特稿

基于Si3N4 探针的单晶硅表面小线宽结构的摩擦诱导纳米加工

展开
  • 西南交通大学牵引动力国家重点实验室摩擦学研究所, 成都610031
钱林茂(1971—), 男, 教授, 博士生导师, 博士, 研究方向为纳米摩擦学和微纳制造等. E-mail: linmao@swjtu.edu.cn

收稿日期: 2014-10-25

  网络出版日期: 2014-12-23

基金资助

国家自然科学基金资助项目(91323103, 51175441)

Friction-Induced Nanofabrication of Small Line-Width Structure on Silicon Surface Based on Si3N4 Probe

Expand
  • Tribology Research Institute, National Traction Power Laboratory,Southwest Jiaotong University, Chengdu 610031, China

Received date: 2014-10-25

  Online published: 2014-12-23

摘要

针对传统纳米加工方法存在的操作复杂和成本昂贵等问题, 提出采用以表面自然氧化层作为掩膜, 结合Si3N4 探针扫描和KOH 溶液后续选择性刻蚀的摩擦诱导纳米加工方法. 基于针尖半径对加工线宽影响的规律, 实现了单晶硅表面较小线宽沟槽结构的加工. 在此基础上, 通过研究沟槽深度随刻蚀时间的变化规律, 确定了最佳的刻蚀加工时间, 并详细研究了载荷以及针尖扫描次数对表面沟槽结构加工的影响规律. 该方法无需专门制备掩膜, 操作简单,有望应用于加工功能表面织构、表面微阀、微反应器及单电子器件等,为纳米结构的加工提供了新途径.

本文引用格式

姚洋洋, 陈磊, 郭剑, 钱林茂 . 基于Si3N4 探针的单晶硅表面小线宽结构的摩擦诱导纳米加工[J]. 上海大学学报(自然科学版), 2014 , 20(6) : 669 -679 . DOI: 10.3969/j.issn.1007-2861.2014.04.006

Abstract

Talking into account limitations of traditional nanofabrication approaches such as complicated manipulation and high cost, a new friction-induced fabrication method is proposed. With the native oxidation layer as etching “mask”, nanofabrication of silicon can be achieved by scanning with a Si3N4 probe and subsequent selective etching in KOH solution. By optimization of the tip radius, the groove structure with small line-width can be realized on monocrystalline silicon surface. Then, etching time dependence of groove depth is investigated to determine the best etching time for fabricating nanostructure.Finally, the effect of applied load and number of sliding cycles on nanostructure fabrication is studied. As a maskless and simple method, the proposed nanofabrication approach makes possible to fabricate surface texture with special functions, micromechanical valves for fluidic manipulation, single-electron devices, etc. With these advantages and potential applications, the direct fabrication method provides opportunities for nanofabrication

参考文献

[1] Carr D W, Sekaric L, Craighead H G. Measurement of nanomechanical resonant structures

in single-crystal silicon [J]. Journal of Vacuum Science & Technology B, 1998, 16: 3821-3824.

[2] Evoy S, Carr D W, Sekaric L, et al. Nanofabrication and electrostatic operation of singlecrystal

silicon paddle oscillators [J]. Journal of Applied Physics, 1999, 86: 6072-6077.

[3] Carr D W, Evoy S, Sekaric L, et al. Measurement of mechanical resonance and losses in

nanometer scale silicon wires [J]. Applied Physics Letters, 1999, 75: 920-922.

[4] Pepin A, Youinou P, Studer V, et al. Nanoimprint lithography for the fabrication of DNA

electrophoresis chips [J]. Microelectronic Engineering, 2002, 61(2): 927-932.

[5] Resnick D J, Dauksher W J, Mancini D, et al. Imprint lithography for integrated circuit

fabrication [J]. Journal of Vacuum Science & Technology B, 2003, 21(6): 2624-2631.

[6] Garnett E, Yang P D. Light trapping in silicon nanowire solar cells [J]. Nano Letters, 2010,

10: 1082-1087.

[7] 崔铮. 微纳米加工技术及其应用[M]. 3 版. 北京: 高等教育出版社, 2013.

[8] 王国彪. 纳米制造前言综述[M]. 北京: 科学出版社, 2009.

[9] Miyake S, Kim J. Fabrication of silicon utilizing mechanochemical local oxidation by diamond

tip sliding [J]. Japanese Journal of Applied Physics, 2001, 40(11B): 1247-1249.

[10] Miyake S, Kim J. Nanoprocessing of silicon by mechanochemical reaction using atomic force microscopy

and additional potassium hydroxide solution etching [J]. Nanotechnology, 2005, 16(1):

149-157.

[11] Ren S L, Yang S R, Zhao Y P. Micro- and macro-tribological study on a self-assembled duallayer

film [J]. Langmuir, 2003, 19: 2763-2767.

[12] Song C F, Li X Y, Yu B J, et al. Friction-induced nanofabrication method to produce protrusive

nanostructures on quartz [J]. Nanoscale Research Letters, 2011, 6: 310.

[13] Tang P, Yu B J, Guo J, et al. Maskless micro/nanofabrication on GaAs surface by frictioninduced

selective etching [J]. Nanoscale Research Letters, 2014, 9: 59.
[14] Yu B J, Dong H S, Qian L M, et al. Friction-induced nanofabrication on monocrystalline

silicon [J]. Nanotechnology, 2009, 20(46): 465303.

[15] Yu B J, Qian L M, Dong H S, et al. Friction-induced hillocks on monocrystalline silicon in

atmosphere and in vacuum [J]. Wear, 2010, 68: 1095-1102.

[16] Guo J, Song C F, Li X Y, et al. Fabrication mechanism of friction-induced selective etching on

Si(100) surface [J]. Nanoscale Research Letters, 2012, 7: 152.

[17] Guo J, Yu B J, Wang X D, et al. Nanofabrication on monocrystalline silicon through frictioninduced

selective etching of Si3N4 mask [J]. Nanoscale Research Letters, 2014, 9(1): 241.

[18] Ebrahimi F, Kalwani L. Fracture anisotropy in silicon single crystal [J]. Materials Science

and Engineering A: Structural Materials Properties Microstructure and Processing, 1999, 268:

116-126.

[19] Yu J X, Qian L M, Yu B J, et al. Effect of surface hydrophilicity on the nanofretting behavior

of Si(100) in atmosphere and vacuum [J]. Journal of Applied Physics, 2010, 108: 034314.

[20] Maw W, Stevens F, Langford S C, et al. Single asperity tribochemical wear of silicon nitride

studied by atomic force microscopy [J]. Journal of Applied Physics, 2002, 92(9): 5103-5109.

[21] Katsuki F. Single asperity tribochemical wear of silicon by atomic force microscopy [J]. Journal

of Materials Research, 2009, 24(l): 173-175.

[22] Mizuhara K, Hsu S M. Tribochemical reaction of oxygen and water on silicon surfaces [J].

Tribol Series, 1992, 21: 323-328.

[23] Beyer M K. The mechanical strength of a covalent bond calculated by density functional

theory [J]. Journal of Chemical Physics, 2000, 112(17): 7307-7312.

[24] Youn S W, Kang C G. Maskless pattern fabrication on Pyrex 7740 glass surface by using

nano-scratch with HF wet etching [J]. Scripta Materialia, 2005, 52(2): 117-122.

[25] Park J W, Lee S S, So B S, et al. Characteristics of mask layer on (100) silicon induced by

tribo-nanolithography with diamond tip cantilevers based on AFM [J]. Journal of Materials

Processing Technology, 2007, 187: 321-325.
文章导航

/