采用共沉淀法和浸渍法制备聚丙烯腈(polyacrylonitrile,PAN)/多金属氧化铁复合光解水催化剂.傅里叶变换红外光谱分析仪（Fourier transform infrared spectroscopy，FTIR）表征表明，热处理后的聚丙烯腈发生了热环化反应，其功能基团与金属离子间具有较强的相互作用.X射线衍射（X-ray diffraction,XRD）表征表明，催化体系中的氧化铁主要为立方晶系，铜、镍及钯均以氧化物形态存在.在光催化反应中，催化剂表现出了较好的催化效果，最高催化产氢速率达到714.3 μmol/(g·h).

Polyacrylonitrile (PAN)/polymetalliciron oxides used as photocatalysts for water splitting were prepared by coprecipitation and impregnation methods. Fourier transform infrared spectroscopy (FTIR) showed that the cyclic structures were formed in the PAN chains after heat treatment. The functional groups of PAN showed strong interactions with metal ions. According to X-ray diffraction (XRD) characterizations, iron oxides were Fe₃O₄ cubic crystalline in the photocatalysts, and other metal ions existed as their relative oxides. Photocatalysis for water splitting into H₂ presented efficient activity and the optimum rate reached 714.3 μmol/(g·h).