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期刊社   2011, Vol. 17 Issue (4): 458-470    DOI: 10.3969/j.issn.1007-2861.2011.04.013
  数理化科学 |
含氟砌块的分子设计合成及其在合成含氟杂环化合物中的应用
蒋海珍1,宋力平1,2,罗会华1,易海1,朱仕正2,郝健1,2
1.上海大学 理学院,上海 200444; 2.中国科学院 有机氟化学重点实验室,上海 200032
Design and Synthesis of Fluorine-Containing Building Blocks and Application to Synthesis of Fluorinated Heterocycles
JIANG Hai-zhen1,SONG Li-ping1,2,LUO Hui-hua1,YI Hai1,ZHU Shi-zheng2,HAO Jian1,2
1. College of Sciences, Shanghai University, Shanghai 200444, China; 2. Key Laboratory of Organofluorine Chemistry, Chinese Academy of Sciences, Shanghai 200032, China
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摘要 由于氟原子赋予的特殊性能,含氟杂环化合物在医药、农药及特种功能材料等研究领域受到广泛关注.综述近年来本研究团队常用的一些新颖含氟砌块如含氟酮酸酯、含氟亚胺酰卤等的设计合成及其在含氟杂环化合物合成中的应用进展.
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关键词:  含氟砌块  含氟杂环化合物  酮酸酯  亚胺酰卤    
Abstract: Fluorinated heterocycles have attracted substantial research attention in the fields of medicine, pesticide and special-function materials, which have special properties caused by fluorine atoms. This review highlights the recent development on the synthesis of novel fluorine-containing building blocks, such as fluorine-containing keto esters and fluorine-containing imidoyl halides, and on their applications to the preparation of fluorinated heterocycles.
Key words:  fluorinated heterocycle    fluorine-containing building block    imidoyl halide    keto ester
收稿日期:  2011-06-30                出版日期:  2011-08-30          
ZTFLH:  O 626  
基金资助: 

国家自然科学基金资助项目(20772079,21072127,21032006,21072128);上海市科委基金资助项目 (08JC1409900, 10JC1405600)

通讯作者:  郝健(1964~),男,教授,博士生导师,博士,研究方向为有机氟化学、功能材料等. E-mail:jhao@staff.shu.edu.cn    E-mail:  E-mail:jhao@staff.shu.edu.cn
引用本文:    
蒋海珍1,宋力平1,2,罗会华1,易海1,朱仕正2,郝健1,2. 含氟砌块的分子设计合成及其在合成含氟杂环化合物中的应用[J]. 期刊社 , 2011, 17(4): 458-470.
JIANG Hai-zhen1,SONG Li-ping1,2,LUO Hui-hua1,YI Hai1,ZHU Shi-zheng2,HAO Jian1,2. Design and Synthesis of Fluorine-Containing Building Blocks and Application to Synthesis of Fluorinated Heterocycles. Journal Home , 2011, 17(4): 458-470.
链接本文:  
http://www.journal.shu.edu.cn/CN/10.3969/j.issn.1007-2861.2011.04.013  或          http://www.journal.shu.edu.cn/CN/Y2011/V17/I4/458
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