云冈石窟开凿于砂岩地层中,具有极其重要的文物价值,但因长期遭受自然因素影响,风化现象十分严重.针对第9窟诵经道北壁,综合采用微波测湿、显微和X射线荧光等技术开展无损检测,获取岩壁的水分时空分布、溶液化学性质以及砂岩风化特征,并结合环境条件探讨水岩作用影响下的砂岩劣化机理.结果表明,岩壁含水量分布存在时空差异,底部普遍比上部潮湿,降雨导致的空气相对湿度波动会引起浅表层砂岩含水量的明显变化,并且在表面出现水膜覆盖和水滴附着现象;风化砂岩内含有大量可溶盐,壁面水溶液呈碱性,主要化学元素包括Mg、S、Na、Ca、Cl、K,其中Mg、S含量远高于其他元素;风化病害形式以粉状和片状为主,微观结构多为疏松、开裂状态,颜色差异与物质组成有关;干湿循环和化学溶蚀是造成诵经道壁面风化的关键因素.研究成果可为类似的石质文物预防性保护提供数据支持和理论参考.
The Yungang Grottoes, carved into sandstone strata, are culturally significant heritage sites. However, prolonged exposure to natural elements has led to considerable weathering. Focusing on the north wall of the Chanting Corridor in Cave 9,nondestructive testing was performed using a combination of microwave moisture measurement, microscopy, and X-ray fluorescence techniques. This study examines the spatiotemporal distribution of moisture, chemical properties of aqueous solutions, and characteristics of sandstone weathering on the walls. Considering environmental conditions,the study also discusses the deterioration mechanisms of sandstone resulting from waterrock interactions. The results showed that the moisture distribution on the wall exhibited spatial heterogeneity, with the lower regions being consistently more humid than the upper regions. Rainfall-induced fluctuations in the ambient relative humidity significantly affected the moisture content of the shallow sandstone layers, resulting in the formation of continuous water films and droplets on the surface. The weathered sandstone contained a high concentration of soluble salts, and the aqueous solution on the wall exhibited an alkaline nature. The primary chemical elements in the solution were Mg, S, Na, Ca, Cl,and K, with Mg and S concentrations being substantially higher than those of the other elements. Weathering pathologies were predominantly observed in powdery and flaky forms,characterized by porous and fractured microstructures, with color variations due to differences in material composition. Wetting-drying cycles and chemical dissolution emerged as key factors contributing to the weathering of the walls in the Chanting Corridor. These findings provide valuable data and a theoretical basis for both scientific understanding and preventive conservation efforts in similar stone cultural heritage sites.
[1] 刁汉婷,仉文岗,王鲁琦,等.石窟岩体水致劣化机理与防治研究进展[J].重庆大学学报, 2024,47(10):1-24.
[2] 曹廷,何刘,王维,等.水岩循环对变质砂岩微观结构损伤与宏观力学劣化影响机理研究[J].工程地质学报, 2024, 32(1):96-107.
[3] 张景科,刘盾,马雨君,等.弱胶结砂岩水岩作用机制——以庆阳北石窟为例[J].东北大学学报(自然科学版), 2022, 43(7):1019-1032;1064.
[4] 甘志鑫,黄继忠,张悦,等.冻融作用下云冈石窟砂岩损伤特性与风化评估[J].上海大学学报(自然科学版), 2024, 30(1):17-30.
[5] CAi Y Y, Yu J, Guo F F, et al. Experimental investigation on the relevance of mechanical properties and porosity of sandstone after hydrochemical erosion[J]. Journal of Mountain Science, 2016, 13(11):2053-2068.
[6] 韩铁林,陈蕴生,师俊平.化学腐蚀后砂岩三轴压缩力学特性及其能量机制的试验研究[J].实验力学, 2016, 31(5):694-706.
[7] 周韬,陈昌鹏,张旸旸,等.海水腐蚀对砂岩物理力学特性与微观结构破坏特征的影响研究[J].矿业科学学报, 2024, 9(2):178-189.
[8] Morillas H, Garcia-Galan J, Maguregui M, et al. In-situ multianalytical methodology to evaluate the conservation state of the entrance arch of La Galea Fortress(Getxo, north of Spain)[J]. Microchemical Journal, 2016, 128:288-296.
[9] Theodoridou M, Torok A. In situ investigation of stone heritage sites for conservation purposes:a case study of the Székesfehérvár Ruin Garden in Hungary[J]. Progress in Earth and Planetary Science, 2019, 6(1):1-14.
[10] WAnG Y H, HAo Z Q, ZhAnG H. In situ investigation of the moisture distribution and deterioration of the fa cade of limestone rock-hewn heritage[J]. Rock Mechanics and Rock Engineering,2024, 57:2755-2762.
[11] Kurik L, Kalamees T, Kallavus U, et al. Influencing factors of moisture measurement when using microwave reflection method[J]. Energy Procedia, 2017, 132:159-164.
[12] 黄继忠,曹铖,张悦,等.微波技术在砖石质文物含水率检测中的应用[J].文物保护与考古科学,2021, 33(1):8-16.
[13] Taye B, Viles H, ORR S A. Seasonality in moisture dynamics in the walls of the rock-cut churches in Lalibela, Ethiopia:implications for weathering[J]. International Journal of Architectural Heritage, 2022, 18(1):1-14.
[14] 何静,周伟强,朱建锋,等.无损原位检测技术在高湿环境下砂岩文物劣化诱因分析中的应用[J].四川文物, 2024(2):111-120.
[15] 周杰,王逢睿,王捷,等.微波在石窟岩体水分可视化探查的研究与应用[J].科学技术与工程, 2021,21(28):12194-12202.
[16] 张悦,章云梦,黄继忠.典型石窟砂岩的毛细吸水与变形响应特征[J].文物保护与考古科学, 2012,34(3):85-93.
[17] 黄继忠,万力,彭涛,等.云冈石窟水分来源探查工程及若干成果[J].工程勘察, 2012, 40(11):1-5;11.
[18] 秦雅娟,李效珍,张勋.大同市夏季气候变化特征及其对农业生产的影响[J].农业与技术, 2021,41(5):70-71.
[19] 邓云,王金华.云冈石窟风化特征与产物研究[J].遗产与保护研究, 2019, 4(3):1-5.
[20] ORR S A, Young M, STELFox D, et al. An 'isolated diffusion' gravimetric calibration procedure for radar and microwave moisture measurement in porous building stone[J]. Journal of Applied Geophysics, 2019, 163:1-12.
[21] 张悦,陈浩宇,洪杰,等.云冈石窟第10窟风化砂岩原位无损检测与评估[J].石窟与土遗址保护研究, 2024, 3(3):32-44.
[22] 任建光,王旭升,黄继忠,等.云冈石窟建造特征与水患的关系[J].工程勘察, 2012, 40(11):17-21.
[23] 任建光,黄继忠,任志伟,等.云冈石窟盐类析出物与石雕表面风化破坏形式的关系研究[J].文物保护与考古科学, 2021, 33(6):47-51.
[24] 马策,蒋小伟,闫宏彬,等.基于红外热成像技术的石窟壁面凝结水形成规律研究[J].水文地质工程地质, 2022, 49(4):30-36.
[25] Yang X, Jiang X W, Ouyang K G, et al. The mechanisms of salt weathering responsible for sandstone deterioration in the Yungang Grottoes, China[J]. Engineering Geology, 2025, 350:107989.
[26] 周其廷,孙文静,孙德安,等.湿度循环对石窟砂岩孔隙中硫酸盐结晶过程的影响[J].东华大学学报(自然科学版), 2023, 49(2):128-135.
[27] 杜后孟,曹铖,张悦,等. SO2与水分综合影响下的云冈石窟砂岩劣化研究[J].文物保护与考古科学, 2023, 35(5):106-114.
[28] 侯志鑫,者瑞,张中俭.砂岩质文物风化机理研究——以云冈石窟为例[J].工程勘察, 2020, 48(9):1-5;18.
[29] 黄继忠,袁道先,万力,等.水岩作用对云冈石窟石雕风化破坏的化学效应研究[J].敦煌研究,2010(6):59-63.
[30] 曲希玉,陈修,邱隆伟,等.石英溶解型次生孔隙的成因及其对储层的影响——以大牛地气田上古生界致密砂岩储层为例[J].石油与天然气地质, 2015, 36(5):804-813.
[31] 田建锋,喻建,张志国.砂岩中碱性溶蚀研究进展[J].地质科技通报, 2022, 41(5):83-93;100.