Phase transformation and optical absorption properties of high entropy modified zirconia ceramics

  • ZHANG Yan ,
  • PENG Yuqing ,
  • ZHANG Fangzhou ,
  • WANG Qifan ,
  • NING Lixin ,
  • LI Aijun
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  • 1. School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China; 2. Shaoxing Research Institute, Shanghai University, Shaoxing 312074, Zhejiang, China

Received date: 2023-03-22

  Online published: 2025-03-03

Abstract

A group of zirconia-based high-entropy ceramics containing Ce, Al, Y and Si was prepared using a high-temperature sintering method, and the phase structure tran-sition and optical absorption characteristics were studied. X-ray diffractometer (XRD) results showed that the cubic zirconia phase transformation was completed at 1 450 ›. Scanning electron microscopy (SEM) results showed that the doped zirconia ceramic particles exhibited grain refinement, with a minimum average grain size of 234 nm. X-ray photoelectron spectroscopy (XPS) results showed that the oxygen vacancy concentration was positively correlated with the Ce∶Zr atomic ratio. The maximum bending strength of the sintered sample was 130.32 MPa, the minimum porosity was 0.15%, the maximum visible absorption range was 513 nm, and the minimum bandgap after doping was 2.97 eV.

Cite this article

ZHANG Yan , PENG Yuqing , ZHANG Fangzhou , WANG Qifan , NING Lixin , LI Aijun . Phase transformation and optical absorption properties of high entropy modified zirconia ceramics[J]. Journal of Shanghai University, 2025 , 31(1) : 122 -133 . DOI: 10.12066/j.issn.1007-2861.2542

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