退火气氛对 Bi$_{\textbf{2}}$O$_{\textbf{3}}$ 薄膜电致变色性能的影响

doi:10.12066/j.issn.1007-2861.1882

Abstract

Abstract:

Bi$_{2}$O$_{3}$ thin films were prepared with a sol-gel technique, and annealed in air, nitrogen and oxygen. The phase structures of films were analyzed with X-ray diffraction (XRD). Surface morphology was observed with scanning electron microscope (SEM). Electrochromic properties were tested with ultraviolet-visible spectroscopy (UV-Vis) and an electrochemical workstation. It is discovered that the color state of Bi$_{2}$O$_{3}$ thin films switched between black and light yellow transparent. The Bi$_{2}$O$_{3}$ thin film annealed in nitrogen with 100${\%}$ stoichiometric phase, higher $\delta $ phase, and smaller particle size distribution has the highest electrochromic efficiency of about 21 cm$^{2}$/C.

Key words: bismuth, electrochromic, thin film, sol-gel

CLC Number:

TB321

YU Jingjing, SHI Ji, YU Shengwen. Effect of annealing atmosphere on electrochromic property of Bi$_{\textbf{2}}$O$_{\textbf{3}}$ thin films[J]. Journal of Shanghai University（Natural Science Edition）, 2018, 24(6): 968-977.

Figures/Tables 8

Fig. 1

Table 1

Fig. 2

Fig. 3

Fig. 4

Fig. 5

Fig. 6

Fig. 7

References 21

[1]	Platt J R. Electrochromism, a possible change of color producible in dyes by an electric field[J]. J Chem Phys, 1961,34:862-863.
[2]	Patz J A, Campbell-Lendrum D, Holloway T, et al. Impact of regional climate change on human health[J]. Nature, 2005,438(7066):310-317. pmid: 16292302
[3]	Baetens R, Jelle B P, Gustavsen A. Properties, requirements and possibilities of smart windows for dynamic daylight and solar energy control in buildings: a state-of-the-art review[J]. Solar Energy Materials & Solar Cells, 2010,94(2):87-105.
[4]	Joraid A A. Comparison of electrochromic amorphous and crystalline electron beam deposited WO$_3$: thin films[J]. Current Applied Physics, 2009,9:73-79. doi: 10.1016/j.cap.2007.11.012
[5]	Granqvist C G. Electrochromic tungsten oxide films: review of progress[J]. Solar Energy Mater Solar Cells, 2000,60:201-262. doi: 10.1016/S0927-0248(99)00088-4
[6]	张征林, 王怡红, 王宏苏, 等. 电致变色材料及应用[J]. 电子元件与材料, 1999,18:32.
[7]	Granqvist C G. Electrochromic oxide: microstructure and optical properties[J]. Proc Soc, 1993, DOI: 10.1117/12.161949.
[8]	Corbella C, Vives M, Pinyol A, et al. Influence of the porosity of RF sputtered Ta$_2$O$_5$ thin films on their optical properties for electrochromic applications[J]. Solid State Ionics, 2003,165:15-22.
[9]	Shimanoe K, Suetsugu M, Miura N, et al. Bismuth oxide thin film as new electrochromic material[J]. Solid State Ionics, 1998(113/114/115):415-419.
[10]	崔毅, 王聪, 周瑜升. 射频磁控溅法制备 Bi$_{2}$O$_{3}$ 薄膜的电致变色性能研究[J]. 功能材料与器件学报, 2010,16(6):548-554.
[11]	Gomez C L, Depablos-Rivera O, Silva-Bermudez P. Opto-electronic properties of bismuth oxide films presenting different crystallographic phases[J]. Thin Solid Films, 2015,578:103-112.
[12]	Sammes N M, Tompsett G A, Nafe H, et al. Bismuth based oxide electrolytes-structure and ionic conductivity[J]. J Eur Ceram Soc, 1999,19(10):1801-1826.
[13]	Shuk P, Wiemh H D, Guth U, et al. Oxide ion conducting solid electrolytes based on Bi$_{2}$O$_{3}$[J]. Solid State Ionics, 1996,89:179-196.
[14]	Fan H T, Pan S S, Teng X M, et al. Deta-Bi$_{2}$O$_{3}$ thin films prepared by reactive sputtering: fabrication and characterization[J]. Thin Solid Films, 2006,513(1/2):142-147.
[15]	Switzer J A, Shumsky M G, Bohannan E W. Electrodeposited ceramic single crystals[J]. Science, 1999,284(5412):293-296.
[16]	Liu H F, Ansah A K K, Wang Y D, et al. Atomic layer deposition of crystalline Bi$_{2}$O$_{3}$ thin films and their conversion into Bi$_{2}$S$_{3}$ by thermal vapor sulfurization[J]. RSC Advances, 2014,4:58724-58731.
[17]	Cai G F, Tu J P, Zhang J, et al. An efficient route to a porous NiO/reduced graphene oxide hybrid film with highly improved electrochromic properties[J]. Nanoscale, 2012,4:5724-5730. doi: 10.1039/c2nr31397a pmid: 22885412
[18]	Moiseev G K, Vatolin N A, Belousova N V. Thermal decomposition of BiO, Bi$_{2}$O$_{3}$, BiO$_{2}$, and Bi$_{2}$O$_{5}$ in oxygen and argon media[J]. Russ J Phys Chem, 2000,74:1054.
[19]	Yang X, Lian X J, Liu S J. Visible light photoelectrochemical properties of Bi$_{2}$O$_{3 }$ nanoporous films: a study of the dependence on thermal treatment and film thickness[J]. Applied Surface Science, 2013,282:538-543.
[20]	Wen R T, Granqvist C G, Niklasson G A, et al. Eliminating degradation and uncovering ion-trapping dynamics in electrochromic WO$_{3}$ thin films[J]. Nature Materials, 2015,14:996-1001. doi: 10.1038/nmat4368 pmid: 26259104
[21]	Takahashi T, Iwahara H, Nagai Y. High oxide ion conduction in sintered Bi$_{2}$O$_{3}$ containing SrO, CaO or La$_{2}$O$_{3}$[J]. J Appl Electrochem, 1972,2(2):97-104.

Effect of annealing atmosphere on electrochromic property of Bi$_{\textbf{2}}$O$_{\textbf{3}}$ thin films

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 8

References 21

Related Articles 8

Recommended Articles

Metrics

Comments

[1]	AN Baoli, ZHU Xiaoya, XU Jiaqiang. Synjournal and luminescence properties of Bi$_{\textbf{2}}$S$_{\textbf{3}}$ quantum Dots [J]. Journal of Shanghai University（Natural Science Edition）, 2019, 25(2): 227-234.
[2]	RUAN Xiuxiu, ZUO Jianwei, CHEN Hua, XU Nannan, YANG Erwei. Synthesis of organism-based zinc-iron bimetallic catalyst by sol-gel and its visible photocatalytic activity to dyeing effluents [J]. Journal of Shanghai University（Natural Science Edition）, 2016, 22(4): 515-523.
[3]	CHEN Chen, WANG Li-jun, CHEN Zhi-wen, JIAO Zheng, WU Ming-hong. Preparation and Properties of Orthorhombic SnO₂Thin Films [J]. Journal of Shanghai University（Natural Science Edition）, 2013, 19(1): 95-99.
[4]	ZHANG Min, QIN Juan, SUN Niu-yi, ZHANG Xiao-li, SHI Wei-min. Preparation of Half-Heusler Compound Semiconductor TiCoSb Thin Film by Magnetron Sputtering [J]. Journal of Shanghai University（Natural Science Edition）, 2013, 19(1): 71-74.
[5]	GAO Rui-Juan, HANG Jian-Zhong, SHI Li-Yi, SHU Chang, HU Huo-Gen. Improving Water-Wettability of Graphite Using SiO₂Sol-Gel Coatings [J]. Journal of Shanghai University（Natural Science Edition）, 2011, 17(6): 762-767.
[6]	SUN Bohua,HAN Li-feng. Mechanical Analysis of Micromachined Accelerometer with Piezoelectric Thin Films Read-out [J]. Journal of Shanghai University（Natural Science Edition）, 2009, 15(6): 621-627.
[7]	WU Wen-biao;ZHOU Dong-yi;JIN Deng-ren;MENG Zhong-yan. Preparation of SandwichLike Multilayered PbxSr1-xTiO3 Thin Film wit h Study of Dielectric Tunability and Temperature Stability [J]. Journal of Shanghai University（Natural Science Edition）, 2008, 14(5): 498-502 .
[8]	YU Sheng-wen;CAI Jin-yu;YAN Yun-fei;CHENG Jin-rong. BiFeO₃ Thin Films Fabricated by Sol-gel Method and Its Thickness Dependence [J]. Journal of Shanghai University（Natural Science Edition）, 2008, 14(5): 509-513 .