Research Articles

Topological structure of free energy density of nematic liquid crystals

Expand
  • 1. College of Sciences, Shanghai University, Shanghai 200444, China
    2. Shanghai Key Lab for Astrophysics, Shanghai 200234, China

Received date: 2021-06-29

  Online published: 2021-10-08

Abstract

Through the investigation to the classical expressions of free energy density of nematic liquid crystal, a surface term was added to represent the free energy of defects in liquid crystals. By means of $\phi $-mapping method and topological current theory, the new expression of free energy density which was concentrated on the defects was studied. It is shown that the free energy density concentrated on the defects is topologically quantized in the unit of $\frac{1}{2}k\pi $, and the topological quantum numbers are determined by Hopf index and Brouwer degree. The configurations of molecules of liquid crystal around the different disclination strengths of defects are also given in this paper.

Cite this article

ZHANG Canyu, YANG Guohong . Topological structure of free energy density of nematic liquid crystals[J]. Journal of Shanghai University, 2022 , 28(6) : 1094 -1105 . DOI: 10.12066/j.issn.1007-2861.2340

References

[1] Ikeda T. Photomodulation of liquid crystal orientations for photonic applications[J]. Journal of Materials Chemistry, 2003, 13(9): 2037-2057.
[2] Rodarte A L, Nuno Z S, Cao B H, et al. Tuning quantum-dot organization in liquid crystals for robust photonic applications.[J]. Chemphyschem: A European Journal of Chemical Physics and Physical Chemistry, 2014, 15(7): 1413-1421.
[3] Manda R, Pagidi S, Lim Y J, et al. Self-supported liquid crystal film for flexible display and photonic applications[J]. Journal of Molecular Liquids, 2019, 291: 111314.
[4] Lee W, Wu S T. Focus issue introduction: liquid crystal materials for photonic applications[J]. Optical Materials Express, 2011, 1(8): 1585-1587.
[5] Fernandez-Nieves A, Vitelli V, Utada A S, et al. Novel defect structures in nematic liquid crystal shells[J]. Physical Review Letters, 2007, 99(15): 157801.
[6] Coursault D, Grand J, Zappone B, et al. Linear self-assembly of nanoparticles within liquid crystal defect arrays[J]. Advanced Materials, 2012, 24(11): 1461-1465.
[7] Hess A J, Liu Q, Smalyukhi I. Optical patterning of magnetic domains and defects in ferromagnetic liquid crystal colloids[J]. Applied Physics Letters, 2015, 107(7): 071906.
[8] Suh A, Ahn H, Shin T J, et al. Controllable liquid crystal defect arrays induced by an in-plane electric field and their lithographic applications[J]. Journal of Materials Chemistry C, 2019, 7(6): 1713-1719.
[9] Kim Y H, Jeong H S, Kim J H, et al. Fabrication of two-dimensional dimple and conical microlens arrays from a highly periodic toroidal-shaped liquid crystal defect array[J]. Journal of Materials Chemistry, 2010, 20(31): 6557-6561.
[10] Yang G H, Wang Y S, Duan Y S. Contribution of disclination lines to free energy of liquid crystals in single-elastic constant approximation[J]. Communications in Theoretical Physics, 2004, 42(2): 185-188.
[11] De Gennes P, Prost J. International series of monogr: the physics of liquid crystals[M]. Boston: Oxford University Press, 1993.
[12] Nabarro N F R. Theory of crystal dislocation[M]. Boston: Oxford University Press, 1976.
[13] Yang G H, Zhang H, Duan Y S. Topological aspect and bifurcation of disclination lines in two-dimensional liquid crystals[J]. Communications in Theoretical Physics, 2002, 37(5): 513-518.
[14] Duan Y S, Yang G H, Ying J. The quantization of the space-time defects in the earlyUniverse[J]. Helvetica Physica Acta, 1997, 70(4): 565-577.
Outlines

/