Journal of Shanghai University >
Application of novel porous polyaniline in electrode material of supercapacitor
Received date: 2019-01-02
Online published: 2021-02-28
Porous polyaniline (PANI) is prepared through an efficient and cost-effective method by polymerisation of aniline in a HCl solution containing KCl. The KCl solution serves as a pseudo-template for the formation of porous PANI, thereby avoiding the use of organic solvents and hard/soft templates and thus protecting the environment. Because of its highly porous structure and intercrossed nanorods, PANI provides a large surface area, resulting in good electrochemical performance. The porous PANI electrodes show a high specific capacitance of 800 F$\cdot$g-1 prepared with saturated KCl, which is more than six times than that of PANI prepared without KCl as the pseudo-template. Thus, synthesised PANI is an excellent electrode material for supercapacitors and is of great significance in their practical application.
Key words: polyaniline (PANI); porous; supercapacitors; electrochemical property
JU Ge, KHAN Muhammad Arif, ZHENG Huiwen, AN Zhongxun, WU Mingxia, ZHAO Hongbin, XU Jiaqiang . Application of novel porous polyaniline in electrode material of supercapacitor[J]. Journal of Shanghai University, 2021 , 27(1) : 154 -160 . DOI: 10.12066/j.issn.1007-2861.2116
| [1] | Huang Y, Tang Z J, Liu Z X, et al. Toward enhancing wearability and fashion of wearable supercapacitor with modified polyurethane artificial leather electrolyte[J]. Nano-Micro Letters, 2018,10(3):38. |
| [2] | Pei Z B, Hu H B, Liang G J, et al. Carbon-based flexible and all-solid-state micro-supercapacitors fabricated by inkjet printing with enhanced performance[J]. Nano-Micro Letters, 2017,9(2):19. |
| [3] | Bhadra S, Khastgir D, Singha N K, et al. Progress in preparation, processing and applications of polyaniline[J]. Progress in Polymer Science, 2009,34(8):783-810. |
| [4] | Chiou N R, Epstein A J. Polyaniline nanofibers prepared by dilute polymerization[J]. Advanced Materials, 2005,17(13):1679-1683. |
| [5] | Li D, Huang J X, Kaner R B. Polyaniline nanofibers: a unique polymer nanostructure for versatile applications[J]. ChemInform, 2009. DOI: 10.1002/chin.200916271. |
| [6] | Wang Y Q, Shi Y, Pan L J, et al. Dopant-enabled supramolecular approach for controlled synjournal of nanostructured conductive polymer hydrogels[J]. Nano Letters, 2015,15(11):7736-7741. |
| [7] | Pan L, Yu G, Zhai D, et al. Hierarchical nanostructured conducting polymer hydrogel with high electrochemical activity[J]. Proceedings of the National Academy of Sciences of the United States of America, 2012,109(24):9287-9292. |
| [8] | Tong Y J, Huang W X, Luo J, et al. Synjournal and properties of aromatic polyimides derived from 2,2,3,3-biphenyltetracarboxylic dianhydride[J]. Journal of Polymer Science Part A: Polymer Chemistry, 1999,37(10):1425-1433. |
| [9] | Pirhady T N, Ghorbani M, Shojaei A. Controlled growth of hollow polyaniline structures: from nanotubes to microspheres[J]. Polymer, 2013,54(21):5586-5594. |
| [10] | Zhang X, Zhu J H, Haldolaarachchige N, et al. Synthetic process engineered polyaniline nanostructures with tunable morphology and physical properties[J]. Polymer, 2012,53(10):2109-2120. |
| [11] | Amarnath C A, Kim J, Kim K, et al. Nanoflakes to nanorods and nanospheres transition of selenious acid doped polyaniline[J]. Polymer, 2008,49(2):432-437. |
| [12] | Huang J X, Moore J A, Acquaye J H, et al. Mechanochemical route to the conducting polymer polyaniline[J]. Macromolecules, 2005,38(2):317-321. |
| [13] | Wei Z X, Zhang Z M, Wan M X. Formation mechanism of self-assembled polyaniline micro/nanotubes[J]. Langmuir, 2002,18(3):917-921. |
| [14] | Cho S, Shin K H, Jang J. Enhanced electrochemical performance of highly porous supercapacitor electrodes based on solution processed polyaniline thin films[J]. Applied Materials & Interfaces, 2013,5(18):9186-9193. |
/
| 〈 |
|
〉 |