CMK-3 介孔碳材料的功能化及其湿敏性能

doi:10.12066/j.issn.1007-2861.2262

Abstract

Abstract:

Mesoporous materials are widely used in several fields, such as energy storage, catalysis, and humidity sensors. In this study, ordered mesoporous silicon SBA-15 is used as a template to prepare CMK-3 mesoporous carbon materials with specific surface areas greater than 1 000 m²/g using a nanocasting method. The carbon materials are then modified by carboxyl functionalisation using ammonium persulfate. Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), small-angle X-ray diffraction (XRD), and Brunauer-Emmet-Teller (BET) nitrogen adsorption and desorption methods are used to characterise the materials. Results show that both before and after functionalisation, CMK-3 mesoporous carbon materials have favourable ordered mesoporous structures. Using a quartz crystal microbalance (QCM) test platform, the humidity sensing performances of the materials are tested. Results show that after carboxyl functional modification, the materials exhibit a high response to different humidity environments, and their humidity response is clearly enhanced. Particularly in a 97% RH high-humidity environment, a remarkable response of as high as 1 600 Hz is obtained, which proves beneficial to the application of CMK-3 humidity sensitive materials in high-humidity environments.

Key words: ordered mesoporous carbon, carboxyl functionalisation, quartz crystal microbalance (QCM), humidity sensor, CMK-3

CLC Number:

TP212.2

ZHANG Zhiwei, FAN Yu, MA Zhiheng, LI Runlong, HAO Chenran, XU Jiaqiang. Synthesis of functionalised CMK-3 ordered mesoporous carbon materials and their humidity sensitivity performance[J]. Journal of Shanghai University（Natural Science Edition）, 2022, 28(1): 102-110.

Figures/Tables 7

Fig. 1

Fig. 2

Fig. 3

Fig. 4

Fig. 5

Fig. 6

Fig. 7

References 30

[1]	Corma A. From microporous to mesoporous molecular sieve materials and their use incatalysis[J]. Chemical Reviews, 1997, 97(6): 2373-2420. doi: 10.1021/cr960406n
[2]	Melero J A, van Grieken R, Morales G. Advances in the synjournal and catalytic applications of organosulfonic-functionalized mesostructured materials[J]. Chemical Reviews, 2006, 106(9): 3790-3812. pmid: 16967921
[3]	Meng Y, Chen D, Jiao X. Fabrication and characterization of mesoporous Co$_3$O$_4$ core/mesoporous silica shell nanocomposites[J]. Journal of Physical Chemistry B, 2006, 110(31): 15212-15217. doi: 10.1021/jp0626465
[4]	Herranz T, Rojas S, Pérez-Alonso F J, et al. Carbon oxide hydrogenation over silica-supported iron-based catalysts: influence of the preparation route[J]. Applied Catalysis A General, 2006, 308: 19-30. doi: 10.1016/j.apcata.2006.04.007
[5]	Algarra M, Victoria J, RodríGuez-CastellóN E, et al. Heavy metals removal from electroplating wastewater by aminopropyl-Si MCM-41[J]. Chemosphere, 2005, 59(6): 779-786. pmid: 15811406
[6]	Park Y, Yi J, Kang T. Highly selective adsorption of Pt$^{2+}$ and Pd$^{2+}$ using thiol-functionalized mesoporous silica[J]. Industrial & Engineering Chemistry Research, 2004, 43(6): 1478-1484. doi: 10.1021/ie030590k
[7]	Zhao J, Gao F, Fu Y, et al. Biomolecule separation using large pore mesoporous SBA-15 as a substrate in high performance liquid chromatography[J]. Chemical Communications, 2002(7): 752-753.
[8]	Vallet-Regi M, Rámila A, Del-Real R P, et al. A new property of MCM-41: drug delivery system[J]. Chemistry of Materials, 2001, 13(2): 308-311. doi: 10.1021/cm0011559
[9]	Zhao W, Gu J, Zhang L, et al. Fabrication of uniform magnetic nanocomposite spheres with a magnetic core/mesoporous silica shell structure[J]. Journal of the American Chemical Society, 2005, 127(25): 8916-8917. doi: 10.1021/ja051113r
[10]	Giri S, Trewyn B G, Stellmaker M P, et al. Stimuli-responsive controlled-release delivery system based on mesoporous silica nanorods capped with magnetic nanoparticles[J]. Angewandte Chemie International Edition, 2005, 44(32): 5038-5044. doi: 10.1002/(ISSN)1521-3773
[11]	Zhu Y, Cheng Z, Xiang Q, et al. Rational design and synjournal of aldehyde-functionalized mesoporous SBA-15 for high-performance ammonia sensor[J]. Sensors and Actuators B: Chemical, 2017, 256: 888-895. doi: 10.1016/j.snb.2017.10.029
[12]	Qian N, Duan Z, Zhu Y, et al. 4, 4$^{\prime}$-diaminodiphenyl sulfone functionalized SBA-15: toluene sensing properties and improved proton conductivity[J]. Journal of Physical Chemistry C, 2014, 118(4): 1879-1886. doi: 10.1021/jp406688c
[13]	Zhu Y H, Yuan H, Xu J Q, et al. Highly stable and sensitive humidity sensors based on quartz crystal microbalance coated with hexagonal lamelliform monodisperse mesoporous silica SBA-15 thin film[J]. Sensors and Actuators B: Chemical, 2010, 144: 164-169. doi: 10.1016/j.snb.2009.10.053
[14]	Zhu Y H, Li H, Xu J Q, et al. Amine-functionalized SBA-15 with uniform morphology and well-defined mesostructured for highly sensitive chemosensors to detect formaldehyde vapor[J]. Langmuir, 2012, 28: 7843-7850. doi: 10.1021/la300560j
[15]	Ryoo R, Joo S H, Kruk M, et al. Ordered mesoporous carbons[J]. Advanced Materials, 2001, 13(9): 677-681. doi: 10.1002/1521-4095(200105)13:9<>1.0.CO;2-3
[16]	Jun S, Joo S H, Ryoo R M, et al. Synjournal of new, nano-porous carbon with hexagonally ordered mesostructured[J]. Journal of the American Chemical Society, 2000, 122(43): 10712-10713. doi: 10.1021/ja002261e
[17]	Jia Y, Sun C H, Cheng L N, et al. Destabilization of Mg-H bonding through nano-interfacial confinement by unsaturated carbon for hydrogen desorption from MgH$_{2}$[J]. Physical Chemistry Chemical Physics, 2013, 15(16): 5814-5820. doi: 10.1039/c3cp50515d pmid: 23487042
[18]	Wahab M A, Jia Y, Yang D J, et al. Enhanced hydrogen desorption from Mg(BH$_{4})_{2}$ by combining nanoconfinement and a Ni catalyst[J]. Journal of Materials Chemistry A, 2013, 1(10): 3471-3478. doi: 10.1039/c2ta00899h
[19]	Yu X, Tang Z, Sun D, et al. Recent advances and remaining challenges of nanostructured materials for hydrogen storage applications[J]. Progress in Materials Science, 2017, 88: 1-48. doi: 10.1016/j.pmatsci.2017.03.001
[20]	Bazula P A, Lu A H, Nitz J, et al. Surface and pore structure modification of ordered mesoporous carbons via a chemical oxidation approach[J]. Microporous & Mesoporous Materials, 2008, 108(1/2/3): 266-275.
[21]	Lu A H, Li W C, Matoussevitch N, et al. Highly stable carbon-protected cobalt nanoparticles and graphite shells[J]. Chemical Communications, 2005, 1(1): 98-100.
[22]	Vinu A, Hossian K Z, Srinivasu P, et al. Carboxy-mesoporous carbon and its excellent adsorption capability for proteins[J]. Journal of Materials Chemistry, 2007, 17(18): 1819-1825. doi: 10.1039/b613899c
[23]	Srinivasu P, Balasubramanian V, Kumaresan L, et al. Carboxyl group functionalization of mesoporous carbon nanocage through reaction with ammonium persulfate[J]. Journal of Nanoscience and Nanotechnology, 2007, 7(9): 3250-3256. pmid: 18019158
[24]	任杰, 何永红, 高志贤. 压电生物传感器研究进展[J]. 生物技术通讯, 2004, 5: 92-95.
[25]	King H W. Piezoelectric sorption detector.[J]. Analytical Chemistry, 1964, 36(9): 1735-1739. doi: 10.1021/ac60215a012
[26]	King H W. Monitoring of hydrogen, methane, and hydrocarbons in the atmosphere[J]. Environmental Science & Technology, 1970, 4(12): 1136-1141. doi: 10.1021/es60047a008
[27]	Yuan Z, Tai H, Bao X, et al. Enhanced humidity-sensing properties of novel graphene oxide/zinc oxide nanoparticles layered thin film QCM sensor[J]. Materials Letters, 2016, 174: 28-31. doi: 10.1016/j.matlet.2016.01.122
[28]	Yao Y, Zhang H, Sun J, et al. Novel QCM humidity sensors using stacked black phosphorus nanosheets as sensing film[J]. Sensors & Actuators B: Chemical, 2017, 244: 259-264.
[29]	Zhang Y, Yu K, Xu R, et al. Quartz crystal microbalance coated with carbon nanotube films used as humidity sensor[J]. Sensors & Actuators A: Physical, 2005, 120: 142-146.
[30]	武月桃, 樊煜, 刘艳丽, 等. MIL-125(Ti) 及其氨基功能化材料修饰石英晶体微天平的湿敏性能[J]. 无机化学学报, 2019, 35(4): 635-642.

Synthesis of functionalised CMK-3 ordered mesoporous carbon materials and their humidity sensitivity performance

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 7

References 30

Related Articles 0

Recommended Articles

Metrics

Comments