中文

Journal of Shanghai University >

2021 , Vol. 27 >Issue 2: 369 - 378

DOI: https://doi.org/10.12066/j.issn.1007-2861.2157

Research Articles

Design and application of Co-Mn metal-organic-frameworks derived bimetallic sulfides as anode for lithium-ion batteries

Expand
  • School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China

Received date: 2019-03-11

  Online published: 2019-10-20

Fold

Abstract

The facile synthesis of a Co-Mn metal-organic-framework (MOF) with a porous structure is reported. The prepared bimetallic MOF was then vulcanized to obtain a porous CoS$_{2}$/MnS bimetallic composite. By comparing single metal MnS and CoS$_{2}$ materials prepared by the same method, it was observed that the CoS$_{2}$/MnS bimetal composite exhibited a petal-like porous sheet structure and a smaller particle size than that of single metal composites. When used as an electrode material in lithium-ion batteries, the CoS$_{2}$/MnS composite exhibited the best lithium storage performance among contemporary composites. It was believed that the porous petal-like structure provided a short transport pathway for lithium-ions. The synergistic combination of the two metal sulfides also effectively inhibited the rapid capacity decay caused by volume changes during cycling. In addition, the carbon skeleton derived from the MOF organic ligands further played a positive role in the enhancement of the electronic conductivity of the material.

Key words： lithium-ion batteries; bimetallic sulfides; anode materials; metal-organic-framework (MOF)

Cite this article

CHEN Hengqiao, LÜ Liping, WU Minghong . Design and application of Co-Mn metal-organic-frameworks derived bimetallic sulfides as anode for lithium-ion batteries[J]. Journal of Shanghai University, 2021 , 27(2) : 369 -378 . DOI: 10.12066/j.issn.1007-2861.2157

References

[1] Hu X, Li C, Lou X, et al. Hierarchical CuO octahedra inherited from copper metal-organic frameworks: high-rate and high-capacity lithium-ion storage materials stimulated by pseudocapacitance[J]. Journal of Materials Chemistry A, 2017,5(25):12828-12837.
[2] Li C, Chen T Q, Xu W J, et al. Mesoporous nanostructured Co$_{3}$O$_{4}$ derived from MOF template: a high-performance anode material for lithium-ion batteries[J]. Journal of Materials Chemistry A, 2015,3(10):5585-5591.
[3] Gao X, Wang B Y, Zhang Y, et al. Graphene-scroll-sheathed alpha-MnS coaxial nanocables embedded in N, S Co-doped graphene foam as 3D hierarchically ordered electrodes for enhanced lithium storage[J]. Energy Storage Materials, 2019,16:46-55.
[4] Li B S, Wang R R, Chen Z L, et al. Embedding heterostructured MnS/Co$_{1-x}$S nanoparticles in porous carbon/graphene for superior lithium storage[J]. Journal of Materials Chemistry A, 2019,7(3):1260-1266.
[5] Wang R R, Li B S, Lai L F, et al. 3D urchin-like architectures assembled by MnS nanorods encapsulated in N-doped carbon tubes for superior lithium storage capability[J]. Chemical Engineering Journal, 2019,355:752-759.
[6] Wang Y H, Zhang Y Y, Peng Y Y, et al. Physical confinement and chemical adsorption of porous C/CNT micro/nano-spheres for CoS and Co$_{9}$S$_{8}$ as advanced lithium batteries anodes[J]. Electrochimica Acta, 2019,299:489-499.
[7] Lin W J, Huang Y H, He G Q. Unique CoS hierarchitectures for high-performance lithium ion batteries[J]. Crystengcomm, 2018,20(42):6727-6732.
[8] Geng H B, Su H, Lin C H, et al. Double-layer N,S-codoped carbon protection of MnS nanoparticles enabling ultralong-life and high-rate lithium ion storage[J]. ACS Applied Energy Materials, 2018,1(9):4867-4873.
[9] Yi X L, He W, Zhang X D, et al. Hollow mesoporous MnO/MnS/SiC/S-CN composites prepared from soda pulping black liquor for lithium-ion batteries[J]. Journal of Alloys and Compounds, 2018,735:1306-1313.
[10] Lu J, Xia G, Gong S, et al. Metallic 1T phase MoS$_{2}$ nanosheets decorated hollow cobalt sulfide polyhedra for high-performance lithium storage[J]. Journal of Materials Chemistry A, 2018,6(26):12613-12622.
[11] Hong X, Kim J, Shi S F, et al. Ultrafast charge transfer in atomically thin MoS$_{2}$/WS$_{2}$ heterostructures[J]. Nat Nanotechnol, 2014,9(9):682-686.
[12] Kang W, Zhang Y, Fan L, et al. Metal-organic framework derived porous hollow Co$_{3}$O$_{4}$/N-C polyhedron composite with excellent energy storage capability[J]. ACS Appl Mater Interfaces, 2017,9(12):10602-10609.
[13] Ji D, Zhou H, Tong Y L, et al. Facile fabrication of MOF-derived octahedral CuO wrapped 3D graphene network as binder-free anode for high performance lithium-ion batteries[J]. Chemical Engineering Journal, 2017,313:1623-1632.
[14] Liu W, Yang H Z, Zhao L, et al. Mesoporous flower-like Co$_{3}$O$_{4}$/C nanosheet composites and their performance evaluation as anodes for lithium ion batteries[J]. Electrochimica Acta, 2016,207:293-300.
[15] Han X, Chen W M, Han X G, et al. Nitrogen-rich MOF derived porous Co$_{3}$O$_{4}$/N-C composites with superior performance in lithium-ion batteries[J]. Journal of Materials Chemistry A, 2016,4(34):13040-13045.
[16] Li G R, Xie C C, Shen Z R, et al. Cobalt oxide 2D nano-assemblies from infinite coordination polymer precursors mediated by a multidentate pyridyl ligand[J]. Dalton Trans, 2016,45(18):7866-7874.
[17] Zhang L M, Yan B, Zhang J H, et al. Design and self-assembly of metal-organic framework-derived porous Co$_{3}$O$_{4}$ hierarchical structures for lithium-ion batteries[J]. Ceramics International, 2016,42(4):5160-5170.
[18] Xiu Z, Alfaruqi M H, Gim J, et al. Hierarchical porous anatase TiO$_{2}$ derived from a titanium metal-organic framework as a superior anode material for lithium ion batteries[J]. Chem Commun, 2015,51(61):12274-12277.
[19] Zhang B W, Hao S J, Xiao D R, et al. Templated formation of porous Mn$_{2}$O$_{3}$ octahedra from Mn-MIL-100 for lithium-ion battery anode materials[J]. Materials & Design, 2016,98:319-323.
[20] Wang Q, Zou R, Xia W, et al. Facile Synjournal of ultrasmall CoS$_{2}$ nanoparticles within thin N-doped porous carbon shell for high performance lithium-ion batteries[J]. Small, 2015,11(21):2511-2517.
[21] Wu R, Wang D P, Rui X, et al. In-situ formation of hollow hybrids composed of cobalt sulfides embedded within porous carbon polyhedra/carbon nanotubes for high-performance lithium-ion batteries[J]. Adv Mater, 2015,27(19):3038-3044.
[22] Sun H, Xin G, Hu T, et al. High-rate lithiation-induced reactivation of mesoporous hollow spheres for long-lived lithium-ion batteries[J]. Nat Commun, 2014,5:4526.
Options
Outlines

/

〈 〉