上海中心城区道路灰尘中氯代多环芳烃的时空分布特征

doi:10.3969/j.issn.1007-2861.2016.01.001

上海大学学报(自然科学版) ›› 2016, Vol. 22 ›› Issue (2): 131-140.doi: 10.3969/j.issn.1007-2861.2016.01.001

上海中心城区道路灰尘中氯代多环芳烃的时空分布特征

吴明红1, 王玉洁1, 刘文龙1, 唐量1, KANNAN Kurunthachalam2, OHURA Takeshi3, 马静1

1. 上海大学环境与化学工程学院, 上海200444;
2. Wadsworth Center, New York State Department of Health, New York 12201-0509, USA;
3. Faculty of Agriculture, Meijo University, Nagoya 468-8502, Japan

收稿日期:2016-01-15 出版日期:2016-04-30 发布日期:2016-04-30
通讯作者: 马静(1980—), 女, 副研究员, 博士, 研究方向为环境地球化学. E-mail: jingma@shu.edu.cn
作者简介:马静(1980—), 女, 副研究员, 博士, 研究方向为环境地球化学. E-mail: jingma@shu.edu.cn
基金资助:
国家自然科学基金资助项目(21477072); 国家杰出青年科学基金资助项目(11025526); 上海大学长江学者和创新团队发展计划资助项目(IRT13078)

Seasonal and spatial distributions of chlorinated PAHs in road dust from downtown Shanghai

WU Minghong1, WANG Yujie1, LIU Wenlong1, TANG Liang1, KANNAN Kurunthachalam2, OHURA Takeshi3, MA Jing1

1. School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China;
2. Wadsworth Center, New York State Department of Health, New York 12201-0509, USA;
3. Faculty of Agriculture, Meijo University, Nagoya 468-8502, Japan

Received:2016-01-15 Online:2016-04-30 Published:2016-04-30

摘要/Abstract

摘要：

选取了上海中心城区的道路灰尘作为研究对象, 运用气相色谱-质谱(gas chromatography-mass spectrometry, GC/MS)联用技术对道路灰尘中20种氯代多环芳烃(chlorinated polycyclic aromatic hydrocarbons, ClPAHs)进行了检测, 分析了道路灰尘中ClPAHs的时空分布特征和毒性当量(toxic equivalent quantity, TEQ)等. 结果表明, 11种ClPAHs的检出率均大于50%, 说明ClPAHs在上海中心城区道路灰尘中普遍存在. 研究区域内的ClPAHs浓度呈现出明显的季节特征, 即冬季>夏季, 冬季∑ClPAHs浓度最高为24.9 ng/g干重. 在空间分布上, 交通枢纽区浓度最高(冬季为21.2 ng/g干重, 夏季为10.7 ng/g干重), 建筑施工区、商业区次之, 近绿地区最低. 在道路灰尘中最主要的两个组分是6-ClBaP和7-ClBaA. ClPAHs在冬季和夏季的TEQ范围分别为0.01~4.81和0.01~1.78 ng-TEQ/g干重, 其中
7-ClBaA在ClPAHs总毒性当量中的贡献最大.

关键词: 道路灰尘 , 时空分布, 污染特征 , 氯代多环芳烃

Abstract:

Concentrations of twenty chlorinated polycyclic aromatic hydrocarbons (ClPAHs) in road dust from downtown Shanghai were analyzed using gas chromatographymass spectrometry (GC/MS). Eleven of twenty ClPAH congeners were found in road dust samples with more than a detection rate of 50%, indicating that ClPAHs were ubiquitous in road dust in downtown Shanghai. Seasonal variability of ClPAHs concentrations were observed, with higher concentrations in winter than in summer. The highest concentration of total ClPAHs was 24.9 ng/(g dw) (dw means dry weight) in winter. Concentrations of
ClPAHs varied greatly in different functional areas, In particular, the highest concentration was found in transportation hub regions (21.2 ng/(g dw) in winter and 10.7 ng/(g dw) in summer) followed by construction and commercial areas, while the lowest concentration was found in green areas. The compositional analysis showed that 6-ClBaP and 7-ClBaA were the two most important components in the road dust samples. The toxic equivalent
quantity (TEQ) ranges of ClPAHs were 0.01~4.81 ng-TEQ/(g dw) in winter and 0.01~1.78 ng-TEQ/(g dw) in summer, and the toxic equivalent of 7-ClBaA contributed the most.

Key words: pollution characteristics , road dust , seasonal and spatial distribution, chlorinated polycyclic aromatic hydrocarbons (ClPAHs)

吴明红1, 王玉洁1, 刘文龙1, 唐量1, KANNAN Kurunthachalam2, OHURA Takeshi3, 马静1. 上海中心城区道路灰尘中氯代多环芳烃的时空分布特征[J]. 上海大学学报(自然科学版), 2016, 22(2): 131-140.

WU Minghong1, WANG Yujie1, LIU Wenlong1, TANG Liang1, KANNAN Kurunthachalam2, OHURA Takeshi3, MA Jing1. Seasonal and spatial distributions of chlorinated PAHs in road dust from downtown Shanghai[J]. Journal of Shanghai University（Natural Science Edition）, 2016, 22(2): 131-140.

参考文献

[1] Li K X, Liang T, Wang L Q, et al. Contamination and health risk assessment of heavy metals in road dust in Bayan Obo mining region in Inner Mongolia, North China [J]. Journal
of Geographical Sciences, 2015, 25(12): 1439-1451.
[2] Song N N, Ma J H,Yu Y, et al. New observations on PAH pollution in old heavy industry cities in northeastern China [J]. Environmental Pollution, 2015, 205: 415-423.
[3] Teixeira E C, Agudelo-Castaneda D M, Mattiuzi C D. Contribution of polycyclic aromatic hydrocarbon (PAH) sources to the urban environment: a comparison of receptor models [J].
Science of the Total Environment, 2015, 538: 212-219.
[4] Xu H M, Guinot B, Niu X Y, et al. Concentrations, particle-size distributions, and indoor/ outdoor differences of polycyclic aromatic hydrocarbons (PAHs) in a middle school classroom in Xi’an, China [J]. Environmental Geochemistry and Health, 2015, 37(5): 861-873.
[5] Chen B, Stein A F, Castell N, et al. Modeling and evaluation of urban pollution events of atmospheric heavy metals from a large Cu-smelter [J]. Science of the Total Environment, 2016, 539: 17-25.
[6] Huang J H, Li F, Zeng G M, et al. Integrating hierarchical bioavailability and population distribution into potential eco-risk assessment of heavy metals in road dust: a case study in Xiandao District, Changsha City, China [J]. Science of the Total Environment, 2016, 541: 969-976.
[7] Mummullage S, Egodawatta P, Ayoko G A, et al. Use of physicochemical signatures to assess the sources of metals in urban road dust [J]. Science of the Total Environment, 2016, 541: 1303-1309.
[8] Ohura T, Amagai T, Makino M. Behavior and prediction of photochemical degradation of chlorinated polycyclic aromatic hydrocarbons in cyclohexane [J]. Chemosphere, 2008, 70(11): 2110-2117.
[9] Horii Y, Khim J S, Higley E B, et al. Relative potencies of individual chlorinated and brominated polycyclic aromatic hydrocarbons for induction of aryl hydrocarbon receptor-mediated
responses [J]. Environmental Science & Technology, 2009, 43(6): 2159-2165.
[10] Ohura T, Morita M, Makino M, et al. Aryl hydrocarbon receptor-mediated effects of chlorinated polycyclic aromatic hydrocarbons [J]. Chemical Research in Toxicology, 2007, 20(9):
1237-1241.
[11] 马静. 废弃电子电器拆解地环境中持久性有毒卤代烃的分布特征及对人体暴露的评估[D]. 上海: 上海交通大学, 2009: 162.
[12] Shiraishi H, Pilkington N H, Otsuki A, et al. Occurrence of chlorinated polynuclear aromatic hydrocarbons in tap water [J]. Environmental Science & Technology, 1985, 19: 585-590.
[13] Horii Y, Ohura T, Yamashita N, et al. Chlorinated polycyclic aromatic hydrocarbons in sediments from industrial areas in Japan and the United States [J]. Archives of Environmental
Contamination and Toxicology, 2009, 57(4): 651-660.
[14] Ma J, Chen Z Y, Wu M H, et al. Airborne PM2.5/PM10-associated chlorinated polycyclic aromatic hydrocarbons and their parent compounds in a suburban area in Shanghai, China [J]. Environmental Science & Technology, 2013, 47(14): 7615-7623.
[15] Ohura T, Kitazawa A, Amagai T, et al. Occurrence, profiles, and photostabilities of chlorinated polycyclic aromatic hydrocarbons associated with particulates in urban air [J]. Environmental Science & Technology, 2005, 39(1): 85-91.
[16] Ohura T, Fujima S, Amagai T, et al. Chlorinated polycyclic aromatic hydrocarbons in the atmosphere: seasonal levels, gas-particle partitioning and origin [J]. Environmental Science & Technology, 2008, 42(9): 3296-3302.
[17] Kitazawa A, Amagai T, Ohura T. Temporal trends and relationships of particulate chlorinated
polycyclic aromatic hydrocarbons and their parent compounds in urban air [J]. Environmental
Science & Technology, 2006, 40(15): 4592-4598.
[18] 常静, 刘敏, 侯立军, 等. 城市地表灰尘的概念、污染特征与环境效应[J]. 应用生态学报, 2007, 18(5):
1153-1158.
[19] Horii Y, Ok G, Ohura T, et al. Occurrence and profiles of chlorinated and brominated polycyclic aromatic hydrocarbons in waste incinerators [J]. Environmental Science & Technology, 2008, 42: 1904-1909.
[20] Ma J, Horii Y, Cheng J P, et al. Chlorinated and parent polycyclic aromatic hydrocarbons in environmental samples from an electronic waste recycling facility and a chemical industrial complex in China [J]. Environmental Science & Technology, 2009, 43(3): 643-649.

上海中心城区道路灰尘中氯代多环芳烃的时空分布特征

Seasonal and spatial distributions of chlorinated PAHs in road dust from downtown Shanghai

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 2

编辑推荐

Metrics

本文评价

[1]	张晓岚, 顾越, 李晓静, 余应新. 淀山湖表层水、沉积物和鱼体中有机氯农药的时空变化及人体暴露风险[J]. 上海大学学报(自然科学版), 2016, 22(2): 122-130.
[2]	马静1 吴明红1 徐刚1 王文华2 程金平2. 结构-活性关系对氯代多环芳烃性质的预测[J]. 上海大学学报(自然科学版), 2010, 16(5): 536-540.