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Effect of In-situ Annealing on Properties of CdZnTe Crystals

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  • School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China

Received date: 2013-11-07

  Online published: 2014-12-23

Abstract

CdZnTe (CZT) single crystals were grown by a modified vertical Bridgman method. After the growth was completed, the crystals were annealed at a constant temperature for a long time. Infrared microscope, I-V characteristic curves, and multi-channel spectrometer were employed to analyze Te inclusions distribution in the crystal, electrical resistivity and spectroscopy response of CZT wafers. The results show that in-situ annealing can greatly decrease concentration of Te inclusions, and most of the Te inclusion sizes are less than 5 μm. In addition, electrical resistivity of CZT is increased from 4.54×108 to 3.73×1010  after annealing. The 241Am@59.5 keV   keV keV-ray pulse height spectra of CZT crystal after in-situ annealing reaches 7.29%.

Cite this article

ZHANG Thao, MIN Jia-Hua, LIANG Xiao-Yan, TENG Jia-Qi, SHI Bin-Bin, WANG Lin-Jun . Effect of In-situ Annealing on Properties of CdZnTe Crystals[J]. Journal of Shanghai University, 2014 , 20(6) : 701 -706 . DOI: 10.3969/j.issn.1007-2861.2014.01.027

References

[1] Shin H Y, Sun C Y. Temperature-gradient-solution grown CdTe crystals for gamma-ray detectors [J].Journal of Crystal Growth, 1998, 186: 67-78.

[2] Limousin O. New trends in CdTe and CdZnTe detectors for X- and gamma-ray applications [J].

Nucl Instrument Methods Phys Res A, 2003, 504: 24-37.

[3] Hermon H, Schieber M, Lee E Y, et al. CZT detectors fabricated from horizontal and vertical

Bridgman-grown crystals [J]. Nucl Instrum Methods Phys Res A, 2001, 458: 503-510.

[4] Benson J D, Cornfeld A B, Martinka M, et al. Ellipsometric analysis of CdZnTe preparation

for HgCdTe MBE growth [J]. Journal of Crystal Growth, 1997, 175/176: 659-664.

[5] Schlesinger T E, Toney J E, Yoon H, et al. Cadmium zinc telluride and its use as a nuclear

radiation detector material [J]. Materials Science & Engineering, 2001, 32: 103-189.

[6] 朱世富, 赵北君, 王瑞林, 等. 室温半导体核辐射探测器新材料及其器件研究[J]. 人工晶体学报,

2004, 33(1): 6-12.

[7] 王东, 闵嘉华, 梁小燕, 等. 溶液法制备CdZnTe 晶体中Te 夹杂相分析[J]. 上海大学学报: 自然科

学版, 2013, 19(1): 67-70.

[8] Bolotnikov A E, Camarda G S, Carini G, et al. Performance-limiting defects in CdZnTe

detectors [J]. IEEE Transactions on Nuclear Science, 2006, 54(4): 821-827.

[9] Zeng D M, Jie W Q, Zha G Q, et al. Effect of annealing on the residual stress and strain

distribution in CdZnTe wafers [J]. Journal of Crystal Growth, 2007, 305: 50-54.

[10] Yu P F, He Y H, Wang T, et al. Characterization of detector-grade CdZnTe: Al crystals

obtained by annealing [J]. Journal of Crystal Growth , 2011, 324: 22-25.

[11] Vydyanath H R, Ellsworth J A, Fisher R F. Vapor phase equilibria in the CZT alloy

system [J]. Journal of Electron Mater, 1993, 22(8): 1067-1073.

[12] Yadava R D S, Sundersheshu B S, Anandan M, et al. Precipitation in CdTe crystals studied

through Mie scattering [J]. Journal of Electronic Materials, 1994, 23(12): 1349-1357.
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