was identified as Pseudomonas sp. according to the 16S rDNA sequence. After 5 days of aerobic incubation, the degradation rate of 10 mg/L TBBPA was 91.4% at 30 ℃, pH=7, and 150 r/min. The temperature, rotation speed, pH and TBBPA concentration could influence the degradation rate, among which pH was the most influential parameter. The optimal conditions for bacterial degradation and the growth of strain W1-2 were 150 r/min, 30~35 ℃, initial TBBPA concentration of 10 mg/L, and pH=8 according to a single-factor experiment. Strain W1-2 had an excellent degradation ability at high levels of TBBPA(30 mg/L) and under micro-oxygen conditions (0 r/min) without the support of other carbon sources. This study on the degradation characteristics of strain W1-2 provides a new perspective to explore the microbial removal of TBBPA in aerobic environments.

    Copper-ion-doped vanadium-based coordination polymers for high-performance hybrid supercapacitors
    GAO Yun, ZHI Chuanwei, LIU Tongxin, LÜ Liping
    2022, 28(1):  67-79.  doi:10.12066/j.issn.1007-2861.2221
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    The microspheres of copper-ion-doped vanadium-based coordination polymers (V-Cu-HHTP) with diameters of approximately 1.5 μm are prepared through two steps of microwave treatment. The introduction of Cu$^{2+}$ is achieved by cation exchange and is assumed to improve electronic conductivity and provide the synergic effect derived from the bimetallic feature of the vanadium-based coordination polymers. Results show that the V-Cu-HHTP exhibit good specific capacitance and cycle stability when used as electrode materials in supercapacitors. More specifically, V-Cu-HHTP show a capacitance of287 F$\cdot$g$^{-1}$ at 1 A$\cdot$g$^{-1}$ and have a 98.6% capacitance retention of 10 A$\cdot$g$^{-1}$ after 3 000 charging--discharging cycles. In comparison, the V-HHTP electrode shows a lower specific capacitance of 227 F$\cdot$g$^{-1}$ at 1 A$\cdot$g$^{-1}$ with a 94.2% capacitance retention of 10 A$\cdot$g$^{-1}$. An asymmetric supercapacitor is assembled with the V-Cu-HHTP as a cathode and activated carbon (AC) as an anode (denoted as V-Cu-HHTP//AC). The assembled V-Cu-HHTP//AC device can achieve a potential window of 1.6 V, and the energy density is as high as 44.1 Wh$\cdot$Kg$^{-1}$ when the power density is 795.0 W$\cdot$Kg$^{-1}$. We attribute these excellent electrochemical properties to the following. First, the bimetal-based coordination polymer provides an excellent synergistic effect derived from the two metallic elements. Second, Cu doping improves the electronic conductivity and structural stability of the vanadium-based coordination polymers. The porous characteristics of V-Cu-HHTP provide numerous active sites to the electrode, thus leading to improved energy storage properties.

    Characteristics of nitrogen-containing components within submicron particles in Shanghai
    ZHANG Yuying, CHEN Hao, FENG Jialiang
    2022, 28(1):  80-90.  doi:10.12066/j.issn.1007-2861.2232
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    The formation, transformation, transportation, and deposition of inorganic and organic nitrogen within fine particles is critical in the nitrogen cycle. To understand the concentrations, compositions, and seasonal variations of the nitrogen-containing components within submicron particles (PM$_{1}$) in Shanghai, PM$_{1}$ samples were collected in Shanghai during 2017—2018 using a high-volume sampler. The concentrations of water-soluble ions and water-soluble organic nitrogen (WSON) were measured using ion chromatography and UV/Vis photometry. The annual average concentrations of NH$_{4}^{+}$-N, NO$_{3}^{-}$-N, and WSON within PM$_{1}$ in Shanghai were 1.79, 0.97, and 0.41 μg/m3 respectively. NH$_{4}^{+}$-N showed the highest contribution (56 %) to the water-soluble total nitrogen (WSTN), followed by NO$_{3}^{-}$-N (31 %), while the annual contribution of WSON to WSTN was 13 %. The concentrations of the nitrogen-containing components within PM$_{1}$ in Shanghai were highest in winter and lowest in summer. However, the contributions of NH$_{4}^{+}$-N, NO$_{3}^{-}$-N, and WSON to WSTN differed. The contribution of NH$_{4}^{+}$-N to WSTN showed a small seasonal variation, and a distinct trend of higher in winter (38 %) and lower in summer (18 %) was observed for the contribution of NO$_{3}^{-}$-N, while the contribution of WSON to WSTN was the highest in summer (22 %) and lowest in winter (8 %). Positive matrix factorisation (PMF) showed that secondary formation and the burning of biomass contributed 48 % of the WSON within PM$_{1}$ in Shanghai, with coal combustion contributing 11 %, secondary formation from biogenic volatile organic compounds 20 %, and emissions from kitchens and vehicles 21 %. The sources of WSON varied significantly according to season.

    Adsorption and transport properties of the lithium ion in a covalent organic framework/carbon nanotube composite by molecular simulation
    XU Yi, CUI Zhiyuan, WU Fan, YUAN Bin
    2022, 28(1):  91-101.  doi:10.12066/j.issn.1007-2861.2224
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    In this study, the adsorption and transport properties of the lithium ion (Li$^{+})$ in a covalent organic framework/carbon nanotube composite (COF@CNT) are investigated through molecular simulation. The adsorption sites and sequence of Li$^{+}$ are defined and the corresponding adsorption energy is obtained. In addition, apparent change in the morphology of the COF@CNT is identified. When saturated adsorption is reached, the volumetric change rate of the COF@CNT is only 0.25. Simultaneously, the average voltage is maintained at greater than 2.00 V, and the theoretical capacity reaches as high as1402.47 mAh/g. Finally, the electronic conductivity of Li$^{+}$ inside the COF@CNT exceeds that in a pure CNT. The results of this study can provide a theoretical basis for the practical application of these systems.

    Synthesis of functionalised CMK-3 ordered mesoporous carbon materials and their humidity sensitivity performance
    ZHANG Zhiwei, FAN Yu, MA Zhiheng, LI Runlong, HAO Chenran, XU Jiaqiang
    2022, 28(1):  102-110.  doi:10.12066/j.issn.1007-2861.2262
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    Mesoporous materials are widely used in several fields, such as energy storage, catalysis, and humidity sensors. In this study, ordered mesoporous silicon SBA-15 is used as a template to prepare CMK-3 mesoporous carbon materials with specific surface areas greater than 1 000 m2/g using a nanocasting method. The carbon materials are then modified by carboxyl functionalisation using ammonium persulfate. Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), small-angle X-ray diffraction (XRD), and Brunauer-Emmet-Teller (BET) nitrogen adsorption and desorption methods are used to characterise the materials. Results show that both before and after functionalisation, CMK-3 mesoporous carbon materials have favourable ordered mesoporous structures. Using a quartz crystal microbalance (QCM) test platform, the humidity sensing performances of the materials are tested. Results show that after carboxyl functional modification, the materials exhibit a high response to different humidity environments, and their humidity response is clearly enhanced. Particularly in a 97% RH high-humidity environment, a remarkable response of as high as 1 600 Hz is obtained, which proves beneficial to the application of CMK-3 humidity sensitive materials in high-humidity environments.

    Effects of Nb on hydrogen diffusion in Fe-13Cr-6Al-2Mo alloys
    MA Xingxing, CHEN Yexin, ZHANG Huawei
    2022, 28(1):  111-120.  doi:10.12066/j.issn.1007-2861.2236
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    In this study, the diffusion behaviors of hydrogen atoms in Fe-13Cr-6Al-2Mo and Fe-13Cr-6Al-2Mo-0.5Nb alloys were studied by the electrochemical hydrogen permeation method. The effects of 0.5% Nb (mass fraction) added to the alloy on the diffusion behavior of hydrogen atoms in the Fe-13Cr-6Al-2Mo alloy were analyzed. Results showed that the grain of the alloy was refined, and a large amount of fine Fe$_2$Nb phase was dispersed in the Fe-13Cr-6Al-2Mo alloy when 0.5% Nb was added. The results also showed that 0.5% Nb greatly reduced the apparent diffusion coefficient of hydrogen in the Fe-13Cr-6Al-2Mo alloy and increased the diffusion activation energy of hydrogen in the alloy by 50.3%. The Nb atom effectively reduced the diffusion rate of hydrogen in the FeCrAlMo-based alloy by increasing the hydrogen trap concentration in the alloy.

    Effect of molybdenum disulfide-graphene oxide nanohybrids on anticorrosive waterborne polyurethane acrylate coatings
    WANG Jiangyu, GUO Xiaofeng, SHI Lei, CHEN Liquan, WANG Xu, LIU Liqi
    2022, 28(1):  121-131.  doi:10.12066/j.issn.1007-2861.2249
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    Metal corrosion considerably affects the global economy; thus, strategies for the prevention of metal corrosion have gained considerable research and industrial attention. To develop one such strategy, herein, molybdenum disulfide-graphene oxide (MoS$_{2}$-GO) nanohybrids is synthesized by a simple method. The as-synthesized MoS$_{2}$-GO nanohybrids are added to waterborne polyurethane acrylates (WPUA) to prepare anticorrosive MoS$_{2}$-GO/WPUA coatings. Firstly, silane-functionalized molybdenum disulfide (A-MoS$_{2}$) via simple covalent functionalization with 3-aminopropyltriethoxysilane (APTES) is obtained. Secondly, MoS$_{2}$-GO nanohybrids are synthesized by a simple method in N, N-dimethylformamide (DMF). Finally, different amounts of the MoS$_{2}$-GO nanohybrids (0, 0.2%, 0.4%, 0.6%, 0.8%, 1.0%) are added to WPUA to prepare MoS$_{2}$-GO/WPUA coatings. The results show that the MoS$_{2}$-GO nanohybrids are synthesized successfully. The surface of the 0.4% MoS$_{2}$-GO/WPUA coating consisting the 0.4% MoS$_{2}$-GO sample is smooth. The contact angle is 99.67$^{\circ}$ and $\vert Z\vert _{0.01{\rm Hz}}$ is 3.19$\times $10$^{7}\Omega \cdot $cm2 after 28 days of immersion in 3.5% NaCl. The Nyquist plot shows a semicircle and the phase angle diagram has a single peak close to 90$^{\circ}$, indicating high corrosion resistance.

    Swelling characteristics of a mixture of crushed granite and bentonite under the condition of alkali-thermo coupling
    QIN Aifang, HU Hongliang
    2022, 28(1):  132-144.  doi:10.12066/j.issn.1007-2861.2238
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    During the life of a high-level radioactive waste repository, the decay heat of nuclear waste and alkaline pore water produced by the aging of concrete affect the working performance of the buffer material. To study the effects of alkali-thermo coupling on the swelling characteristics of buffer materials, NaOH solution is used in this study to simulate alkaline pore water, and a water bath pot is used to provide a constant temperature solution, where the solution is continuously circulated in a self-developed corrosion-resistant consolidator. The evolution curves of the swelling force are obtained through swelling force experiments under concentrations of 0.1, 0.5, and 1.0 mol/L and temperatures of 25 $^\circ$C and 50 $^\circ$C. Results showed that at the same temperature, the maximum and final swelling force of the sample decreased with an increase in the solution concentration. In addition, at the same concentration of alkaline solution infiltration, the maximum and final swelling force of the sample decreased with an increase in the granite mixing rate. Under the same granite mixing rate and same infiltration solution, the maximum and final swelling force of the sample decreased with an increase in temperature. The attenuation degree of swelling force increased with increases in solution concentration and temperature. For the mixture of crushed granite and bentonite, under the same temperature and same infiltration solution, the attenuation degree of swelling force decreased with an increase in the granite mixing rate.

    Thermodynamic analysis of a fluid-saturated porous thermo-elastic symmetric plane
    ZHU Yuanyuan, YANG Xiao, WU Haitao
    2022, 28(1):  145-156.  doi:10.12066/j.issn.1007-2861.2264
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    To address problems related to geometric nonlinearity and the local thermal equilibrium, the thermodynamic characteristics of an incompressible fluid-saturated porous thermo-elastic half-plane subjected to surface temperature loadings are studied. First, a mathematical model of the problem of geometric nonlinearity is established based on the porous media theory. Then, a synthetic numerical computation method is presented to simulate the numerical results of the problem. Here, the differential quadrature method and second-order backward difference scheme are applied to discretize the mathematical model in the spatial and time domains, respectively. In addition, the Newton-Raphson iterative method is used to solve nonlinear algebraic equations and to present the numerical results of the problem. The method presented in this study is proven to be effective and reliable, where its advantages include a small calculated amount and high accuracy. Finally, the thermodynamic characteristics of the fluid-saturated porous thermo-elastic half-plane subjected to surface temperature loadings are studied, and the effects of material parameters and geometric nonlinearity on the dynamic characteristics are considered in detail.

    Digital Film and Television Technology
    Inner-relation modelling with memory networks in aspect-based sentiment analysis
    ZHANG Ke, ZHANG Wenjun, ZHU Yunwen, XING Yixue
    2022, 28(1):  157-169.  doi:10.12066/j.issn.1007-2861.2265
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    Aspect-based sentiment analysis (ABSA) predicts the sentiment polarity of particular entities in given sentences. Studies show that the most effective methods use features obtained by modelling entities and their contexts with attention to sentiment prediction. However, these methods calculate the attention weights of contexts by using mean vectors for target entities. In addition, these methods cannot highlight the importance of individual words in the text of whole sentences. Therefore, this study proposes an aspect-based sentiment analysis method that can model the inner relations with memory networks, where networks can learn more effective contextual representations. First, gated recurrent units (GRUs) are used to embed the distributed representations of aspect words and words in sentences. Then, a long short-term memory network (LSTM) takes the distributed representation as input to increase the weights of entities according to the attention-based contextual relationship. Finally, through a query mechanism, aspect-based sentiment polarity is obtained. The proposed model is tested on the open-source datasets Semeval-2014 and Semeval-2016, with results showing that the proposed method is effective and the accuracy is higher than that of the baselines.

    Incorporating article information for sentiment analysis of news comments
    YANG Yipu, ZHU Yonghua, GAO Haiyan, GAO Wenjing
    2022, 28(1):  170-178.  doi:10.12066/j.issn.1007-2861.2252
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    News comments reflect people's opinions or sentiments toward news events. Therefore, analysis of news comments is potentially useful for many applications. Traditional methods of sentiment analysis focus on the contents of comments while ignoring the influence of news topics and semantics information from news articles. This study proposes a sentiment analysis approach using support vector machine and $K$-means clustering that considers the impact of news articles on the sentiments of news comments. Experimental results on a news comment dataset demonstrate the effectiveness of our proposed method.