Research Articles

Effect of Fe content on the crystal structure and mechanical properties of ordered Ni4Mo alloy

Expand
  • Institute of Materials, Shanghai University, Shanghai 200072, China

Received date: 2018-03-30

  Online published: 2020-03-22

Abstract

The effect of iron content on the crystal structure and mechanical properties of ordered Ni4Mo alloy has been studied in this paper. The results show that the crystal structure of the alloys is still single-phase with D1$_{\rm a}$ structure when the content of iron is less than 10% in the ordered Ni4Mo alloy. However, the crystal structure of the ordered Ni$_{70}$Mo$_{20}$Fe$_{10 }$ alloy is single phase with the face-centered cubic structure when the content of iron is 10% in the alloy. When the content of iron is increased continuously, there is a second phase with close-packed hexagonal structure precipitated in alloy. The elongation of the ordered Ni$_{70}$Mo$_{20}$Fe$_{10 }$ alloys reaches 30.9%, which is 12 times of the elongation of the ordered Ni4Mo alloys when tested in vacuum. Additionally, the hydrogen embrittlement susceptibility of the ordered Ni4Mo alloy in gaseous hydrogen is also effectively reduced by iron alloying.

Cite this article

Teng WANG, Yexin CHEN, Yaxi XIE . Effect of Fe content on the crystal structure and mechanical properties of ordered Ni4Mo alloy[J]. Journal of Shanghai University, 2020 , 26(1) : 85 -94 . DOI: 10.12066/j.issn.1007-2861.2022

References

[1] 张澜庭, 毛大立, 吴建生 . 金属间化合物在工业中的应用[J]. 上海金属, 1999,21(2):11-14.
[1] Zhang L T, Mao D L, Wu J S . The application of intermetallic compounds to industry[J]. Shanghai Metals, 1999,21(2):11-14.
[2] 陈业新 . 金属间化合物的环境氢脆[J]. 上海大学学报(自然科学版), 2011,17(4):487-502.
[2] Chen Y X . Environmental hydrogen embrittlement of intermetallics[J]. Journal of Shanghai University (Natural Science Edition), 2011,17(4):487-502.
[3] Hata S, Matsumura S, Kuwano N , et al. Short range order and its transformation to long range order in Ni$_4$Mo[J]. Acta Materialia, 1998,46(3):881-892.
[4] Cheng X Y, Lin G W, Li H G . Effect of atomic ordering on the hydrogen-induced environmental embrittlement of Ni$_4$Mo intermetallics[J]. Intermetallics, 2005,13(3/4):289-294.
[5] Cheng X Y, Wan X J . The effect of ordering on the environmental embrittlement of Ni$_4$Mo alloy[J]. Scripta Materialia, 2002,46(6):465-470.
[6] 陈爱萍, 陈业新, 万晓景 , 等. 有序度对Ni$_3$Fe合金环境氢脆的影响[J]. 材料研究学报, 2003,17(1):74-77.
[6] Chen A P, Chen Y X, Wan X J , et al. Effect of degree of order on the environmental embrittlement of Ni$_3$Fe intermetallics[J]. Chinese Journal of Materials Research, 2003,17(1):74-77.
[7] 王松, 万晓景, 姚美意 . Ni$_3$Fe的环境氢脆研究[J]. 上海大学学报 (自然科学版), 2000,6(1):25-28.
[7] Wang S, Wan X J, Yao M Y . Environmental embrittlement of Ni$_3$Fe[J]. Journal of Shanghai University (Natural Science Edition), 2000,6(1):25-28.
[8] Raman A, Schbert K . On the constitution of some alloy series related to TiAl$_3$. Ⅱ. Investigations in some T4-Zn-Al, T4-Zn-Ga-and T4-Ga-Ge systems[J]. Z Metallk, 1965,56:40-43.
[9] Liu C T, Inouye H . Control of ordered structure and ductility of (Fe,Co,Ni)$_3$V alloys[J]. Metallurgical Transactions A, 1979,10(10):1515-1525.
[10] Van Vucht J H N . Influence of radius ratio on the structure of intermetallic compounds of the AB$_3$ type[J]. Journal of the Less Common Metals, 1966,11(5):308-322.
[11] Tawancy H M . Effect of chemical compsition on the mechanical properties and ordering behavior of a Ni-Mo alloy[J]. Scripta Metall Mater, 1995,32(10):1525-1531.
[12] Beck P A. Close-packed ordered alloys [M]// N ewkirk J B, G avin R M. Advances in X-ray analysis, New York: Plenum Press, 1969: 1-21.
[13] 姚学兴, 陈南平 . (Fe,Co,Ni)$_3$V合金的组织结构与力学性能[J]. 机械工程材料, 1991,15(2):27-31.
[13] Yao X X, Chen N P . Microstructures and mechanical properties of (Fe,Co,Ni)$_3$V alloys[J]. Materials for Mechanical Engineering, 1991,15(2):27-31.
[14] Chen Y X, Yao M Y, Wan X J , et al. Effect of Fe on the environmental embrittlement of Co$_3$Ti alloy[J]. Intermetallics, 2000,8(5/6):585-588.
[15] Yao M Y, Wan X J, Chen Y X , et al. Environmental embrittlement of Fe-based, Co-based, Ni-based and Ti-based intermetallics in gaseous hydrogen[J]. Journal of Shanghai University (English Edition), 2000,4(10):169-172.
Outlines

/