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Removal of Cr(Ⅵ) in soil by chitosan stabilized nanoscale zero iron
Received date: 2016-01-18
Online published: 2016-04-30
Removal efficiency of Cr(Ⅵ) in soils by chitosan stabilized nanoscale zero-valent iron was studied. Experimental results showed that the removal efficiency increased with zero-valent iron dosage. The maximum removal efficiency was 95.9%, six times of 100 mesh iron filing. The initial concentration of Cr(Ⅵ) in soil and pH value were all inversely proportional to the removal efficiency. Removal of Cr(Ⅵ) in soils by zero-valent iron was a result of the interaction of adsorption and reduction. The reduction process of nanoscale zero-valent iron accorded with pseudo first-order reaction kinetics, and the apparent rate constant kobs was 0.016/min.
Key words: chitosan; Cr(Ⅵ); nanoscale zero-valent iron; soil
YAN Lijun1,2, LIU Moli1, HU Xuefeng1 . Removal of Cr(Ⅵ) in soil by chitosan stabilized nanoscale zero iron[J]. Journal of Shanghai University, 2016 , 22(2) : 203 -210 . DOI: 10.3969/j.issn.1007-2861.2016.01.011
[1] Avudainayagam S, Megharaj M, Owens G. Chemistry of chromium in soils with emphasison tannery waste sites [J]. Reviews of Environmental Contamination and Toxicology, 2003, 178: 53-91.
[2] Fu F L, Ma J, Xie L P, et al. Chromium removal using resin supported nanoscale zero-valent iron [J]. Journal of Environmental Management, 2013, 128: 822-827.
[3] Zhang W X.Nanoscale iron particles for environmental remediation: on overview [J]. Journal of Nanoparticle Research, 2003, 5(3/4): 323-332.
[4] Singh R, Misra V, Singh R P. Synthesis, characterization and role of zero-valent iron nanoparticle in removal of hexavalent chromium from chromium-spiked soil [J]. Journal of Nanoparticle Research, 2011, 13: 4063-4073.
[5] Wang Q, Qian H J, Yang Y P, et al. Reduction of hexavalent chromium by carboxymethyl cellulose-stabilized zero-valent iron nanoparticles [J]. Journal of Contaminant Hydrology, 2010, 114(1/2/3/4): 35-42.
[6] Geng B, Jin Z H, Li T L, et al. kinetics of hexavalent chromium removal from water by chitosan-Fe0 nanoparticles [J]. Chemosphere, 2009, 75(6): 825-830.
[7] Huang D L, Chen G M, Zeng G M, et al. Synthesis and application of modified zero-valent iron nanoparticles for removal of hexavalent chromium from wastewater [J]. Water Air and Soil Pollution, 2015, 226: 375.
[8] Wang C, Xu Z. Comprehensive study on the removal of chromate from aqueous solution by synthesized kaolin supported nanoscale zero-valent iron [J]. Desalintion and Water Treatment, 2016, 57: 5065-5078.
[9] Shi Y J, Chen C W, Dong C D, et al. Granulation for extended-release of nanoscale zerovalent iron exemplified by hexavalent chromium reduction in aqueous solution [J]. Separation
and Purification Technology, 2015, 156: 1073-1081.
[10] Fonseca B, Maio H, Quintelas C, et al. Retention of Cr(Ⅵ) and Pb (Ⅱ) on a loamy sand soil: kinetics, equilibria and breakthrough [J]. Chemical Engineering Journal, 2009, 152: 212-219.
[11] Zhang Y, Li Y, Li J, et al. Enhanced Cr(Ⅵ) removal by using the mixture of pillared bentonite and zero-valent iron [J]. Chemical Engineering Journal, 2012, 185: 243-249.
[12] Ali S W, Mirza M, Bhatti T M. Dispersion of iron nanoparticles by polymer-based hybrid material for reduction of hexavalent chromium [J]. Journal of Nanomaterials, 2015, DOI:
10.1155/2015/895837.
[13] 潘湛昌, 黄慧民, 邓淑华, 等. 间接电氧化合成山梨酸前体乙酰氧基己烯酸[J]. 现代化工, 2001, 21(11): 38-41.
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