材料科学与工程

H2S电化学气体传感器的敏感特性评价

展开
  • 1. 上海大学 材料科学与工程学院, 上海 200072; 2. 华瑞科学仪器(上海)有限公司, 上海 201815

收稿日期: 2014-02-25

  网络出版日期: 2015-02-28

基金资助

国家自然科学基金资助项目(11275122)

Sensitive characteristics evaluation of electrochemical H2S gas sensor

Expand
  • 1. School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China; 2. RAE Systems (Shanghai) Co. Ltd., Shanghai 201815, China

Received date: 2014-02-25

  Online published: 2015-02-28

摘要

利用六西格玛(six sigma)统计工具对电化学硫化氢(H2S)气体传感器的气体敏感特性进行了研究, 并运用Minitab 软件对测试数据进行了系统分析. 结果显示, 所测电化学气体传感器对H2S气体响应良好, 灵敏度平均值为0.82 μA/10−6H2S. 在H2S 传感器的量程范围(0∽100×10−6)内, 传感器的响应输出值与H2S 气体体积分数呈现良好的线性关系, 相关指数RSq=99.9%; 传感器对气体的响应速度较快, 响应时间T90 < 20 s. 同时讨论了温度变化对H2S 传感器灵敏度和响应输出值的影响.

本文引用格式

于文双1, 刘玲2, 郭昀1, 衣志伟2, 钱永彪2 . H2S电化学气体传感器的敏感特性评价[J]. 上海大学学报(自然科学版), 2015 , 21(1) : 46 -53 . DOI: 10.3969/j.issn.1007-2861.2014.03.003

Abstract

The sensitive characteristics of electrochemical H2S sensor are studied by applying six sigma statistical tools. The Minitab software is used to analyze the experimental data. The results show that the gas sensor has a quick response to H2S gas, the average sensitivity is 0.82 μA/10−6H2S, the gas sensor has a good linear relationship with concentration of H2S in the measurement range of the sensor, the correlation index RSq = 99.9%, and the response time T90 < 20 s. The influences of temperature on sensitivity and on the average response value of H2S sensor are also discussed.

参考文献

[1] 刘希颖, 赵越. 畜舍中有毒有害气体对畜禽的危害及防治[J]. 饲料工业, 2004, 25(10): 58-60.

[2] 王米, 孟新宇, 赵枝新, 等. 氨气对畜禽养殖业的危害及防治措施[J]. 饲料博览, 2006(7): 38-41.

[3] Sedlak J M, Blurton K F. Electrochemical determination of hydrogen sulphide in air [J]. Talanta, 1976, 23: 445-448.

[4] Bergman I. The voltammetry of some oxidising and reducing toxic gases direct from the gas phase, at gold and platinum metallised-membrane electrodes in acid and alkali [J]. J Electroanal Chem, 1983, 157: 59-73.

[5] Opekar F, Bruckenstein S. Determination of gaseous hydrogen sulfide by cathodic stripping voltammetry after preconcentration on a silver metalized porous membrane electrode [J]. Anal Chem, 1984, 56: 1206-1209.

[6] Taniguchi M, Wakihara M, Uchida T, et al. Sulfur gas sensor using a calcium fluoride solid electrolyte [J]. J Electrochem Soc, 1988, 135: 217-221.

[7] Smith D J, Velelino J F, Falconer R S, et al. Stability, sensitivity and selectivity of tungsten trioxide films for sensing applications [J]. Sensors and Actuators B: Chemical, 1993, 13: 264-268.

[8] Ando M, Suto S, Suzuki T, et al. H2S and CH3SH sensor using a thick-film of gold-loaded tungsten-oxide [J]. Chemistry Letters, 1994, 266: 335-338.

[9] Ando M, Suto S, Suzuki T, et al. Hydrogen sulfide sensing characteristics of tin oxide solderived thin films [J]. J Ceram Soc Jpn, 1996, 104: 409-414.

[10] Ando M, Tsuchida T, Miura N, et al. Influences of microstructure on hydrogen sulfide sensing characteristics of tin dioxide films [J]. Nippon Kagaku Kaishi, 1996, 4: 348-353.

[11] 车建国, 何桢. 六西格玛管理在企业中的应用[J]. 工程机械, 2006, 37(11): 74-75.

[12] 何桢, 梁昭磊, 邹峰. 六西格玛设计模式及其应用[J]. 工程机械, 2006, 37(7): 62-65.

[13] 何桢, 张志红. 精益与六西格玛的结合研究[J]. 工业工程, 2006, 9(3): 5-8.

[14] 马林, 何桢. 六西格玛管理[M]. 2 版. 北京: 中国人民大学出版社, 2007: 1-102.

[15] 夏林. 巧用MINITAB 软件中的箱线图评价镀层均匀性[J].中国高新技术企业, 2013, 12: 62-63.

[16] 杜运通. 线性回归模型在磁通量指标转换上的应用[J]. 中国科技信息, 2013, 14: 61-74.

[17] 龚立雄, 刘娅. 基于Minitab 的生产过程质量特性分析与控制[J]. 重庆理工大学学报: 自然科学版, 2013, 27(2): 69-73.

[18] 石金宝, 魏复盛. 定电位电解传感器的特点与应用[J]. 中国环境监测, 1998, 14(2): 45-47.

[19] 张小水, 古瑞琴, 李志刚, 等. 定电位电解型电化学气体传感器稳定性研究[J]. 陶瓷学报, 2008, 29(3): 286-289.

[20] Moseley P T, Norris J O W, Williams D E. Techniques and mechanisms in gas sensing [M]. Bristol: Adam Hilger, 1991: 161-188.

[21] 马逢时, 周暐, 刘传冰. 六西格玛管理统计指南: MINITAB 使用指导[M]. 北京: 中国人民大学出版社, 2007: 255-311.
文章导航

/