以嘉陵江流域及其梯级开发河段为研究对象, 通过在2008 年8 月(雨季) 及2009 年2 月(旱季) 进行密集采样, 分析测定了河水中溶解无机碳(dissolved inorganic carbon, DIC)含量及其同位素组成, 探讨了河水中DIC的来源及其季节与空间变化特征. 结果表明: 嘉陵江河水DIC 及其同位素13CDIC 组成的平均值, 雨季时为2 018 μmol/L 和−8.6‰, 旱季时为3 150 μmol/L 和−6.0‰, 二者均存在显著的季节变化; 嘉陵江水体13CDIC 的值旱季(枯水期) 高于雨季(丰水期), 与自然河流的季节变化特征相似, 而与水库、湖泊不同, 表明嘉陵江梯级水库群水体“湖沼学反应”并不明显.
The Jialing River and its cascade reservoirs were investigated. Wedensely collected water samples along the Jialing River in August 2008 (rain season) and February 2009 (dry season). We determine the contents and isotopic compositions of dissolved inorganic carbon (DIC), and discuss the sources and spatio-temporal variations of DIC. The results show that the average DIC and 13CDIC were 2 018 μmol/L and −8.6‰ in a rainy season, and 3 150 μmol/L and −6.0‰ in a dry season, showing obvious seasonal variations. The 13CDIC values in winter were heavier than in summer, similar to undammed rivers but different from lakes and reservoirs. This indicates that the hydro-geochemical characteristics of waters in the cascade reservoirs of Jialing River are similar to natural rivers
[1] Meybeck M. Carbon, nitrogen, and phosphorus transport by world rivers [J]. American Journal of Science, 1982, 282(4): 401-450.
[2] Josette G, Leporcq B, Sanchez N, et al. Biogeochemical mass-balances (C, N, P, Si) in three large reservoirs of the Seine Basin (France) [J]. Biogeochemistry, 1999, 47(2): 119-146.
[3] Syvitski J P M, V¨or¨osmarty C J, Kettner A J, et al. Impact of humans on the flux of terrestrial sediment to the global coastal ocean [J]. Science, 2005, 308: 376-380.
[4] Milliman J D. Blessed dams or damned dams? [J]. Nature, 1997, 386: 325-327.
[5] Zhang J, Zhang Z F, Liu S M, et al. Human impacts on the large world rivers: Would the Changjiang (Yangtze River) be an illustration? [J]. Global Biogeochemical Cycles, 1999, 13:
1099-1105.
[6] Kelly V J. Influence of reservoirs on solute transport: a regional-scale approach [J]. Hydrological Processes, 2001, 15: 1227-1249.
[7] Nilsson C, Reidy C A, Dynesius M, et al. Fragmentation and flow regulation of the world’s large river systems [J]. Science, 2005, 308(5720): 405-408.
[8] Friedl G, W¨uest A. Disrupting biogeochemical cycles-Consequences of damming [J]. Aquatic Sciences, 2002, 64(1): 55-65.
[9] Humborg C, Blomqvist S, Avsam E, et al. Hydrological alterations with river damming in northern Sweden: Implications for weathering and river biogeochemistry [J]. Global Biogeochemical Cycles, 2002, 16(3): 12-1-12-13.
[10] 陈庆伟, 刘兰芬, 刘昌明. 筑坝对河流生态系统的影响及水库生态调度研究[J]. 北京师范大学学报 (自然科学版), 2007, 43(5): 578-582.
[11] 刘丛强, 汪福顺, 工雨春, 等. 河流筑坝拦截的水环境响应——来自地球化学的视角[J]. 长江流域资 源与环境, 2009, 18(4): 384-396.
[12] 冉祥滨, 于志刚, 姚庆祯, 等. 水库对河流营养盐滞留效应研究进展[J]. 湖泊科学, 2009, 21(5):614-622.
[13] 张恩仁, 张经. 三峡水库对长江N、P营养盐截留效应的模型分析[J]. 湖泊科学, 2003, 15(1): 41-48.
[14] Aucour A M, Sheppard S M F, Guyomar O, et al. Use of 13C to trace origin and cycling of inorganic carbon in the Rhˆone river system [J]. Chemical Geology, 1999, 159: 87-105.
[15] Barth J A C, Veizer J. Carbon cycle in St. Lawrence aquatic ecosystems at Cornwall (Ontario),Canada: seasonal and spatial variations [J]. Chemical Geology, 1999, 159: 107-128.
[16] Das A, Krishnaswami S, Bhattacharva S K. Carbon isotope ratio of dissolved inorganic carbon (DIC) in rivers draining the Deccan Traps, India: sources of DIC and their magnitudes
[J]. Earth and Planetary Science Letters, 2005, 236(1/2): 419-429.
[17] H´elie J F, Hillaier-Marcel C, Rondeau B. Seasonal changes in the sources and fluxes of dissolved inorganic carbon through the St. Lawrence River—isotopic and chemical constraint
[J]. Chemical Geology, 2002, 186: 117-138.
[18] Wachniew P, R´o˙za´nki K. Carbon budget of a mid-latitude, groundwater-controlled lake: isotopic evidence for the importance of dissolved inorganic carbon recycling [J]. Geochimica et Cosmochimica Acta, 1997, 61(12): 2453-2465.
[19] Wang X F, Veizer J. Respiration-photosynthesis balance of terrestrial aquatic ecosystems, Ottawa area,Canada [J]. Geochimica et Cosmochimica Acta, 2000, 64(22): 3775-3786.
[20] 喻元秀, 刘丛强, 汪福顺, 等. 乌江流域梯级水库中溶解无机碳及其同位素分异特征[J]. 科学通报,2008, 53(16): 1935-1941.
[21] 喻元秀, 汪福顺, 王宝利, 等. 溶解无机碳及其同位素组成特征对初期水库过程的响应——以新建水库(洪家渡) 为例[J]. 矿物学报, 2009, 29(2): 268-274.
[22] 李干蓉, 刘丛强, 陈椽, 等. 猫跳河流域梯级水库夏-秋季节溶解无机碳(DIC) 含量及其同位素组成的分布特征[J]. 环境科学, 2009, 30(10): 2891-2897.
[23] 李铁松, 张桥英. 嘉陵江的起源及流域自然环境研究[J]. 四川师范学院学报(自然科学版), 1996,20(2): 105-108.
[24] Atekwanae A, Krishnamurthy R V. Seasonal variations of dissolved inorganic carbon and 13C of surface waters: application of a modified gas evolution technique [J]. Journal of Hydrology,1998, 205(3/4): 265-278.
[25] 鲍丽然, 李晓东, 刘小龙. 嘉陵江河水主要离子化学组成的时间和空间变化特征[J]. 水利水电科技进展, 2010, 30(4): 35-40.
[26] 刘丛强. 生物地球化学过程与地表物质循环——西南喀斯特流域侵蚀与生源要素循环[M]. 北京: 科学出版社, 2007: 187-192.
[27] 吴起鑫, 韩贵琳, 唐杨. 三峡水库坝前水体水化学及溶解无机碳时空分布特征[J]. 环境科学学报,2012, 32(3): 654-661.