Phase transformation and optical absorption properties of high entropy modified zirconia ceramics

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  • 1. School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China; 2. Shaoxing Research Institute, Shanghai University, Shaoxing 312074, Zhejiang, China

Received date: 2023-03-22

  Online published: 2025-03-03

Abstract

A group of zirconia-based high-entropy ceramics containing Ce, Al, Y and Si was prepared using a high-temperature sintering method, and the phase structure tran-sition and optical absorption characteristics were studied. X-ray diffractometer (XRD) results showed that the cubic zirconia phase transformation was completed at 1 450 ›. Scanning electron microscopy (SEM) results showed that the doped zirconia ceramic particles exhibited grain refinement, with a minimum average grain size of 234 nm. X-ray photoelectron spectroscopy (XPS) results showed that the oxygen vacancy concentration was positively correlated with the Ce∶Zr atomic ratio. The maximum bending strength of the sintered sample was 130.32 MPa, the minimum porosity was 0.15%, the maximum visible absorption range was 513 nm, and the minimum bandgap after doping was 2.97 eV.

Cite this article

ZHANG Yan, PENG Yuqing, ZHANG Fangzhou, WANG Qifan, NING Lixin, LI Aijun . Phase transformation and optical absorption properties of high entropy modified zirconia ceramics[J]. Journal of Shanghai University, 2025 , 31(1) : 122 -133 . DOI: 10.12066/j.issn.1007-2861.2542

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