环境与化学工程

氧化石墨烯-壳聚糖复合材料对甲烯蓝的吸附动力学

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  • (西南民族大学化学与环境保护工程学院, 成都610041)
杨胜韬(1985—), 男, 博士, 研究方向为纳米材料的制备、应用与安全性. E-mail: yangst@pku.edu.cn

网络出版日期: 2013-08-27

基金资助

西南民族大学中央高校基本科研业务费专项资金资助项目(13NZYQN14)

Adsorption Kinetics of Methylene Blue on Graphene Oxide-Chitosan Composite

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  • (College of Chemistry and Environment Protection Engineering, Southwest University for Nationalities,
    Chengdu 610041, China)

Online published: 2013-08-27

摘要

氧化石墨烯-壳聚糖复合材料(graphene oxide-chitosan composite, GO-CS) 可用于清除阳离子染料, 具有吸附量大、易于分离等优点. 对GO-CS吸附阳离子染料甲烯蓝的动力学进行了研究, 结果显示, GO-CS对甲烯蓝的吸附符合二级动力学模型. 颗粒内扩散模型分析表明, GO-CS 吸附甲烯蓝的扩散机制包括颗粒内扩散和表面扩散.此外, 还发现GO-CS 对甲烯蓝的吸附量受pH 值和离子强度的影响, 较高的pH 值和离子强度有利于提高吸附量.

本文引用格式

徐静, 闻宏亮, 欧阳建波, 王宁, 杨胜韬 . 氧化石墨烯-壳聚糖复合材料对甲烯蓝的吸附动力学[J]. 上海大学学报(自然科学版), 2013 , 19(4) : 400 -404 . DOI: 10.3969/j.issn.1007-2861.2013.04.013

Abstract

Graphene oxide-chitosan composite (GO-CS) is powerful in decoloration of cationic dyes. GO-CS holds several advantages including high adsorption capacity and easy separation after adsorption. This paper investigates the adsorption kinetics of methylene blue on GO-CS. The adsorption process is nicely described by a pseudo-second-order model. The diffusion mechanism includes intraparticle diffusion and surface diffusion.The adsorption capacity of GO-CS can be regulated by pH and ionic strength, where higher pH and ionic strength were preferred.

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