Journal of Shanghai University(Natural Science Edition) ›› 2018, Vol. 24 ›› Issue (1): 66-73.doi: 10.12066/j.issn.1007-2861.1768

• Research Articles • Previous Articles     Next Articles

Synthesis and self-assembly of Boc-protected bisguanidines

ZOU Xiaoliang, GU Jun, SUN Yuren, QIAN Qun()   

  1. College of Sciences, Shanghai University, Shanghai 200444, China
  • Received:2016-03-25 Online:2018-02-28 Published:2018-03-05
  • Contact: QIAN Qun E-mail:qianqun@shu.edu.cn

Abstract:

Guanidinium cations are widely used to recognize sulfate and phosphate anions. However, there are few reports about neutral guanidines. In this work, several Boc-protected guanidines are synthesized. With nuclear magnetic resonance (NMR) dilution experiments and single crystal X-ray diffraction. It has been found that there are intermolecular interaction among neutral bisguanidinium in solution and solid state as well.

Key words: guanidine, self-assembly, nuclear magnetic resonance (NMR) dilution experiment

CLC Number: