Research Articles

Preparation and electrochemical properties of porous Sb$_{\mathbf 2}$O$_{\mathbf 3}$/Sb lithium-ion battery anode materials

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  • School of Materials Science and Engineering, Shanghai University, Shanghai 200444, China

Received date: 2019-12-13

  Online published: 2022-01-06

Abstract

An antimony (Sb) and Sb$_{2}$O$_{3}$ composite is prepared by mild oxidization of porous Sb. The oxidization temperature is determined through a gradient experiment, and the Sb$_{2}$O$_{3}$ content of the composite is controlled by controlling the oxidization duration. Results show that Sb contributes good conductivity and that the rate performance of the composite is enhanced, whereas Sb$_{2}$O$_{3 }$ contributes high capacity and the Li$_{2}$O produced during the conversion reaction can prevent agglomeration of Sb. As a result of the synergistic effect, the initial Coulombic efficiency of the Sb$_{2}$O$_{3}$/Sb composite is 78.2% and the retained capacity is 729.6 mAh$\cdot$g$^{-1}$ after 100 cycles at a current density of 200 mA$\cdot$g$^{-1}$. The Sb$_{2}$O$_{3}$/Sb composite sustains a capacity of 203 mAh$\cdot$g$^{-1}$ even at a current density of 10 000 mA$\cdot$g$^{-1}$. Compared with porous Sb, both the cyclic and rate performance of the Sb$_{2}$O$_{3}$/Sb composite is significantly enhanced.

Cite this article

ZHANG Haojie, HU Yemin . Preparation and electrochemical properties of porous Sb$_{\mathbf 2}$O$_{\mathbf 3}$/Sb lithium-ion battery anode materials[J]. Journal of Shanghai University, 2021 , 27(6) : 1047 -1055 . DOI: 10.12066/j.issn.1007-2861.2229

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